Cenozoic temperate and sub‐tropical carbonate sedimentation on an oceanic volcano – Chatham Islands,New Zealand

The Chatham Islands, at the eastern end of the Chatham Rise in the South‐west Pacific, are the emergent part of a Late Cretaceous to Cenozoic stratovolcano complex that is variably covered with limestones and fossiliferous tuffs. Most of these deposits accumulated in relatively shallow, high‐energy, tide‐influenced palaeoenvironments with deposition punctuated by periods of deeper‐water pelagic accumulation. Carbonate components in these neritic deposits are biogenic and dominated by molluscs and bryozoans – a heterozoan assemblage. The widespread Middle to Late Eocene Matanginui Limestone contains local photozoan elements such as large benthonic foraminifera (especially Asterocyclina) and calcareous green algae, reflecting the general Palaeogene sub‐tropical oceanographic setting. More localized Late Eocene to Oligocene deposits (Te One Limestone) as well as Pliocene carbonates (Onoua Limestone) are, however, wholly heterozoan and confirm a generally cooler‐water oceanographic setting, similar to today. Early sea floor diagenesis is interpreted to have removed most aragonite components (infaunal bivalves and epifaunal gastropods). Lack of aragonite resulted in the absence of intergranular calcite cementation during subaerial exposure, such that most carbonates are friable or unlithified. Cementation is, however, present at nodular hardground–firmground caps to metre‐scale cycles. Such cements are microcrystalline or micrometre‐thick isopachous circumgranular rinds with insufficient definitive attributes to pinpoint their environment of formation. The overall palaeoenvironment of deposition is interpreted as mesotrophic, resulting in part from upwelling about the Chatham volcanic massif and in part from nutrient element delivery from the adjacent volcanic terrane and coeval volcanism. Biotic diversity in tuffs is two to three times that in limestones, supporting the notion of especially high nutrient availability during periods of volcanism. These mid‐latitude deposits are strikingly different from their low‐latitude, tropical, photozoan counterparts in the volcanic island–coral reef ecosystem. Ground water seepage and fluvial runoff attenuate coral growth and promote microbial carbonate precipitation in these warm‐water settings. In contrast, nutrients from the same sources feed the system in the Chatham Islands cool‐water setting, promoting active heterozoan carbonate sedimentation.     

Impacts of climate, lake size, and supra- and sub-permafrost groundwater flow on lake-talik evolution, Yukon Flats, Alaska (USA)

In cold regions, hydrologic systems possess seasonal and perennial ice-free zones (taliks) within areas of permafrost that control and are enhanced by groundwater flow. Simulation of talik development that follows lake formation in watersheds modeled after those in the Yukon Flats of interior Alaska (USA) provides insight on the coupled interaction between groundwater flow and ice distribution. The SUTRA groundwater simulator with freeze–thaw physics is used to examine the effect of climate, lake size, and lake–groundwater relations on talik formation. Considering a range of these factors, simulated times for a through-going sub-lake talik to form through 90 m of permafrost range from ～200 to >?1,000  years (vertical thaw rates <?0.1–0.5  m?yr^?1). Seasonal temperature cycles along lake margins impact supra-permafrost flow and late-stage cryologic processes. Warmer climate accelerates complete permafrost thaw and enhances seasonal flow within the supra-permafrost layer. Prior to open talik formation, sub-lake permafrost thaw is dominated by heat conduction. When hydraulic conditions induce upward or downward flow between the lake and sub-permafrost aquifer, thaw rates are greatly increased. The complexity of ground-ice and water-flow interplay, together with anticipated warming in the arctic, underscores the utility of coupled groundwater-energy transport models in evaluating hydrologic systems impacted by permafrost.     

A Compilation of Silicon,Rare Earth Element and Twenty‐One other Trace Element Concentrations in the Natural River Water Reference Material SLRS‐5 (NRC‐CNRC)

The natural river water certified reference material SLRS‐5 (NRC‐CNRC) was routinely analysed in this study for major and trace elements by ten French laboratories. Most of the measurements were made using ICP‐MS. Because no certified values are assigned by NRC‐CNRC for silicon and 35 trace element concentrations (rare earth elements, Ag, B, Bi, Cs, Ga, Ge, Li, Nb, P, Rb, Rh, Re, S, Sc, Sn, Th, Ti, Tl, W, Y and Zr), or for isotopic ratios, we provide a compilation of the concentrations and related uncertainties obtained by the participating laboratories. Strontium isotopic ratios are also given.     

