Glacial–interglacial changes in Subantarctic sea surface temperature and δO-water using foraminiferal Mg

Laboratory culturing experiments with living Globigerina bulloides indicate that Mg/Ca is primarily a function of seawater temperature and suggest that Mg/Ca of fossil specimens is an effective paleotemperature proxy. Using culturing results and a core-top Neogloboquadrina pachyderma calibration, we have estimated glacial–interglacial changes in sea surface temperature (SST) using planktonic Mg/Ca records from core RC11-120 in the Subantarctic Indian Ocean (43°S, 80°E) and core E11-2 in the Subantarctic Pacific Ocean (56°S, 115°W). Our results suggest that glacial SST was about 4°C cooler in the Subantarctic Indian Ocean and 2.5°C cooler in the Subantarctic Pacific. Comparison of SST and planktonic δ¹⁸O records indicates that changes in SST lead changes in δ¹⁸O by on average 1–3 kyr. The glacial–interglacial temperature change indicated by the Subantarctic Mg/Ca records suggests that temperature accounts for 40–60% of the foraminiferal δ¹⁸O change. We have used the Mg/Ca-based SST estimates and δ¹⁸O determinations to generate site-specific seawater δ¹⁸O records, which suggest that seawater δ¹⁸O was on average 1‰ more positive during glacial episodes compared with interglacial episodes.     

On board short-time high temperature heat treatment of ballast water: a field trial under operational conditions

A ballast water short-time high temperature heat treatment technique was applied on board a car-carrier during a voyage from Egypt to Belgium. Ballast water from three tanks was subjected for a few seconds to temperatures ranging from 55 degrees C to 80 degrees C. The water was heated using the vessel's heat exchanger steam and a second heat exchanger was used to pre-heat and cool down the water. The treatment was effective at causing mortality of bacteria, phytoplankton and zooplankton. The International Maritime Organization (IMO) standard was not agreed before this study was carried out, but comparing our results gives a broad indication that the IMO standard would have been met in some of the tests for the zooplankton, in all the tests for the phytoplankton; and probably on most occasions for the bacteria. Passing the water through the pump increased the kill rate but increasing the temperature above 55 degrees C did not improve the heat treatment's efficacy.     

Isotopic signature of burial diagenesis and primary lithological contrasts in periplatform carbonates (Miocene, Great Bahama Bank)

The stable isotope geochemistry of Miocene sediments from the leeward margin of the Great Bahama Bank was examined to investigate burial diagenetic processes in periplatform carbonates. Data indicate that, in addition to differences in bulk proportions of neritic and pelagic carbonate along the slope, rhythmic variation in primary carbonate content has controlled patterns of burial diagenesis and associated geochemical signatures throughout much of the succession examined. The present study focuses on Ocean Drilling Program Sites 1006 and 1007, the most distal of five sites drilled from marginal to deep basin environments during Leg 166. These Miocene sections are characterized by their cyclic appearance, manifest as decimetre‐ to metre‐scale alternations between light‐coloured ooze/chalk/limestone and dark‐coloured marl/marlstone. The section at Site 1006 contains a high proportion of pelagic carbonate and is unlithified to a subbottom depth of ～675 m. Fluctuations in δ¹⁸O and δ¹³C values at this site are independent of lithological variation and reflect primary conditions. At Site 1007, located at the toe‐of‐slope and composed of a mixture of bank‐derived and pelagic carbonate, limestones are densely cemented, show little evidence of compaction and have δ¹⁸O values up to 2‰ higher than coeval sediments at Site 1006. Marlstones at Site 1007 are poorly cemented, exhibit an increase in compaction‐related features with depth and have lower and more variable δ¹⁸O values that are similar to those of coeval sediments at Site 1006. Isotopic and petrographic characteristics of limestone interbeds result from cement precipitation from cold sea water during the first ～100 m of burial. Higher proportions of insoluble materials and pelagic carbonate seem to have inhibited diagenetic alteration in adjacent marlstones; in spite of significant compaction and pressure solution during burial, original isotopic compositions appear to be best preserved in these intervals at Site 1007. The documented contrasts in petrographic and isotopic patterns illustrate the role of primary sediment composition in controlling lithification processes in periplatform carbonates and stress the importance of considering such factors when interpreting geochemical data from ancient shelf and slope limestones.     

