Determining rainy season onset and retreat over Nigeria from precipitation amount and number of rainy days

Summary This study assesses the relative efficiency of the use of rainfall amount and rainy days in the determination of rainfall onset and retreat dates in Nigeria based on rainfall data for the period 1961 to 2000. Daily rainfall data were sourced from the archives of the Nigerian Meteorological Services, Oshodi Lagos. The specific locations for which data were collected are: Ibadan, Ilorin, Kaduna and Kano. The method of percentage cumulative mean rainfall values was employed in the determination of the rainfall onset and retreat dates. The results obtained show that both rainfall amount and rainy days are equally effective in the determination of the mean rainfall onset and retreat dates in Nigeria. With regards to the rainfall onset and retreat dates of the individual years however, the method based on the rainy days is more effective than that based on rainfall amount, as the former yielded more realistic dates than the latter. It is thus recommended that studies investigating rainfall onset and retreat dates within a series of individual years in Nigeria, should be based on rainy days rather than rainfall amount.     

Assessment of the atmospheric concentration of pollutants evaporated from the soil

A model for pollutant redistribution in the soil-atmosphere system is suggested for the case of the local pollution of the underlying surface. The vertical migration of soil pollution is described with a convection-diffusion equation in the sorbing medium, supposing an instantaneous equilibrium is established between the pollutant phases in the soil. The Monin-Obukhov similarity theory for the surface atmospheric layer, modified for the case of limited pollution of the underlying surface, is used to parametrize the pollutant transport and dispersion in the atmosphere. A characteristic feature of the model is its ability to calculate the air pollution concentrations over the polluted soil surface. The model was tested on the results of a field experiment with volatile pesticides.     

The effect of organic materials on the mobility and toxicity of metals in contaminated soils

Organic materials such as compost are often proposed as suitable materials for the remediation of contaminated brownfield sites intended for soft end-use. In addition to vitalising the soil, they are also believed to immobilise metals thereby breaking contaminant-receptor pathways and reducing the ecotoxicity of the contaminants. However, some research has demonstrated contradictory effects between composts on metal immobilisation. In the present study, four different composts and a liming product containing organic matter (LimeX70) were tested to examine both their metal retention and toxicity reduction capabilities on three different metal contaminated soils. Leaching tests, a plant growth test with Greek cress (Lepidium sativum), an earthworm (Eisenia fetida) survival and condition test and a bacterial toxicity test using Vibrio fischeri were carried out. The leaching test results showed that spent mushroom compost caused an increase in metal concentration in the leachates, while LimeX70 caused a decrease. The variation in behaviour between different amendments for each soil was high, so a generic conclusion could not be drawn. Toxicity tests showed significant reduction of metal bioavailability and toxicity for Greek cress, earthworms and bacteria. The results also suggest that more research should be undertaken to understand the mechanisms involved in metal complexation using different types of organic matter, in order to optimise the use of organic materials like compost for soil remediation.     

Compositions,sources and depositional environments of organic matter from the Middle Jurassic clays of Poland

The comprehensive biomarker characteristics from previously undescribed Middle Jurassic clays of Poland are presented. The molecular composition of the organic matter (OM) derived from clays of Aalenian to Callovian age has not changed significantly through time. High relative concentrations of many biomarkers typical for terrestrial material suggest a distinct dominance of OM derived from land plants. Increasing concentrations of C₂₉-diaster-13(17)-enes towards the northern part of the basin indicate an increase in terrestrial input. This terrestrial material would have originated from the enhanced transport of organic matter from land situated at the northern bank of the basin, i.e., the Fennoscandian Shield. The organic matter was deposited in an oxic to suboxic environment, as indicated by relatively low concentrations of C₃₃–C₃₅ homohopanes, moderate to high Pr/Ph ratio values, an absence of compounds characteristic for anoxia and water column stratification, such as isorenieratane, aryl isoprenoids and gammacerane, as well as common benthic fauna and burrows. δ¹⁸O measurements from calcitic rostra of belemnites suggest that the mean value of the Middle Jurassic sea-water temperature of the Polish Basin was 13.1 °C. It is suggested that this mirrored the temperature of the lower water column because belemnites are considered here to be necto-benthic. The organic matter from the Middle Jurassic basin of Poland is immature. This is clearly indicated by a large concentration of biomarkers with the biogenic configurations, such as ββ-hopanes, hop-13(18)-enes, hop-17(21)-enes, diasterenes and sterenes. The identification of preserved, unaltered biomolecules like ferruginol, 6,7-dehydroferruginol and sugiol in Protopodocarpoxylon wood samples from these sediments present particularly strong evidence for the presence of immature OM in the Middle Jurassic sediments. Moreover, the occurrence of these polar diterpenoids is important due to the fact that they are definitely the oldest known natural products detected in geological samples.     

Cl,N, C isotopic analysis of common agro-chemicals for identifying non-point source agricultural contaminants

The isotopic compositions of commercially available herbicides were analyzed to determine their respective ¹⁵N, ¹³C and ³⁷Cl signatures for the purposes of developing a discrete tool for tracing and identifying non-point source contaminants in agricultural watersheds. Findings demonstrate that of the agrochemicals evaluated, chlorine stable isotopes signatures range between δ³⁷Cl = −4.55‰ and +3.40‰, whereas most naturally occurring chlorine stable isotopes signatures, including those of road salt, sewage sludge and fertilizers, vary in a narrow range about the Standard Mean Ocean Chloride (SMOC) between −2.00‰ and +1.00‰. Nitrogen stable isotope values varied widely from δ¹⁵N = −10.86‰ to +1.44‰ and carbon stable isotope analysis gave an observed range between δ¹³C = −37.13‰ and −21.35‰ for the entire suite of agro-chemicals analyzed. When nitrogen, carbon and chlorine stable isotope analyses were compared in a cross-correlation analysis, statistically independent isotopic signatures exist suggesting a new potential tracer tool for identifying herbicides in the environment.     

Infrared imagery of a turbulent intrusion in a stratified environment

A time sequence of airborne infrared imagery provides a unique view of phenomena associated with a turbulent tidal intrusion into a stratified bay. During flood tide, cooler water from the Strait of Juan de Fuca is observed to penetrate Sequim Bay (Washington, U.S.V.) as a turbulent jet. After separating from the shoreline, the jet collapses into the stratified middle part of the bay, forming a mushroom-shaped head consisting of a semicircular plunge front and areas of recirculating flow. As the plunge front advances into the estuary, a set of nonlinear internal waves emerges and propagates toward the relatively stagnant southern part of the bay, where they are a potential source of vertical mixing. This range of phenomena is expected based on laboratory studies, but has not been seen previously in a natural setting.