A Common Reference Material for Cadmium Isotope Studies – NIST SRM 3108

Research into natural mass‐dependent stable isotope fractionation of cadmium has rapidly expanded in the past few years. Methodologies are diverse with MC‐ICP‐MS favoured by all but one laboratory, which uses thermal ionisation mass spectrometry (TIMS). To quantify the isotope fractionation and correct for instrumental mass bias, double‐spike techniques, sample‐calibrator bracketing or element doping has been used. However, easy comparison between data sets has been hampered by the multitude of in‐house Cd solutions used as zero‐delta reference in different laboratories. The lack of a suitable isotopic reference material for Cd is detrimental for progress in the long term. We have conducted a comprehensive round‐robin assay of NIST SRM 3108 and the Cd isotope offsets to commonly used in‐house reference materials. Here, we advocate NIST SRM 3108 both as an isotope standard and the isotopic reference point for Cd and encourage its use as ‘zero‐delta’ in future studies. The purity of NIST SRM 3108 was evaluated regarding isobaric and polyatomic molecular interferences, and the levels of Zn, Pd and Sn found were not significant. The isotope ratio ¹¹⁴Cd/¹¹⁰Cd for NIST SRM 3108 lies within ～ 10 ppm Da^?1 of best estimates for the Bulk Silicate Earth and is validated for all measurement technologies currently in use.     

Decoupling as an alternate model for transpression during the initial opening of the Norwegian-Greenland Sea

Transpressive plate motions during the opening of the Norwegian-Greenland Sea were in some manner responsible for the development of Spitsbergen's Tertiary fold-and-thrust belt. A flower model has been proposed for the large-scale structural architecture of Tertiary deformation (Lowell 1972). An alternate model of decoupling, where convergent and transcurrent motions were accommodated in totally or partially separated, subparallel belts is suggested.     

Rhodolith-bearing limestones as transgressive marker beds: fossil and modern examples from North Island, New Zealand

Rhodoliths are nodular structures composed mainly of the superimposed thalli of calcareous red algae. Because their development is controlled by an array of ecological parameters, rhodoliths are a valuable source of palaeoenvironmental information. However, despite their common use in palaeoecological reconstructions, the stratigraphic significance of rhodolith accumulations seldom has been addressed in detail. In a study of Cenozoic rhodolith‐bearing deposits from the North Island of New Zealand, rhodolithic units, usually of limited lateral extent, typically occur above major unconformities at the base of deepening upwards successions. Two types of transgressive rhodolith‐bearing deposits may be distinguished on the basis of texture and rhodolith internal structure: (i) type A deposits are clast‐supported rhodolithic rudstones containing abundant pebbles and cobbles reworked from the substrate, and are characterized by rhodoliths with a compact concentric to columnar internal structure and a high nucleus to algal cover ratio; (ii) type B deposits are rhodolithic floatstones with a matrix usually consisting of bryozoan fragments, benthic foraminifera and echinoid fragments or terrigenous silty fine sand. The rhodoliths of type B units usually have a loose internal framework with irregular to branched crusts. The two contrasting rhodolith‐bearing units are interpreted as characteristic facies of transgressive systems tract deposits, analogous to shell concentrations formed under conditions of low net sedimentation. Type A deposits are correlated with relatively high‐energy settings and/or narrow submerged palaeotopographic lows, whereas type B deposits are interpreted as forming in lower‐energy settings. The association between transgression and development of rhodolithic facies is confirmed by observations of a modern rhodolith production site at Whangaparaoa Peninsula in North Island, where algal nodules grow above a ravinement surface cut during the Holocene sea‐level rise, and also by a review of published fossil examples, many of which show stratigraphic and compositional attributes analogous to those of the New Zealand occurrences. The review indicates that transgressive rhodolith accumulations develop more commonly in, but are not restricted to, non‐tropical settings. It is suggested that a combination of factors, such as low net sedimentary input, nature of the substrate, sea‐level rise and inherited physiography contribute to determine the relationship between rhodolith‐bearing deposits and transgressive settings.     

