Distribution of elements and minerals between a coal and its overlying sedimentary rocks in a limnic environment

Previous studies have shown that the Pewee coal, which outcrops in the Wartburg Basin in northeast Tennessee (U.S.A.), formed in an upper delta-plain (limnic) environment and had not been subject to marine conditions. Most elemental concentrations decrease upwards, from the base to the top of the coal; however in some locations, several elements show significant increases in concentration at the very top of the coal. Correlation coefficients for elements within the coal and to a lesser degree, the sediments, reflect typical clay minerals. The major mineral phases identified were kaolinite, illite, chlorite, siderite and quartz.Although minor lateral variations in chemical and maceral composition occur, the Pewee coal is relatively homogeneous within the study area. Elements which tend to be soluble in low-pH solutions (especially Ca) may have reacted with fluids coming from the peat and have been transported away from the coal-sediment contact. Chlorite is absent in the coal, perhaps due to its solubility in an acid environment. With these few exceptions, there is little direct evidence that diagenetic processes influenced the movement of elements from the coal into the sediment, or vice versa.The decrease in elemental concentrations upward in the Pewee coal is thought to result from a gradual decrease in the amount of detritus being brought into the Pewee swamp. The increase in abundance of detritus at the top of the coal in some locations suggests a sudden change in environmental conditions, perhaps as the result of the establishment of a new distributary system.     

Volcanic and tectonic evolution of the Northern Antarctic Peninsula—Late Cenozoic to recent

Field investigation together with a number of geochemical petrographical analyses, as well as absolute K-Ar age determinations and geophysical data, allow the recognition of an evolutionary sequence of geodynamic events which have affected the northern region of Antarctic Peninsula and the adjacent islands.A significant volcanic calc-alkaline belt, which developed on the northwestern margin of the Antarctic Peninsula during the Cretaceous to Middle Tertiary, is indicative of active subduction of the Antarctic plate in that area. This activity decreases during the Lower Miocene, giving way to an expansive phase represented by the Bransfield Rift. These extensional processes are dominant during the Pliocene, creating a rift system in southeastern Bransfield towards Larsen. Both the Bransfield and Larsen systems comprise one “fan-like rift system”, associated with the Prince Gustav Rift and the Scotia Arc micro-plate. Ejection of abundant pyroclastic material generated a large plateau of palagonite hyaloclastites of basaltic alkaline composition. During the Pleistocene-Recent, the extensional activity continued, as evidenced by the active volcanic fractures represented in Bransfield by the Deception, Penguin and Bridgeman volcanic centres; in the Prince Gustav Rift by Paulet Islands and others, and in Larsen by the Coley, Seal Nunatak and Argo volcanic centres. The latter is characterized by basaltic olivine-alkaline effusions. These rifts and the continental blocks are affected by a series of fractures with a N60°–70°W strike, which could be directly associated with the Hero Fracture Zone extending northwest of the South Shetland Islands Trench.     

The structural state of iron in oxidized vs. reduced glasses at 1 atm: A57Fe Mössbauer study

A general model for the structural state of iron in a variety of silicate and aluminosilicate glass compositions in the systems Na₂O-Al₂O₃-SiO₂-Fe-O, CaO-Al₂O₃-SiO₂-Fe-O, and MgO-Al₂O₃-SiO₂-Fe-O is proposed. Quenched melts with variable Al/Si and NBO/T (average number of nonbridging oxygens per tetrahedrally coordinated cation), synthesized over a range of temperatures and values of oxygen fugacity, are analyzed with⁵⁷Fe Mössbauer spectroscopy. For oxidized glasses with Fe³⁺/∑Fe>0.50, the isomer shift for Fe³⁺ is in the range ～0.22–0.33 mm/s and ～0.36 mm/s at 298 K and 77 K, respectively. These values are indicative of tetrahedrally coordinated Fe^3?. This assignment is in agreement with the interpretation of Raman, luminescence, and X-ray,K-edge absorption spectra. The values of the quadrupole splitting are ～0.90 mm/s (298 K and 77 K) in the Na-aluminosilicate glasses and compare with the values of 1.3 mm/s and 1.5 mm/s for the analogous Ca- and Mg-aluminosilicate compositions. The variations in quadrupole splittings for Fe³⁺ are due to differences in the degree of distortion of the tetrahedrally coordinated site in each of the systems. The values of the isomer shifts for Fe²⁺ ions in glasses irrespective of Fe³⁺/∑Fe are in the range 0.90–1.06 mm/s at 298 K and 1.0–1.15 mm/s at 77 K. The corresponding range of values of the quadrupole splitting is 1.75–2.10 mm/s at 298 K and 2.00–2.35 mm/s at 77 K. The temperature dependence of the hyperfine parameters for Fe²⁺ is indicative of noninteracting ions, but the values of the isomer shift are intermediate between those values normally attributable to tetrahedrally and octahedrally coordinated Fe²⁺. The assignment of the isomer-shift values of Fe²⁺ to octahedral coordination is in agreement with the results of other spectral studies. For reduced glasses (Fe³⁺/∑Fe≈<0.50), the value of the isomer shift for Fe³⁺ at both 298 K and 77 K increases and is linearly correlated with decreasing Fe³⁺/∑Fe in the range of \(f_{O_2 } \) between 10^?3 and 10^?6 atm when a single quadrupole-split doublet is assumed to represent the absorption due to ferric iron. The increase in value of the isomer shift with decreasing \(f_{O_2 } \) is consistent with an increase in the proportion of Fe³⁺ ions that are octahedrally coordinated. The concentration of octahedral Fe³⁺ is dependent on the \(T - f_{O_2 } \) conditions, and in the range of log \(f_{O_2 } \) between 10^?2.0 and 10^?5 a significant proportion of the iron may occur as iron-rich structural units with stoichiometry similar to that of inverse spinels such as Fe₃O₄, in addition to isolated Fe²⁺ and Fe³⁺ ions.     

