1600 K和20 GP温压条件下的顽火辉石电导率

在温度750～1600 K和压力10～20 GPa条件下,借助于Kawai-5000多面顶砧高温高压设备,就位测量了(Mg_0.9Fe_0.1) SiO₃ 顽火辉石的电导率.实验结果显示,顽火辉石的电导率在高温区以小极化子机制为主,在低温区以质子导电为主,因为实验后的样品中有一定的水含量.另外,X射线衍射实验表明压力（20 GPa）诱发了顽火辉石向林伍德石的相变,这是我们首次在顽火辉石的电导率实验中观测到林伍德石含水相变,而且含水林伍德石的电导率与已有的实验结果相当一致.     

Newly-generated Daliangshan Fault Zone—Shortcutting on the central section of Xianshuihe-Xiaojiang fault system

The Daliangshan fault zone is the eastern branch in the central section of Xianshuihe-Xiaojiang fault system. It has been neglected for a long time, partly because of no destructive earthquake records along this fault zone. On the other hand, it is located on the remote and inaccessible plateau. So far it was excluded as part of the Xianshuihe-Xiaojiang fault system. Based on the interpretation of aerophotographs and field investigations, we document this fault zone in detail, and give an estimation of strike-slip rate about 3 mm/a in Late Quaternary together with age dating data. The results suggest that the Daliangshan fault zone is a newly-generated fault zone resulted from shortcutting in the central section of Xianshuihe-Xiaojiang fault system because of the clockwise rotation of the Southeastern Tibetan Crustal Block, which is bounded by the Xianshuihe-Xiaojiang fault system. Moreover, the shortcutting may make the Daliangshan fault zone replace the Anninghe and Zemuhe fault zones gradually, and finally, the later two fault zones will probably die out with the continuous clockwise rotation.     

Perturbed physics ensemble using the MIROC5 coupled atmosphere–ocean GCM without flux corrections: experimental design and results

In this study, we constructed a perturbed physics ensemble (PPE) for the MIROC5 coupled atmosphere–ocean general circulation model (CGCM) to investigate the parametric uncertainty of climate sensitivity (CS). Previous studies of PPEs have mainly used the atmosphere-slab ocean models. A few PPE studies using a CGCM applied flux corrections, because perturbations in parameters can lead to large radiation imbalances at the top of the atmosphere and climate drifts. We developed a method to prevent climate drifts in PPE experiments using the MIROC5 CGCM without flux corrections. We simultaneously swept 10 parameters in atmosphere and surface schemes. The range of CS (estimated from our 35 ensemble members) was not wide (2.2–3.2?°C). The shortwave cloud feedback related to changes in middle-level cloud albedo dominated the variations in the total feedback. We found three performance metrics for the present climate simulations of middle-level cloud albedo, precipitation, and ENSO amplitude that systematically relate to the variations in shortwave cloud feedback in this PPE.     

Fluctuation of dissolved organic carbon in seawater of Sagami Bay during 1971–1972

Fluctuation of dissolved organic carbon (DOC) was studied during 1971–1972 at monthly intervals in surface layers of Sagami Bay. Concentration of DOC varied from 0.8 to 1.7 mgC/l in surface water (0 m). Maximum concentration of 1.7 mgC/l was observed in July 1971 and after then DOC decreased gradually to a minimum of 0.8 mgC/l in May 1972. The fluctuation of DOC during the observation periods seems to have close relations with those of water temperature and salinity. High DOC concentration found in summer months may be associated with bloom of phytoplankton or intrusion of seawater from Tokyo Bay and/or inland water containing high DOC.     

Connectivity of molten Fe alloy in peridotite based on in situ electrical conductivity measurements: implications for core formation in terrestrial planets

The connectivity of molten Fe-S in peridotite has been experimentally investigated by means of in situ electrical conductivity measurements at high temperatures and 1 GPa. Starting materials were powdered mixtures of peridotite KLB-1 with various amounts (0, 3, 6, 13, 19, 24 vol.%) of the 1 GPa eutectic composition in the Fe-FeS binary system. At temperatures above the eutectic point in the Fe-FeS system (∼980 °C) and below the solidus of KLB1 (∼1200 °C), molten Fe-S in a solid silicate matrix interconnects when the volume fraction is over ∼5%. Conductivity-temperature paths indicate that in the presence of partial silicate melting the connectivity of molten Fe-S in a peridotite matrix is inhibited. Based on observations of retrieved samples, the percolation threshold of Fe-S melts in the presence of low to moderate degrees of silicate melt is estimated at 13±2 vol.%. These results indicate that if the volume fraction of Fe-alloy in a planetesimal was initially greater than 5%, and if early heating by decay of radionuclides raised the temperature of the interior above the Fe-alloy melting point, initial metal segregation was controlled by permeable flow of molten iron alloy in a solid silicate matrix. These conditions were likely met by many terrestrial objects in the early solar nebula. Efficient removal of residual Fe-alloy (5 vol.%) from silicate requires high-degree melting of silicate so that metal can segregate as droplets. Giant impacts during the final stage of accretion of large planetary objects could supply the energy required for high-degrees of melting. Alternatively, if initial metal segregation were delayed until a planetary object grew to large size (∼1000 km in diameter), release of gravitational potential energy due to metal segregation could contribute enough heat to form a magma ocean.     

Nonaqueous titration of functional groups in humic acid

Humic acid was titrated by sodium methoxide in dimethylsulfoxide using platinum-calomel electrode systems. Adding benzoic acid and phenol as internal standards to humic acid yielded two inflections. The titer at the first inflection point was equivalent to the carboxyl groups whose pK_a (H₂O) values were less than 7. The difference between the titers at the two inflection points was equivalent to the phenolic hydroxyl groups whose pK_a (H₂O) values were 7–10. Calculated results for the carboxyl and phenolic hydroxyl groups in humic acid obtained by the nonaqueous titration method agreed closely with those obtained by conventional methods.     

