Abnormal composition of carbon isotopes in underground alkaline waters of Kuzbass

The first data on abnormally high δ¹³С values in hydrocarbonates (НСО ₃^-) dissolved in underground waters of coal deposits of Kuzbass (up to +30.9‰) are reported. It is shown that such an unusual isotope composition of waters results from the long, strictly directed interaction in the water–rock–gas–organic material system occurring under the conditions of hindered water exchange. Extensive fractionation of C isotopes is the result of the evolution of the water–rock–gas–coal system after penetration of infiltration waters into the coal deposits and their long interaction with all these components, rather than metamorphism of organic material upon its transformation into coal. With respect to such an approach, the isotope composition of dissolved C may indicate the duration of the evolution in the water–rock–gas–organic material system.     

Influence of long-period oscillations on the development of droughts in Northern Eurasia

Doklady Earth Sciences - Estimates of the influence of the Atlantic long-period oscillation (ALO) on the formation of droughts in Northern Eurasia were obtained using the results of numerical...     

Disseminated gold–sulfide mineralization at the Zhaima deposit,eastern Kazakhstan

The Zhaima gold–sulfide deposit is located in the northwestern part of the West Kalba gold belt in eastern Kazakhstan. The mineralization is hosted in Lower Carboniferous volcanic and carbonate rocks formed under conditions of marginal-sea and island-arc volcanic activity. The paper considers the mineralogy and geochemistry of primary gold–sulfide ore and Au-bearing weathering crusts. Au-bearing arsenopyrite–pyrite mineralization formed during only one productive stage. Disseminated, stringer–disseminated, and massive rocks are enriched in Ti, Cr, V, Cu, and Ni, which correspond to the mafic profile of basement. The main ores minerals are represented by finely acicular arsenopyrite containing Au (up to few tens of ppm) and cubic and pentagonal dodecahedral pyrite with sporadic submicroscopic inclusions of native gold. The sulfur isotopic composition of sulfides is close to that of the meteoritic standard (δ³⁴S =–0.2 to +0.2). The ⁴⁰Ar/³⁹Ar age of three sericite samples from ore veinlets corresponds to the Early Permian: 279 ± 3.3, 275.6 ± 2.9, and 272.2 ± 2.9 Ma. The mantle source of sulfur, ore geochemistry, and spatial compatibility of mineralization with basic dikes allow us to speak about the existence of deep fluid–magmatic systems apparently conjugate with the Tarim plume.     

Deposition conditions and distribution features of native gold individuals in the veins of the Tokur mesothermal deposit,Russia

The paper discusses factors in the deposition and concentration of native gold and the spatial distribution of its individuals within the sufide-poor gold–quartz veins at the mesoabyssal Tokur deposit. The major factors in deposition of gold were sealing of the hydrothermal system, a sudden drop in fluid pressure, and repeated immiscibility in the fluid. Native gold was deposited in relation to initial acts of prolonged and discrete opening and preopening of cavities in three mineral assemblages of the productive association II. Most native gold individuals with a visible size of 0.1–1.5 mm were together with the early generation of quartz 2 on cavity walls adjacent to altered rocks. This is caused by the high content of Au complexes in initial hydrothermal solutions favoring rapid oversaturation during cavity formation. Gold fills interstices between grains of quartz 2 throughout the deposit and mineral assemblages. The vertical-flow distribution of gold has been established in economic veins; the upper and middle levels are enriched in gold, and samples with the greatest gold grade of 100–500 g/t or higher are concentrated there. This is caused both by the predominance of mineral association II at these levels and probable natural flotation of gold grains contained in the gold–gas associate for immiscibility of the hydrothermal fluid at the second stage of the ore-forming process.     

Geology and mineralogy of the Alakha spodumene granite porphyry deposit,Gorny Altai,Russia

The Alakha lithium–tantalum deposit in the southern Altai, Russia, is represented by a stock of spodumene-bearing granite porphyry localized in the Kalba–Narym–Koktogai lithium–tantalum rare-metal granitic belt, unique in extent (more than 1000 km). This belt is a part of the Altai accretionary–collisional system. Judging from forecasting, the Alakha deposit can be regarded as an uneroded proxy of a pegmatite body both in dimensions and mean Li₂O and Ta₂O₅ contents (0.98 wt % and 114 ppm, respectively); however, the oregenerating potential of this deposit remains insufficiently studied and had not yet been claimed. In this paper, we attempt to fill this gap with a detailed mineralogical study, which allows us to provide insights into the crystallization of Li-bearing high-silicic magma and redistribution of components during magmatic and postmagmatic processes. Accessory mineral assemblages in muscovite–spodumene–K-feldspar granite porphyry and muscovite albitite—the main petrographic rock varieties of the Alakha stock—turned out to be almost identical. A significant similarity in the chemistry of major rock-forming minerals is established for spodumene granite porphyry of the Alakha stock and spodumene pegmatites from large deposits, which makes it possible to suggest that they are close in the petrogenetic mechanism of their formation. The mineral assemblages of muscovite albitite in the apical portion of the Alakha stock are connected by gradual transition with those of spodumene granite porphyry. Such a transition is caused by postmagmatic metasomatic alteration of the latter.     

