Origin of blocky aragonite cement in Cenozoic glaciomarine sediments,McMurdo Sound,Antarctica

Inorganic aragonite occurs in a wide spectrum of depositional environments and its precipitation is controlled by complex physio-chemical factors. This study investigates diagenetic conditions that led to aragonite cement precipitation in Cenozoic glaciomarine deposits of McMurdo Sound, Antarctica. A total of 42 sandstones that host intergranular cement were collected from the CIROS-1 core, located proximal to the terminus of Ferrar Glacier. Standard petrography, Raman spectroscopy and electron microprobe analysis reveal a prominent aragonite cement phase that occurs as a pore-filling blocky fabric throughout the core. Oxygen isotope compositions (δ¹⁸O = −30·0 to −8·6‰ Vienna Pee-Dee Belemnite) and clumped isotope temperatures (TΔ₄₇ = 13·1 to 31·5°C) determined from the aragonite cements provide precise constraints on isotopic compositions (δ¹⁸O_w) of the parent fluid, which mostly range from −10·8 to −7·2‰ Vienna Standard Mean Ocean Water. The fluid δ¹⁸O_w values are consistent with those of pore water, previously identified as cryogenic brine in the nearby AND-2A core. Petrographic and geochemical data suggest that aragonite cement in the CIROS-1 core precipitated from a similar brine. The brine likely formed and infiltrated sediments in flooded glacial valleys along the western margin of McMurdo Sound during the middle Miocene Climatic Transition, and subsequently flowed basinward in the subsurface. Consequently, the brine forms as a longstanding subsurface fluid that has saturated Cenozoic sediments below southern McMurdo Sound since at least the middle Miocene. Aragonite cementation in the CIROS-1 core is interpreted to reflect its proximal position to sites of brine formation and greater likelihood of experiencing brines with sustained high carbonate saturation states and Mg/Ca ratios. This unusual occurrence expands the range of known natural occurrences of aragonite cement. Given the potential for cryogenic brine formation in glaciomarine settings, blocky aragonite, as the end member of the spectrum of aragonite cement morphology, may be more widespread in glaciomarine sediments than currently thought.     

Changing Intra‐Urban Location Patterns of Major League Sports Facilities

The boom in U.S. major league sporting venue construction has forced many cities to face issues related to the provision of such facilities, including the location choice. Recent data show that the suburbanization trend long assumed in the literature has been reversed, with a resurgence in downtown venues. This paper demonstrates the reversal and discusses the reasons behind this recent trend. These include a concomitant trend toward smaller market franchises, increasing corporate sponsorship, deliberate downtown revitalization strategies, and the advantages accruing to owners when different parts of an urban area compete for franchises.     

Relationship Between Oil Exposure and Reproductive Parameters in Fish Collected Following the Exxon Valdez Oil Spill

Following the Exxon Valdez oil spill (EVOS) in 1989, the effect of oil exposure on reproductive parameters was investigated in wild populations of female dolly varden, yellowfin sole, and pollock. Exposure to oil was the highest in the first year of sampling and decreased in the subsequent years of sampling. Both positive and negative correlations between reproductive parameters and indices of exposure were detected in varying degrees for all three species. Reproductive parameters were not measured in the first year of sampling. For those parameters found to be significantly correlated to oil exposure, an exponential regression function was used to project reproductive parameters of fish sampled in the first year of the spill. A higher proportion of dolly varden sampled in 1989 were projected to have depressed plasma estradiol-17β compared to the fish sampled in 1990.     

Unreported bycatch in the New Zealand West Coast South Island hoki fishery

There are recognised benefits to managing fisheries by individual transferable quotas (ITQs), but ITQs may increase incentives to discard fish.     

