Giant ancient landslide in the Alma water gap (Crimean Mountains,Ukraine): notes to the predisposition,structure, and chronology

Large-scale ancient landslides of the area of more than 5 km² and volume exceeding 200 × 10⁶ m³ are characteristic features of the valleys incised in the northern periphery of the Crimean Mountains (Ukraine). The largely affected area is located in the outermost cuesta range of the Crimean Mountains which consists of rigid Sarmatian limestones overlying weak Middle Miocene and Upper Palaeogene deposits. A giant landslide arose in the Alma water gap as a reflection of several coincident preparatory factors such as suitable bedrock stratification, smectite-rich bedrock exposed to swelling activity, presence of faults parallel to the valley trend, and river capture event which preceded the landslide event. The occurrence of such ancient megaslides is particularly interesting in the area which is characterized by low precipitation (<500 mm/year) and weak contemporary seismicity. It probably reflects a more dynamic environment in humid phases of the Holocene; however, seismic triggering along the Mesozoic suture zone cannot be rejected. Compressional features such as gravitational folds in the central and distal parts of the landslide, which probably correlate with the whole landslide genesis or its significant reactivation, arose, according to the radiocarbon dating, during the Holocene climatic optimum in the Atlantic period. The slope deformation has been relatively quiescent since that time, except minor historic reactivization which took place in the frontal part of the landslide. We suppose that the studied landslide could be classified as a transitional type of slope deformation with some signs of spreading and translational block slides.     

Tidal Marsh Restoration Design Affects Feedbacks Between Inundation and Elevation Change

Tidal marsh (re)creation on formerly embanked land is increasingly executed along estuaries and coasts in Europe and the USA, either by restoring complete or by reduced tidal exchange. Ecosystem functioning and services are largely affected by the hydro-geomorphologic development of these areas. For natural marshes, the latter is known to be steered by feedbacks between tidal inundation and sediment accretion, allowing marshes to reach and maintain an equilibrium elevation relative to the mean sea level. However, for marsh restoration sites, these feedbacks may be disturbed depending on the restoration design. This was investigated by comparing the inundation-elevation change feedbacks in a natural versus restoration site with reduced tidal exchange in the Scheldt estuary (Belgium). This study analyzes long-term (9 years) datasets on elevation change and tidal inundation properties to disentangle the different mechanisms behind this elevation-inundation feedback. Moreover, subsequent changes in sediment properties that may affect this feedback were explored. In the restoration area with reduced tidal exchange, we found a different elevation-inundation feedback than on natural marshes, which is a positive feedback on initially high sites (i.e., sediment accretion leads to increasing inundation, hence causing accelerating sediment accretion rates) and a gradual silting up of the whole area. Furthermore, there is evidence for the presence of a relict consolidated sediment layer. Consequently, shallow subsidence is less likely to occur. Although short-term ecological development of the tidal marsh was not impeded, long-term habitat development may be affected by the differences in hydro-geomorphological interactions. An increase of inundation frequency on the initially high sites may cause inhibition of habitat succession or even reversed succession. Over time, the climax state of the restoration area may be different compared to natural marshes. Moreover, sediment-related ecosystem services, such as nutrient and carbon burial, may be positively influenced because of continuing sedimentation, although flood water storage potential will decrease with increasing elevation. Depending on the restoration goals, ecosystem trajectories and delivery of ecosystem services can be controlled by adaptive management of the tidal volume entering the restoration area.     

Mineralogy and chemical composition of the clay fraction of Neogene shales from the Surma Group in the Bengal basin,Bangladesh

Mineralogical and chemical investigations (<2μm clay separates) of shale samples from the Neogene-age Surma Group obtained from four wells (Habiganj-11, Shahbazpur-1, Titas-11, Titas-15) in the Bengal basin, Bangladesh, were carried out in order to reveal the clay mineral composition as reservoir exploration and exploitation requires a good understanding of the clay minerals. The samples were analyzed by X-ray diffraction (XRD), scanning electron microscope (SEM) and X-Ray fluorescence spectrometry (XRF). Mineralogically, the sub-surface Surma Group shales comprise predominantly quartz, plagioclase, illite, chlorite, kaolinite, with lesser amounts of K-feldspar, dolomite and smectite, and minor to trace amounts of calcite, siderite and pyrite. The chemical composition of the <2 μm clay separates also suggests an illite and chlorite-rich composition. With increasing burial depth, the Surma Group shales are enriched in illite. The gradual decreasing of the smectite clays with depth and ultimate disappearance at greater depths (≥ 3000 m) may have been responsible for the presence of the diagenetic illite. Based on the mineralogical composition it is most likely that the illite-chlorite associations together with quartz and feldspar were predominantly detrital in origin and thus reflect the presence of a rapidly-rising source terrain not subjected to intense weathering.     

