Transport of three herbicides in ground water at Twin Lake test site,Chalk River,Ontario, Canada

A field tracer test performed under natural flow conditions at the Twin Lake test site, Chalk River Laboratories of the Atomic Energy of Canada Ltd. in Chalk River, Ontario, Canada, using tritium and three herbicides (Chlortoluron, Terbuthylazine, and Pendimethalin) was interpreted using the dispersion equation with a combined reaction model. The reaction model couples an instantaneous equilibrium reaction governed by a linear adsorption isotherm with a reversible or irreversible kinetic reaction of the first order, and decay. An improved interpretation method consists of a simultaneous fitting of theoretical concentration and mass-recovery curves to the experimental data, which leads to a more reliable determining of reaction models and improves the accuracy of fitting. Tritium served as the reference tracer to determine the flow velocity, dispersivity, and the recovery of the herbicides. Chlortoluron was slightly delayed by equilibrium exchange with strongly reduced concentration due to an irreversible kinetic reaction and/or decay. Terbuthilazine was slightly delayed by equilibrium exchange, with strongly reduced concentration due to a reversible kinetic reaction with some influence of decay. A strong equilibrium reaction and a strong reversible kinetic reaction without degradation governed the transport of Pendimethalin, reducing considerably its concentration. The results obtained show that simulations based only on Kd and decay constant, especially if these parameters are found in the laboratory, may considerably differ from those performed with reaction parameters determined in properly performed field tests. The dominant reaction types, and the values of parameters found in the study, supply useful information on the transport of the investigated herbicides in sandy aquifers under natural flow conditions.     

Steady state hodographs in a baroclinic boundary layer

If the steady-state geostrophic wind vector varies exponentially with height in the planetary boundary layer, calculated hodographs of the 24-hour mean wind resemble the classic Ekman spiral distorted by thermal effects. For such an assumed distribution, Lettau's (1967) conclusion that the effects of thermal influence on the steady-state boundary-layer winds can be linearly superimposed on the effects of internal friction is justified.The minimum value of the cross-isobar angle of the surface wind for a given magnitude of the thermal wind vector occurs when that vector points about 345° to the right of the surface geostrophic wind vector and the maximum value occurs when it points at an azimuth of about 120° relative to the surface geostrophic wind vector. The range of values of the cross-isobar angle is almost directly proportional to the magnitude of the thermal wind vector.Hodographs resulting from the assumed variation of the geostrophic wind have approximately the same shape as 24-hour mean hodographs at two locations over the Great Plains.This work is part of a thesis submitted to the University of Wisconsin in partial fulfillment of the requirements for the Ph.D. Degree, written under the supervision of Professor H. Lettau, Department of Meteorology.     

Sedimentology and kinematics of a large, retrogressive growth-fault system in Upper Carboniferous deltaic sediments, western Ireland

Growth faulting is a common feature of many deltaic environments and is vital in determining local sediment dispersal and accumulation, and hence in controlling the resultant sedimentary facies distribution and architecture. Growth faults occur on a range of scales, from a few centimetres to hundreds of metres, with the largest growth faults frequently being under‐represented in outcrops that are often smaller than the scale of feature under investigation. This paper presents data from the exceptionally large outcrops of the Cliffs of Moher, western Ireland, where a growth‐fault complex affects strata up to 60 m in thickness and extends laterally for ≈ 3 km. Study of this Namurian (Upper Carboniferous) growth‐fault system enables the relationship between growth faulting and sedimentation to be detailed and permits reconstruction of the kinematic history of faulting. Growth faulting was initiated with the onset of sandstone deposition on a succession of silty mudstones that overlie a thin, marine shale. The decollement horizon developed at the top of the marine shale contact for the first nine faults, by which time aggradation in the hangingwall exceeded 60 m in thickness. After this time, failure planes developed at higher stratigraphic levels and were associated with smaller scale faults. The fault complex shows a dominantly landward retrogressive movement, in which only one fault was largely active at any one time. There is no evidence of compressional features at the base of the growth faults, thus suggesting open‐ended slides, and the faults display both disintegrative and non‐disintegrative structure. Thin‐bedded, distal mouth bar facies dominate the hangingwall stratigraphy and, in the final stages of growth‐fault movement, erosion of the crests of rollover structures resulted in the highest strata being restricted to the proximity of the fault. These upper erosion surfaces on the fault scarp developed erosive chutes that were cut parallel to flow and are downlapped by the distal hangingwall strata of younger growth faults.     