A reduced-rank prediction model of stream-channel size response to traditional agricultural land-use practices in southwestern Nigeria

Stream-channel morphologic responses are found to be related to different parameters measuring traditional agricultural land-use patterns and practices in 50 small headwater basins in southwest Nigeria. The problem of intercorrelations among these parameters made it initially difficult to establish their precise channel enlargement effects and to calibrate an impact prediction model. Through factor analysis of the 22 land-use and morphometric parameters, six factors identified as measures of traditional land-use practice, farm size, planting activities, shortened fallow, relief and overland flow, were found to account for 86% of the variance in the data. The factor-defining variables are length of cropping period, areas in short fallow, farm-plot size, length of farm preparation, relief ratio and overland flow. In a multiple regression analysis, only the first three variables were found to be statistically significant in explaining stream-channel morphologic responses. Thus, areas in short fallows, average farm size and length of cropping period adequately described those aspects of the traditional farming practices that affect basin hydrologic and channel responses. Since these variables were orthogonally derived, they formed the basis for the evaluation of the channel impact status of traditional land-use activities. The duplication of information and effects in the original 22-variable full-rank model were removed while utilizing the three-factor reduced model.     

Small-scale heterogeneity and soil-moisture variability in the unsaturated zone

The distribution of water within a soil profile can only be partly explained by the time distribution and rate of surface-water input. Observed differences in soil moisture within the unsaturated zone result from the interaction of surface-water inputs with spatially inhomogeneous soil characteristics. Water which initially percolates vertically is differentially impeded as a result of subtle textural changes in the soil, and is then preferentially retained in such zones of transition, causing large differences in soil-water content to occur. The scale of this vertical variability is of tenths of metres, whilst lateral variability of soil moisture reflects textural changes over a few metres. The observed influence of small-scale heterogeneity on soil-water content suggests that the conventional assumptions of isotropicity and homogeneity of the textural and hydraulic properties of porous media used in drainage basin and hillslope hydrological models need scrutiny, even for single stratigraphic units.     

Changes in the shape of the circumpolar vortex due to heating from above

Summary Based on model considerations it is shown that, under certain assumptions, zonalization of tropospheric circulation may be expected in the region of the auroral oval as a result of heat released at the time energetic electrons penetrate from the Sun into the lower stratosphere.

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STATISTICAL EVALUATION OF MT AND AMT METHODS APPLIED TO A BASALT-COVERED AREA IN SOUTHEASTERN ANATOLIA,TURKEY*

The efficacy of the magnetotelluric and audiomagnetotelluric (MT/AMT) methods for detailing the structure of a hypothetical geological section is investigated by using the singular value decomposition (SVD) technique. The section is representative of southeastern Turkey, which is mostly covered by basalt and is a prime area for oil exploration. One of the geological units, the Germav shale at a depth of 600 m, is a problem layer for electromagnetic surveys because of its very low resistivity (on average 3 Ωm) and highly variable thickness across the area (200–900 m). In the MT frequency range (0.0004–40 Hz) its total conductance—or, since its resistivity is known from resistivity log information, its thickness—is the best resolved model parameter. The total depth to the Germav shale and the resistivity of the Cambrian/Precambrian basement are the marginally resolved parameters. In the AMT frequency range (4–10000 Hz) the resistivity of the surface basalt layer strongly affects the resolution of the other, less important, model parameters which are the total depth to the Germav shale and the total conductance of the Germav shale. The errors in the measurements determine the number of model parameters resolvable, and are also important for interpretation of the geological model parameters to within a desired accuracy. It is shown that statistical evaluation of the MT and/or AMT interpretations by using an SVD factorization of the sensitivity matrix can be helpful to define the importance of some particular stage of the interpretation, and also provides a priori knowledge to plan a proposed survey. Arrangements of MT and AMT observations, together with some Schlumberger resistivity soundings, on a large grid will certainly provide three-dimensional detailed information of the deep geoelectric structure of the area.     

Geochemical and petrological relations in some deccan basalts, Western Maharashtra, India

Petrographic and geochemical data are given for some basaltic rocks from the Koynaghat, Ambaghat and Panvel sections of the western Deccan volcanic province. This study confirms geochemical features established earlier for the Deccan basalts but brings out minor additional characters. Mineralogical and major-element compositions of the basaltic flows from the Koyna and Panvel sections indicate tholeiitic affinity; the Ambaghat flows exhibit a slight affinity towards alkali basalt. Rare earth element (REE) distribution patterns and trace-element abundances suggest minor fractionation of olivine and plagioclase during the evolution of the flows. The general similarity of chemical and mineralogical features over a wide area and the lack of conspicuous inter-element relationships suggest that the flows reflect the combined effects of partial melting, minor mineral fractionation and selective crustal contamination.