Phase boundary between ilmenite and perovskite structures in MnGeO3 determined by in situ X-ray diffraction measurements

In situ X-ray observations of the phase transition from ilmenite to perovskite structure in MnGeO₃ were carried out in a Kawai-type high-pressure apparatus interfaced with synchrotron radiation. The phase boundary between the ilmenite and perovskite structures in the temperature range of 700–1,400°C was determined to be P (GPa) = 16.5(±0.6) − 0.0034(±0.0006)T (°C) based on Anderson’s gold pressure scale. The Clapeyron slope, dP/dT, determined in this study is consistent with that for the transition boundary between the ilmenite and the perovskite structure in MgSiO₃.     

Marine reservoir correction for the Pacific coast of central Japan using C ages of marine mollusks uplifted during historical earthquakes

In this study we utilize marine shell samples from two levels of historically uplifted sessile mollusk assemblages and raised wave-cut benches to evaluate the marine reservoir correction (ΔR) for the Pacific coast of central Japan. Elevation measurements of the uplifted marine shells indicate that the lower assemblage emerged during the 1923 Taisho Kanto earthquake (M7.9), whereas uplift of the upper assemblage is most likely but less confidently ascribed to the 1703 Genroku Kanto earthquake (M8.2). Radiocarbon dating of carefully selected samples from the upper and lower assemblages yielded very similar ΔR values of 82 ± 33 and 77 ± 32 yr, respectively. We regard the former ΔR value as a representative and more reliable value given the uncertainty in correlation of the upper assemblage with the 1703 earthquake. This result is consistent with previously reported ΔR values for the Pacific coast of south-central Japan and areas around the Sea of Japan that are influenced by warm ocean currents. Radiocarbon dating of coseismically uplifted shells can aid in estimating marine reservoir ages in the tectonically active Japan Islands.     

Relative contribution of feedback processes to Arctic amplification of temperature change in MIROC GCM

The finding that surface warming over the Arctic exceeds that over the rest of the world under global warming is a robust feature among general circulation models (GCMs). While various mechanisms have been proposed, quantifying their relative contributions is an important task in order to understand model behavior. Here we apply a recently proposed feedback analysis technique to an atmosphere–ocean GCM under two and four times CO₂ concentrations which approximately lead to seasonally and annually sea ice-free climates. The contribution of feedbacks to Arctic temperature change is investigated. The surface warming in the Arctic is contributed by albedo, water vapour and large-scale condensation feedbacks and reduced by the evaporative cooling feedback. The surface warming contrast between the Arctic and the global averages (AA) is maintained by albedo and evaporative cooling feedbacks. The latter contributes to AA predominantly by cooling the low latitudes more than the Arctic. Latent heat transport into the Arctic increases and hence evaporative cooling plus large-scale condensation feedback contributes positively to AA. On the other hand, dry-static energy transport into the Arctic decreases and hence dynamical heating feedback contributes negatively to AA. An important contribution is thus made via changes in hydrological cycle and not via the ‘dry’ heat transport process. A larger response near the surface than aloft in the Arctic is maintained by the albedo, water vapour, and dynamical heating feedbacks, in which the albedo and water vapour feedbacks contribute through warming the surface more than aloft, and the dynamical heating feedback contributes by cooling aloft more than the surface. In our experiments, ocean and sea ice dynamics play a secondary role. It is shown that a different level of CO₂ increase introduces a latitudinal and seasonal difference into the feedbacks.     

Crystal structure, Raman and FTIR spectroscopy, and equations of state of OH-bearing MgSiO3 akimotoite

MgSiO₃ akimotoite is stable relative to majorite-garnet under low-temperature geotherms within steeply or rapidly subducting slabs. Two compositions of Mg–akimotoite were synthesized under similar conditions: Z674 (containing about 550 ppm wt H₂O) was synthesized at 22 GPa and 1,500 °C and SH1101 (nominally anhydrous) was synthesized at 22 GPa and 1,250 °C. Crystal structures of both samples differ significantly from previous studies to give slightly smaller Si sites and larger Mg sites. The bulk thermal expansion coefficients of Z674 are (153–839 K) of a ₁ = 20(3) × 10^?9 K^?2 and a ₀ = 17(2) × 10^?6 K^?1, with an average of α ₀ = 27.1(6) × 10^?6 K^?1. Compressibility at ambient temperature of Z674 was measured up to 34.6 GPa at Sector 13 (GSECARS) at Advanced Photon Source Argonne National Laboratory. The second-order Birch–Murnaghan equation of state (BM2 EoS) fitting yields: V ₀ = 263.7(2) Å³, K _T0 = 217(3) GPa (K′ fixed at 4). The anisotropies of axial thermal expansivities and compressibilities are similar: α _a  = 8.2(3) and α _c  = 10.68(9) (10^?6 K^?1); β _a  = 11.4(3) and β _c  = 15.9(3) (10^?4 GPa). Hydration increases both the bulk thermal expansivity and compressibility, but decreases the anisotropy of structural expansion and compression. Complementary Raman and Fourier transform infrared (FTIR) spectroscopy shows multiple structural hydration sites. Low-temperature and high-pressure FTIR spectroscopy (15–300 K and 0–28 GPa) confirms that the multiple sites are structurally unique, with zero-pressure intrinsic anharmonic mode parameters between ?1.02 × 10^?5 and +1.7 × 10^?5 K^?1, indicating both weak hydrogen bonds (O–H···O) and strong OH bonding due to long O···O distances.