Trace element distributions in aquatic sediments of Danang – Hoian area, Vietnam

 Distribution of the trace elements Cr, Cu, Ni, Pb and Zn in surficial sediments of the river/sea environment in Danang – Hoian area (Vietnam) was investigated to examine the degree of metal pollution caused by anthropogenic activities. Point sources from domestic and industrial wastes are identified as dominant contributors of trace element accumulation. Surficial sediments of Hoian River show extremely high total concentrations of Cu (Average Concentration 295 μg/g), Ni (AC 112 μg/g), Pb (AC 396 μg/g) and Zn (AC 429 μg/g) that exceed assigned safety levels ER-M. Similarly, the sediments of Han River show high Pb (AC 188 μg/g) and Zn (AC 282 μg/g) contents. In marine sediments of Thanhbinh beach Pb is also enriched (138 μg/g) above guideline levels. In contrast the sediments of the Cude River are dominated by trace element concentrations close to background values. Received: 17 December 1998 · Accepted: 6 May 1999     

A study of volcanogenic exhalation mineralization

This paper considers volcanogenic exhalation mineralization using data from 35 years of observation of fumarole activity during an earlier phase of the posteruptive activity of the Second Cone, which is one of the New Tolbachik volcanoes that were formed during the eruption at the North Vent of the Great Tolbachik Fissure Eruption (Kamchatka, 1975–1976). We describe the main types of mineral associations, identify the key mineral species and the secondary and accessory minerals, as well as the sequence of mineral generation. We provide a summary of minerals and compounds that have been identified in ejecta of fumaroles on the Second Cone.     

Ice flow direction during late Paleozoic glaciation in western Paraná Basin, Brazil

The recent discovery of ice-striated surfaces associated with the late Paleozoic Aquidauana Formation suggests that glaciers coming from southwest Africa reached westernmost parts of the Paraná Basin in central Brazil. Abrasion features were developed by glaciers moving from SSE towards NNW, mainly on an unconsolidated bed. These records expand to about 1,050,000 km², the coverage of the late Paleozoic glaciation in the region of the Paraná Basin in Western Gondwana.

Resumen

A recente descoberta de superfícies estriadas associadas à Formação Aquidauana, de idade permocarbonífera, sugere que as geleiras provenientes do sudoeste da África alcançaram as porções ocidentais da Bacia do Paraná, na região central do Brasil. As feições de abrasão foram geradas pelo deslocamento de geleiras de SSE para NNW, principalmente sobre substrato inconsolidado. Estes novos registros evidenciam que a glaciação neopaleozóica cobriu uma área de pelo menos de 1.050.000 km² na região ocupada pela Bacia do Paraná no Gondwana Ocidental.     

High-Resolution Non-Hydrostatic Simulations of Flash-Flood Episodes with Grid-Nesting and Ice-Phase Parameterization

Summary ?Simulations of two heavy rainfall events south of the Alps have been conducted with a non-hydrostatic model at horizontal resolutions ranging from 40 to 2.5 km. Emphasis is placed on the assessment of two recent model developments: a detailed explicit mixed phase microphysical scheme and a two-way interactive grid nesting method. In the high-resolution simulations, the impact of the ice phase was found to be quite substantial, accelerating the propagation of the surface front and modifying the spatial distribution of the rainfall. Simulations carried out with two-way interactive grid nesting yielded more realistic overall precipitation patterns, particularly at the finest horizontal resolution. Received March 22, 1999/Revised June 28, 1999