Cross-stratified calcarenites from New Zealand: subaqueous dunes in a cool-water, Oligo-Miocene seaway

Cross-bedded, cool-water, bioclastic limestones of the Te Kuiti Group on the North Island of New Zealand are composed primarily of bryozoans, echinoderms, and benthic foraminifers. Their prominent, large-scale, unidirectional cross-stratification is interpreted as produced by migrating subaqueous dunes on the floor of a 50–100 km wide, north-east-trending seaway in water depths of 40–60 m. These dunes are thought to have developed in response to strong, seaway-parallel, tidal currents combined with a north-east-directed, set-up or oceanic current. Cross-stratification is organized into four hierarchical levels: (1) cross-lamination; (2) first-order sets; (3) second-order sets; and (4) cross-stratified successions. The levels are based on increasing degrees of internal complexity. Distinct attributes such as internal organization, cross-set thickness, foreset shape, and lower bounding-surface shape are used to describe and interpret the cross-stratification. All these attributes are here integrated in a new and expanded classification of unidirectional cross-stratification that emphasizes flow and bedform dynamics rather than overall set shape. Individual cross-stratified successions are interpreted to have formed by dunes with varying sinuosity, superposition, and flow history, under conditions of different current strength but constant sediment production. Horizontally bedded successions are the result of robust, active dune fields that grew during times of vigorous sediment transport. Formset successions were produced from large compound dunes and are the expression of languid and decaying dune fields that developed during times of decreasing sediment transport. These decaying dunes were gradually smothered by continuously and locally produced bioclastic sediment. Formset cross-stratified successions are most likely to develop in carbonates, where the sediment is produced in place, than in terrigenous clastics where the sediment is imported.     

Enhanced Acoustic Backscatter Due to High Abundance of Sand Dollars, Dendraster excentricus

Detailed acoustic surveys of benthic sediments were conducted in July 1995 and September 1998 in the vicinity of Humboldt Bay, California. During these surveys, a band of enhanced acoustic backscatter was observed offshore from the bay entrance, approximately parallel to the isobaths, in water depths ranging from 16-24 m. In order to assess the cause of the increase in backscatter levels, a more comprehensive study was conducted in August and September 1999 using 100 kHz side-scan sonar, bottom grab sampling and underwater video recording. New observations indicated that a dense population of sand dollars ( Dendraster excentricus ) coincided with the enhanced backscatter band. Compared to the two previous acoustic studies, the central section of the band expanded westward by 180 m and the southern section of the band shifted eastward by 160 m, possibly resulting from a change in the biological or physical factors which influence the location and breadth of sand dollars. The relationship between high sand dollar abundance and enhanced acoustic backscatter was further verified in the nearshore region off Samoa Beach California, where a dense, banded population of sand dollars was previously observed. Video footage confirmed the presence of a band of sand dollars, also nominally parallel to the isobaths, in water depths of 8-15 m. A band of enhanced backscatter coincided with the dense sand dollar population. The identification of dense aggregations of sand dollars through enhanced acoustic backscatter could lead to the use of acoustic techniques to study sand dollar distributions and abundance.     

A structural model from local earthquake tomography: Application to present-day tectonics of the Upper Rhine Graben

We present a novel numerical approach to construct quantitative tectonic models from crustal velocity distributions derived from local earthquake tomography. Independent constraints on the location and orientation of structures are obtained from earthquake hypocenters and seismic reflection profiles. An application of this method is given for the southern end of the Upper Rhine Graben (northwestern Europe). Kinematic boundary conditions are imposed on the structural model to investigate the large scale intraplate deformation in the region. A 3-D finite element code is used to calculate the displacements, the distribution of stresses, and the potential for brittle failure in the Graben. The modeling takes into account the intersection and curvature of crustal faults. The results demonstrate the dependence of fault interaction in the system on kinematic conditions, as well as the influence of minor faults on the kinematics of major basin bounding master faults. We show that although most of the deformation in the region is taken up by the eastern boundary faults of the Rhine Graben, all faults in the system have the potential to be (re)activated. In particular, a fault system underlying the front of the Jura fold and thrust belt appears to accommodate a large part of the intraplate deformation.     

MINERALOGIC AND CHEMICAL VARIATIONS BETWEEN UPPER CRETACEOUS CONTINENTAL BELLY RIVER SHALES AND MARINE WAPIABI SHALES IN WESTERN ALBERTA, CANADA

Nineteen shales from the continental Belly River Formation and sixteen shales from the marine Wapiabi Formation were studied by X-ray diffraction and fluorescence methods. The diffraction data indicate that dolomite and Mite are present in signifi- cant amounts only in the Wapiabi. Feldspar and 12 Å and 14 Å clays are more abundant in the continental shales. The marine shales are enriched in K, Ca, Rb and Zr. The continental shales are higher than marine shales in Sr and Mn. The Rb/K is higher in the marine shales, the Sr/Ca is lower than in the continental shales.