Soft X-ray spectroscopic studies of the reaction of fractured pyrite surfaces with Cr(VI)-containing aqueous solutions

We have used synchrotron-based soft X-ray core-level photoemission and adsorption spectroscopies to study the reaction of aqueous sodium chromate solutions with freshly fractured pyrite surfaces. Pyrite surfaces were reacted with 50 μM sodium chromate solution at pH 7 for reaction times between 1 min and 37 hr. Additional experiments were performed at pH 2 and pH 4 with 50 μM sodium chromate solutions and at pH 7 with 5 mM solutions. At chromate concentrations of 50 μM, all chromium present on the pyrite surface was in the form of Cr(III), while at 5 mM, both Cr(III) and Cr(VI) were present at the pyrite surface. Minor quantities of oxidized sulfur species (sulfate, sulfite, and zero-valent sulfur) were identified as reaction products on the pyrite surface. The amount of oxidized sulfur species observed on the surface was greater when pyrite was reacted with 5 mM Cr(VI) solutions because the rate of chromium deposition exceeded the rate of dissolution of pyrite oxidation products, effectively trapping Cr(VI) and oxidized sulfur species in an overlayer of iron(III)-containing Cr(III)-hydroxide. This work shows that pyrite, an extremely cheap and readily available waste material, may be suitable for the removal of hexavalent chromium from acidic to circumneutral waste streams. The reduced chromium ultimately forms a coating on the pyrite surface, which passivates the pyrite surface towards further oxidation.     

Inclusions in diamonds from the K14 and K10 kimberlites, Buffalo Hills, Alberta, Canada: diamond growth in a plume?

Analyses of mineral inclusions, carbon isotopes, nitrogen contents and nitrogen aggregation states in 29 diamonds from two Buffalo Hills kimberlites in northern Alberta, Canada were conducted. From 25 inclusion bearing diamonds, the following paragenetic abundances were found: peridotitic (48%), eclogitic (32%), eclogitic/websteritic (8%), websteritic (4%), ultradeep? (4%) and unknown (4%). Diamonds containing mineral inclusions of ferropericlase, and mixed eclogitic-asthenospheric-websteritic and eclogitic-websteritic mineral associations suggests the possibility of diamond growth over a range of depths and in a variety of mantle environments (lithosphere, asthenosphere and possibly lower mantle).

Eclogitic diamonds have a broad range of C-isotopic composition (δ¹³C=−21‰ to −5‰). Peridotitic, websteritic and ultradeep diamonds have typical mantle C-isotope values (δ¹³C=−4.9‰ av.), except for two ¹³C-depleted peridotitic (δ¹³C=−11.8‰, −14.6‰) and one ¹³C-depleted websteritic diamond (δ¹³C=−11.9‰). Infrared spectra from 29 diamonds identified two diamond groups: 75% are nitrogen-free (Type II) or have fully aggregated nitrogen defects (Type IaB) with platelet degradation and low to moderate nitrogen contents (av. 330 ppm-N); 25% have lower nitrogen aggregation states and higher nitrogen contents (30% IaB; <1600 ppm-N).

The combined evidence suggests two generations of diamond growth. Type II and Type IaB diamonds with ultradeep, peridotitic, eclogitic and websteritic inclusions crystallised from eclogitic and peridotitic rocks while moving in a dynamic environment from the asthenosphere and possibly the lower mantle to the base of the lithosphere. Mechanisms for diamond movement through the mantle could be by mantle convection, or an ascending plume. The interaction of partial melts with eclogitic and peridotitic lithologies may have produced the intermediate websteritic inclusion compositions, and can explain diamonds of mixed parageneses, and the overlap in C-isotope values between parageneses. Strong deformation and extremely high nitrogen aggregation states in some diamonds may indicate high mantle storage temperatures and strain in the diamond growth environment. A second diamond group, with Type IaA–IaB nitrogen aggregation and peridotitic inclusions, crystallised at the base of the cratonic lithosphere. All diamonds were subsequently sampled by kimberlites and transported to the Earth's surface.     

The contribution of faint blue galaxies to the submillimetre counts and background

Observations in the submillimetre (submm) waveband have recently revealed a new population of luminous sources. These are proposed to lie at high redshift and to be optically faint because of their high intrinsic dust obscuration. The presence of dust has been previously invoked in optical galaxy count models which use the Bruzual & Charlot evolution models with an exponential τ =9 Gyr star formation rate (SFR) for spirals, and these fit the count data well from U to K . We now show that by using either a 1/ λ or Calzetti absorption law for the dust and re-distributing the evolved spiral galaxy ultraviolet (UV) radiation into the far-infrared (FIR), these models can account for all of the 'faint' ( 1 mJy) 850-μm galaxy counts, but fail to fit 'bright' ( 2 mJy) sources, indicating that another explanation for the submm counts may apply at brighter fluxes, e.g., quasi-stellar objects (QSOs) or ultraluminous infrared galaxies (ULIRGs). We find that the main contribution to the faint, submm number counts is in the redshift range 0.5< z <3, peaking at z ≈1.8. The above model, using either dust law, can also explain a significant proportion of the extragalactic background at 850 μm, as well as producing a reasonable fit to the bright 60-μm IRAS counts.     