IR photometry and models for the dust envelopes of two carbon stars

The results of JHKLM photometry of two carbon stars are presented: the irregular variable NQ Cas and the Mira star BD Vul. Data on the mean fluxes supplemented with mid-IR observations with the IRAS, AKARI, andWISE satellites are used to compute spherically symmetrical model dust envelopes for the stars, consisting of particles of amorphous carbon and silicon carbide. The optical depth in the visible for the comparatively cool dust envelope of BD Vul, with a dust temperature at its inner boundary T₁ = 610 K, is fairly low: τ_V = 0.13. The dust envelope of NQ Cas is appreciably hotter (T₁ = 1550 K), and has τ_V = 0.32. The estimated mass-loss rates are 1.5 × 10^?7M_⊙/yr for NQ Cas and 5.9 × 10^?7M_⊙/yr for BD Vul.     

<Emphasis Type="Italic">Deepwater Horizon</Emphasis> Oil Spill Impacts on Salt Marsh Fiddler Crabs (<Emphasis Type="Italic">Uca</Emphasis> spp.)

The Deepwater Horizon oil spill was the largest marine oil spill in US waters to date and one of the largest worldwide. Impacts of this spill on salt marsh vegetation have been well documented, although impacts on marsh macroinvertebrates have received less attention. To examine impacts of the oil spill on an important marsh invertebrate and ecosystem engineer, we conducted a meta-analysis on fiddler crabs (Uca spp.) using published sources and newly available Natural Resources Damage Assessment (NRDA) and Gulf of Mexico Research Initiative (GoMRI) data. Fiddler crabs influence marsh ecosystem structure and function through their burrowing and feeding activities and are key prey for a number of marsh and estuarine predators. We tested the hypothesis that the spill affected fiddler crab burrow density (crab abundance), burrow diameter (crab size), and crab species composition. Averaged across multiple studies, sites, and years, our synthesis revealed a negative effect of oiling on all three metrics. Burrow densities were reduced by 39 % in oiled sites, with impacts and incomplete recovery observed over 2010–2014. Burrow diameters were reduced from 2010 to 2011, but appeared to have recovered by 2012. Fiddler crab species composition was altered through at least 2013 and only returned to reference conditions where marsh vegetation recovered, via restoration planting in one case. Given the spatial and temporal extent of data analyzed, this synthesis provides compelling evidence that the Deepwater Horizon spill suppressed populations of fiddler crabs in oiled marshes, likely affecting other ecosystem attributes, including marsh productivity, marsh soil characteristics, and associated predators.     

Effects of heavy metal (Pb) concentration on some growth parameters of plants grown in lead polluted soil under organic fertilizer amendment

This study investigated morphological variation and biomass accumulation that occurred in Sida acuta and Chromolaena odorata plants grown in lead polluted soil under organic fertilizer amendment. The study was carried out in the screen house at the Biological Gardens of the Obafemi Awolowo University, Ile-Ife, Osun State. The experiment was a factorial combination of one heavy metal (Pb) at five levels of concentration (0, 200, 400, 800 and 1,000 mg/kg) in a completely randomized design, and were replicated three times for each of the two plants and two levels (0 g/kg and 9.4 g/kg) of organic fertilizer (OBD-Plus). Each pot was filled with 5 kg of air-dried and sieved soil and placed on a plastic tray for the collection of excess water. Two weeks after planting, seedlings of uniform height were transplanted from the nursery to experimental pots at the rate of one seedling per pot and grown for 10 weeks. The growth parameters of the plants were biomonitored for 7 weeks. After 10 weeks of treatment, the plants were harvested and dried to calculate the biomass accumulation. The two plant species performed better under fertilizer application than without it. For each of the plant species the growth parameters decreased as the levels of Pb concentration increased. Furthermore, the plants' biomass decreased significantly (p<0.05) as the levels of Pb concentration increased. The organic fertilizer helped to improve the plants' performance in lead-polluted soil.