A Regional Scale Investigation of Climatological Tropical Convection and Precipitation in the Amazon Basin

This study constructs a regional scale climatology of tropical convection and precipitation from more than 15 years of monthly outgoing longwave radiation (OLR) and precipitation data on 2.5°× 2.5° latitude‐longitude grid to examine the spatial and temporal patterns and variability of convection and precipitation in the Amazon Basin. A linear regression analysis also detects if any trends exist in the two datasets. The region of study extends from 15°N to 25°S and 30° to 80°W that encompass the Amazon Basin and surrounding fringe areas for the period from January 1979 through December 1995 for the OLR data and up to 1996 for the precipitation dataset. The basin‐average mean monthly and seasonal climatology serve as a ‘baseline’ reference for comparison with the full time series of basin‐average monthly OLR and precipitation to illustrate the interannual variability and identify anomalous periods of wet and dry conditions. A linear trend analysis of OLR data found small negative values across the Amazon Basin indicating a slight increase in convective activity over the period of study. The analysis of the precipitation time series, however, shows no coincidental increase in precipitation as would be expected with an increase in convective activity. Portions of Rondônia and Mato Grosso, areas that have undergone extensive deforestation, illustrate no trend in precipitation as suggested by GCM simulation results. The only area featuring any large change in precipitation occurs in a small area in the northwestern region of South America where a large positive trend in precipitation exists.     

A laboratory investigation into the effects of slope on lava flow morphology

In an attempt to model the effect of slope on the dynamics of lava flow emplacement, four distinct morphologies were repeatedly produced in a series of laboratory simulations where polyethylene glycol (PEG) was extruded at a constant rate beneath cold sucrose solution onto a uniform slope which could be varied from 1° through 60°. The lowest extrusion rates and slopes, and highest cooling rates, produced flows that rapidly crusted over and advanced through bulbous toes, or pillows (similar to subaerial “toey” pahoehoe flows and to submarine pillowed flows). As extrusion rate and slope increased, and cooling rate decreased, pillowed flows gave way to rifted flows (linear zones of liquid wax separated by plates of solid crust, similar to what is observed on the surface of convecting lava lakes), then to folded flows with surface crusts buckled transversely to the flow direction, and, at the highest extrusion rates and slopes, and lowest cooling rates, to leveed flows, which solidified only at their margins. A dimensionless parameter, Ψ, primarily controlled by effusion rate, cooling rate and flow viscosity, quantifies these flow types. Increasing the underlying slope up to 30° allows the liquid wax to advance further before solidifying, with an effect similar to that of increasing the effusion rate. For example, conditions that produce rifted flows on a 10° slope result in folded flows on a 30° slope. For underlying slopes of 40°, however, this trend reverses, slightly owing to increased gravitational forces relative to the strength of the solid wax. Because of its significant influence on heat advection and the disruption of a solid crust, slope must be incorporated into any quantitative attempt to correlate eruption parameters and lava flow morphologies. These experiments and subsequent scaling incorporate key physical parameters of both an extrusion and its environment, allowing their results to be used to interpret lava flow morphologies on land, on the sea floor, and on other planets.     

Lithium isotope variations in Tonga–Kermadec arc–Lau back‐arc lavas and Deep Sea Drilling Project (DSDP) Site 204 sediments

Lithium isotopes have been identified as a promising tracer of subducted materials in arc lavas due to the observable variations in related reservoirs such as subducting sediments and altered oceanic crust. The Tonga–Kermadec arc–Lau back‐arc provides an end‐member of subduction zones with the coldest thermal structure on Earth. Reported here are Li isotope data for 14 lavas from the arc front and 7 back‐arc lavas as well as 12 pelagic and volcaniclastic sediments along a profile through the sedimentary sequence at DSDP Site 204. The arc and back‐arc lavas range from basalts to dacites in composition with SiO₂ = 48.3–65.3 wt% over which Li concentrations increase from 2 ppm to 16 ppm. Li/Y ratios range from 0.08 to 0.77 and from 0.24 to 0.65 in the arc and back‐arc lavas, respectively. The majority of the lavas have δ⁷Li that ranges from 2.5 ‰ to 5.0 ‰ with an average of (3.6 ±0.7) ‰, similar to that reported from other arcs and there is no distinction between the arc front and back‐arc lavas. The pelagic sediments have variable Li concentrations (33–133 ppm) and δ⁷Li that ranges from 1.2 ‰ to 10.2 ‰ while the volcaniclastic sediments have an even greater range of Li concentrations (3.6–165 ppm) and generally higher δ⁷Li values (8–14 ‰). However, δ⁷Li in the lavas does not correlate with commonly used trace element ratio or isotope signatures indicative of slab‐derived fluids or the sediments. This is probably because the range of δ⁷Li in the lavas and sediments overlap. Calculated sediment mass‐balance models require significantly more sediment than previous estimates based on Th–Nd–Be isotopes. This may indicate that a sizeable proportion of the total Li budget in the lavas is provided by Li‐enriched fluids from the subducting sediments and/or altered oceanic crust.     