The Influence of Wellbore Inflow on Electromagnetic Borehole Flowmeter Measurements

This paper describes a combined field, laboratory, and numerical study of electromagnetic borehole flowmeter measurements acquired without the use of a packer or skirt to block bypass flow around the flowmeter. The most significant finding is that inflow through the wellbore screen changes the ratio of flow through the flowmeter to wellbore flow. Experiments reveal up to a factor of two differences in this ratio for conditions with and without inflow through the wellbore screen. Standard practice is to assume the ratio is constant. A numerical model has been developed to simulate the effect of inflow on the flowmeter. The model is formulated using momentum conservation within the borehole and around the flowmeter. The model is embedded in the MODFLOW-2000 ground water flow code.     

Genesis and evolution of the lithospheric mantle beneath the Buffalo Head Terrane, Alberta (Canada)

Mantle xenoliths and xenocrysts were retrieved from three of the 88–86 Ma Buffalo Hills kimberlites (K6, K11, K14) for a reconnaissance study of the subcontinental lithospheric mantle (SCLM) beneath the Buffalo Head Terrane (Alberta, Canada). The xenoliths include spinel lherzolites, one garnet spinel lherzolite, garnet harzburgites, one sheared garnet lherzolite and pyroxenites. Pyroxenitic and wehrlitic garnet xenocrysts are derived primarily from the shallow mantle and lherzolitic garnet xenocrysts from the deep mantle. Harzburgite with Ca-saturated garnets is concentrated in a layer between 135–165 km depth. Garnet xenocrysts define a model conductive paleogeotherm corresponding to a heat flow of 38–39 mW/m². The sheared garnet lherzolite lies on an inflection of this geotherm and may constrain the depth of the lithosphere–asthenosphere boundary (LAB) beneath this region to ca 180 km depth.

A loss of >20% partial melt is recorded by spinel lherzolites and up to 60% by the garnet harzburgites, which may be related to lithosphere formation. The mantle was subsequently modified during at least two metasomatic events. An older metasomatic event is evident in incompatible-element enrichments in homogeneous equilibrated garnet and clinopyroxene. Silicate melt metasomatism predominated in the deep lithosphere and led to enrichments in the HFSE with minor enrichments in LREE. Metasomatism by small-volume volatile-rich melts, such as carbonatite, appears to have been more important in the shallow lithosphere and led to enrichments in LREE with minor enrichments in HFSE. An intermediate metasomatic style, possibly a signature of volatile-rich silicate melts, is also recognised. These metasomatic styles may be related through modification of a single melt during progressive interaction with the mantle. This metasomatism is suggested to have occurred during Paleoproterozoic rifting of the Buffalo Head Terrane from the neighbouring Rae Province and may be responsible for the evolution of some samples toward unradiogenic Nd and Hf isotopic compositions.

Disturbed Re–Os isotope systematics, evident in implausible model ages, were obtained in situ for sulfides in several spinel lherzolites and suggest that many sulfides are secondary (metasomatic) or mixtures of primary and secondary sulfides. Sulfide in one peridotite has unradiogenic ¹⁸⁷Os/¹⁸⁸Os and gives a model age of 1.89±0.38 Ga. This age coincides with the inferred emplacement of mafic sheets in the crust and suggests that the melts parental to the intrusions interacted with the lithospheric mantle.

A younger metasomatic event is indicated by the occurrence of sulfide-rich melt patches, unequilibrated mineral compositions and overgrowths on spinel that are Ti-, Cr- and Fe-rich but Zn-poor. Subsequent cooling is recorded by fine exsolution lamellae in the pyroxenes and by arrested mineral reactions.

If the lithosphere beneath the Buffalo Head Terrane was formed in the Archaean, any unambiguous signatures of this ancient origin may have been obliterated during these multiple events.     

An overview of hydrometeorological datasets from a small agricultural catchment (Nučice) in the Czech Republic

We introduce the freely available web-based Water in an Agricultural Landscape—NUčice Database (WALNUD) dataset that includes both hydrological and meteorological records at the Nučice experimental catchment (0.53 km²), which is representative of an intensively farmed landscape in the Czech Republic. The Nučice experimental catchment was established in 2011 for the observation of rainfall–runoff processes, soil erosion processes, and water balance of a cultivated landscape. The average altitude is 401 m a.s.l., the mean land slope is 3.9%, and the climate is humid continental (mean annual temperature 7.9°C, annual precipitation 630 mm). The catchment is drained by an artificially straightened stream and consists of three fields covering over 95% of the area which are managed by two different farmers. The typical crops are winter wheat, rapeseed, and alfalfa. The installed equipment includes a standard meteorological station, several rain gauges distributed across the basin, and a flume with an H-type facing that is used to monitor stream discharge, water turbidity, and basic water quality indicators. Additionally, the groundwater level and soil water content at various depths near the stream are recorded. Recently, large-scale soil moisture monitoring efforts have been introduced with the installation of two cosmic-ray neutron sensors for soil moisture monitoring. The datasets consist of observed variables (e.g. measured precipitation, air temperature, stream discharge, and soil moisture) and are available online for public use. The cross-seasonal, open access datasets at this small-scale agricultural catchment will benefit not only hydrologists but also local farmers.