Sequence stratigraphic framework for mixed aeolian,peritidal and marine environments: Insights from the Pennsylvanian subtropical record of Western Pangaea

Due to difficulties in correlating aeolian deposits with coeval marine facies, sequence stratigraphic interpretations for arid coastal successions are debated and lack a unifying model. The Pennsylvanian record of northern Wyoming, USA, consisting of mixed siliciclastic–carbonate sequences deposited in arid, subtropical conditions, provides an ideal opportunity to study linkages between such environments. Detailed facies models and sequence stratigraphic frameworks were developed for the Ranchester Limestone Member (Amsden Formation) and Tensleep Formation by integrating data from 16 measured sections across the eastern side of the Bighorn Basin with new conodont biostratigraphic data. The basal Ranchester Limestone Member consists of dolomite interbedded with thin shale layers, interpreted to represent alternating deposition in shallow marine (fossiliferous dolomite) and supratidal (cherty dolomite) settings, interspersed with periods of exposure (pedogenically modified dolomites and shales). The upper Ranchester Limestone Member consists of purple shales, siltstones, dolomicrites and bimodally cross‐bedded sandstones in the northern part of the basin, interpreted as deposits of mixed siliciclastic–carbonate tidal flats. The Tensleep Formation is characterized by thick (3 to 15 m) aeolian sandstones interbedded with peritidal heteroliths and marine dolomites, indicating cycles of erg accumulation, preservation and flooding. Marine carbonates are unconformably overlain by peritidal deposits and/or aeolian sandstones interpreted as lowstand systems tract deposits. Marine transgression was often accompanied by the generation of sharp supersurfaces. Lags and peritidal heteroliths were deposited during early stages of transgression. Late transgressive systems tract fossiliferous carbonates overlie supersurfaces. Highstand systems tract deposits are lacking, either due to non‐deposition or post‐depositional erosion. The magnitude of inferred relative sea‐level fluctuations (>19 m), estimated by comparison with analogous modern settings, is similar to estimates from coeval palaeotropical records. This study demonstrates that sequence stratigraphic terminology can be extended to coastal ergs interacting with marine environments, and offers insights into the dynamics of subtropical environments.     

Bulk rock composition and geochemistry of olivine-hosted melt inclusions in the Grey Porri Tuff and selected lavas of the Monte dei Porri volcano, Salina, Aeolian Islands, southern Italy

The Aeolian Islands are an arcuate chain of submarine seamounts and volcanic islands, lying just north of Sicily in southern Italy. The second largest of the islands, Salina, exhibits a wide range of compositional variation in its erupted products, from basaltic lavas to rhyolitic pumice. The Monte dei Porri eruptions occurred between 60 ka and 30 ka, following a period of approximately 60,000 years of repose. The bulk rock composition of the Monte dei Porri products range from basaltic-andesite scoria to andesitic pumice in the Grey Porri Tuff (GPT), with the Monte dei Porri lavas having basaltic-andesite compositions. The typical mineral assemblage of the GPT is calcic plagioclase, clinopyroxene (augite), olivine (Fo_72?84) and orthopyroxene (enstatite) ± amphibole and Ti-Fe oxides. The lava units show a similar mineral assemblage, but contain lower Fo olivines (Fo_57?78). The lava units also contain numerous glomerocrysts, including an unusual variety that contains quartz, K-feldspar and mica. Melt inclusions (MI) are ubiquitous in all mineral phases from all units of the Monte dei Porri eruptions; however, only data from olivine-hosted MI in the GPT are reported here. Compositions of MI in the GPT are typically basaltic (average SiO₂ of 49.8 wt %) in the pumices and basaltic-andesite (average SiO₂ of 55.6 wt %) in the scoriae and show a bimodal distribution in most compositional discrimination plots. The compositions of most of the MI in the scoriae overlap with bulk rock compositions of the lavas. Petrological and geochemical evidence suggest that mixing of one or more magmas and/or crustal assimilation played a role in the evolution of the Monte dei Porri magmatic system, especially the GPT. Analyses of the more evolved mineral phases are required to better constrain the evolution of the magma.