Minimal‐disturbance seismic rehabilitation of steel moment‐resisting frames using light‐weight steel elements

This paper presents a rehabilitation technique developed under a design and construction scheme, termed minimal‐disturbance seismic rehabilitation. This scheme pursues enhancing the seismic performance of buildings with the intention of improving the continuity of business while minimizing obstruction of the visual and physical space of building users and the use of heavy construction equipment and hot work (welding/cutting). The developed rehabilitation technique consists of light‐weight steel elements and aims to decrease demands to beam‐ends of steel moment‐resisting frames. The behavior of the baseline model was verified through numerical analysis and proof‐of‐concept testing. Furthermore, the effectiveness of rehabilitation is studied through retrofitting a four‐story steel moment‐resisting frame originally designed with Japanese design guidelines. Copyright © 2015 John Wiley & Sons, Ltd.     

The promise and perils of building a co-management regime: An institutional assessment of New Zealand fisheries management between 1999 and 2005

This article uses a longitudinal survey (1999–2005) of commercial stakeholder organizations (CSOs) to assess the development, strengths and weaknesses of New Zealand's fisheries co-management over its first six years. After presenting the current characteristics and activities of CSOs, the institutional analysis and development (IAD) Framework is used to examine the regime. Results show a pattern of strengths and weaknesses with some areas substantially improved since earlier waves of the survey, while other areas have experienced surprising setbacks. These results suggest that in 2005 the regime remained fragile. Finally, New Zealand's recent move towards inshore “Shared Fisheries” management is explored in light of these findings.     

The UVic earth system climate model: Model description,climatology, and applications to past,present and future climates

Abstract

A new earth system climate model of intermediate complexity has been developed and its climatology compared to observations. The UVic Earth System Climate Model consists of a three‐dimensional ocean general circulation model coupled to a thermodynamic/dynamic sea‐ice model, an energy‐moisture balance atmospheric model with dynamical feedbacks, and a thermomechanical land‐ice model. In order to keep the model computationally efficient a reduced complexity atmosphere model is used. Atmospheric heat and freshwater transports are parametrized through Fickian diffusion, and precipitation is assumed to occur when the relative humidity is greater than 85%. Moisture transport can also be accomplished through advection if desired. Precipitation over land is assumed to return instantaneously to the ocean via one of 33 observed river drainage basins. Ice and snow albedo feedbacks are included in the coupled model by locally increasing the prescribed latitudinal profile of the planetary albedo. The atmospheric model includes a parametrization of water vapour/planetary longwave feedbacks, although the radiative forcing associated with changes in atmospheric CO₂ is prescribed as a modification of the planetary longwave radiative flux. A specified lapse rate is used to reduce the surface temperature over land where there is topography. The model uses prescribed present‐day winds in its climatology, although a dynamical wind feedback is included which exploits a latitudinally‐varying empirical relationship between atmospheric surface temperature and density. The ocean component of the coupled model is based on the Geophysical Fluid Dynamics Laboratory (GFDL) Modular Ocean Model 2.2, with a global resolution of 3.6° (zonal) by 1.8° (meridional) and 19 vertical levels, and includes an option for brine‐rejection parametrization. The sea‐ice component incorporates an elastic‐viscous‐plastic rheology to represent sea‐ice dynamics and various options for the representation of sea‐ice thermodynamics and thickness distribution. The systematic comparison of the coupled model with observations reveals good agreement, especially when moisture transport is accomplished through advection.

Global warming simulations conducted using the model to explore the role of moisture advection reveal a climate sensitivity of 3.0°C for a doubling of CO₂, in line with other more comprehensive coupled models. Moisture advection, together with the wind feedback, leads to a transient simulation in which the meridional overturning in the North Atlantic initially weakens, but is eventually re‐established to its initial strength once the radiative forcing is held fixed, as found in many coupled atmosphere General Circulation Models (GCMs). This is in contrast to experiments in which moisture transport is accomplished through diffusion whereby the overturning is reestablished to a strength that is greater than its initial condition.

When applied to the climate of the Last Glacial Maximum (LGM), the model obtains tropical cooling (30°N‐30°S), relative to the present, of about 2.1°C over the ocean and 3.6°C over the land. These are generally cooler than CLIMAP estimates, but not as cool as some other reconstructions. This moderate cooling is consistent with alkenone reconstructions and a low to medium climate sensitivity to perturbations in radiative forcing. An amplification of the cooling occurs in the North Atlantic due to the weakening of North Atlantic Deep Water formation. Concurrent with this weakening is a shallowing of, and a more northward penetration of, Antarctic Bottom Water.

Climate models are usually evaluated by spinning them up under perpetual present‐day forcing and comparing the model results with present‐day observations. Implicit in this approach is the assumption that the present‐day observations are in equilibrium with the present‐day radiative forcing. The comparison of a long transient integration (starting at 6 KBP), forced by changing radiative forcing (solar, CO₂, orbital), with an equilibrium integration reveals substantial differences. Relative to the climatology from the present‐day equilibrium integration, the global mean surface air and sea surface temperatures (SSTs) are 0.74°C and 0.55°C colder, respectively. Deep ocean temperatures are substantially cooler and southern hemisphere sea‐ice cover is 22% greater, although the North Atlantic conveyor remains remarkably stable in all cases. The differences are due to the long timescale memory of the deep ocean to climatic conditions which prevailed throughout the late Holocene. It is also demonstrated that a global warming simulation that starts from an equilibrium present‐day climate (cold start) underestimates the global temperature increase at 2100 by 13% when compared to a transient simulation, under historical solar, CO₂ and orbital forcing, that is also extended out to 2100. This is larger (13% compared to 9.8%) than the difference from an analogous transient experiment which does not include historical changes in solar forcing. These results suggest that those groups that do not account for solar forcing changes over the twentieth century may slightly underestimate (～3% in our model) the projected warming by the year 2100.     

Redox potential measurements and Mössbauer spectrometry of Fe adsorbed onto Fe (oxyhydr)oxides

The redox properties of Fe^II adsorbed onto a series of Fe^III (oxyhydr)oxides (goethite, lepidocrocite, nano-sized ferric oxide hydrate (nano-FOH), and hydrous ferric oxide (HFO)) have been investigated by rest potential measurements at a platinum electrode, as a function of pH (−log₁₀[H⁺]) and surface coverage. Using the constant capacitance surface complexation model to describe Fe^II adsorption onto these substrates, theoretical values of the suspension redox potential (E_H) have been computed, under the assumption that Fe^II adsorption occurs at crystal growth sites of the substrate surface. Good agreement between calculated and experimental E_H values is observed for nano-FOH and HFO, however the redox potentials measured for lepidocrocite and goethite are significantly more oxidizing than predicted. Mössbauer spectroscopic analysis of ⁵⁷Fe^II adsorbed onto HFO and goethite shows that in both cases the adsorbed ⁵⁷Fe^II is incorporated into the crystal structure of the substrate, in broad agreement with the thermodynamic model, but is almost completely oxidized to ⁵⁷Fe^III. The mechanism by which the adsorbed ⁵⁷Fe^II is oxidized is not resolved in this work, but is thought to be due to electron transfer to the substrate, rather than a net oxidation of the suspension. The disagreement between experimental and calculated rest potential measurements in the goethite and lepidocrocite systems is thought to be due to the poor electrochemical equilibration of these suspensions with the platinum electrode, rather than a failure of the thermodynamic model. The model developed for the redox potential of adsorbed Fe^II allows direct assessment of the reactivity of this species towards oxidized pollutants.