A geochemical and geophysical approach to derive a conceptual circulation model of CO2-rich mineral waters: A case study of Vilarelho da Raia, northern Portugal

The Vilarelho da Raia-Chaves region, located in northern Portugal adjacent to the Spanish border, is characterized by both hot and cold CO₂-rich mineral waters issuing from springs and drilled wells. The present paper updates the conceptual circulation model of the Vilarelho da Raia cold CO₂-rich mineral waters. Vilarelho da Raia mineral waters, dominated by Na and HCO₃ ions, have formed mainly by interaction with CO₂ of deep-seated mantle origin. The δ ¹⁸O, δ ²H and ³H values indicate that these waters are the result of meteoric waters infiltrating into Larouco Mountain, NW of Vilarelho da Raia, circulating at shallow depths in granitic rocks and moving into Vilarelho da Raia area. The conceptual geochemical and geophysical circulation model indicates that the hot and cold CO₂-rich mineral waters of Chaves (76 °C) and Vilarelho da Raia (17 °C) should be considered manifestations of similar but not the same geohydrological systems. Electronic Publication     

Semantic Expansion of Geographic Web Queries Based on Natural Language Positioning Expressions

The need for better Web search tools is getting increasing attention nowadays. About 20% of the queries currently submitted to search engines include geographic references. Thus, it is particularly important to work with the semantics of such queries, both by understanding the terminology and by recognizing geographic references in natural language text. In this paper, we explore the use of natural language expressions, which we call positioning expressions, to perform geographic searches on the Web, without resorting to geocoded data or gazetteers. Such positioning expressions denote the location of a subject of interest with respect to a landmark. Our approach leads to a query expansion technique that can be explored by virtually any keyword‐based search engine. Results obtained in our experiments show an expressive improvement over the traditional keyword‐based search and a potential path for tackling many kinds of common geographic queries.     

Integrated modelling for water quality management in a eutrophic reservoir in south-eastern Portugal

The Enxoé Reservoir was built in 1998. Since 2000, it has exhibited frequent high chlorophyll-a concentrations, reaching a geometric mean three times higher than the national limit for eutrophication, presenting the reservoir with the highest eutrophic state in Portugal. Toxic algal blooms have also often been observed, which pose serious challenges to water managers, as the reservoir is used for potable water production (25,000 inhabitants). The objective of this study was to implement a reservoir model (CE-QUAL-W2), with inputs from a watershed model (SWAT), in order to represent the actual reservoir state and to test management measures to reduce its trophic level and algal bloom concentration peaks. The integrated model was used to depict the origin of its trophic status. Simulations were also compared to measured data at the reservoir surface (water level, nitrate, orthophosphate, suspended solids, and oxygen) and in water profiles (temperature, oxygen). The model was able to represent stratification and thermocline depths, as well as the actual chlorophyll-a and dissolved oxygen concentrations. The model results showed that internal phosphorus load from deposited sediments was an important factor in fuelling the algal blooms. This process occurs predominantly in summer, when stratification takes place and aeration is reduced, promoting anoxic conditions in the bottom waters. Since the reservoir is relatively shallow (average 5 m), released phosphorus is then easily able to reach the photic zone in most parts of the reservoir, where it is consumed. Different management scenarios were tested, suggesting that a mesotrophic level could barely be reached and maintained simply by reducing the nutrient loads (both external and internal). It is suggested that only an increase in the reservoir dam height could produce a mesotrophic level, averting anoxia by blocking the release of phosphorus from sediments to the photic zone. Future work should focus on a cost–benefit analysis to test the feasibility of each of the proposed scenarios, taking advantage of the integration strategy to assess where in the watershed load reductions would be most effective.     

Free-Phase Gas Detection in Groundwater Wells via Water Pressure and Continuous Field Parameters

Detection of free-phase gas (FPG) in groundwater wells is critical for accurate assessment of dissolved gas concentrations and the occurrence of FPG in the subsurface, with consequent implications for understanding groundwater contamination and greenhouse gas emissions. However, identifying FPG is challenging during routine groundwater monitoring and there is poor agreement on the best approach to detect the occurrence of FPG in groundwater. In this study, laboratory experiments in a water column were designed to mimic nonflowing and flowing conditions in a groundwater well to evaluate how the presence of FPG affects water pressure and commonly used continuous field parameters. The laboratory results were extrapolated to interpret field data at an abandoned exploration well with episodic release of free-gas CO₂. The FPG effect on water pressure varied between flowing and nonflowing wells, and depending on whether the FPG was above or below the sensor. Electrical conductivity values were decreased and/or behaved erratically when FPG was present in the water column. Findings from this study have shown that the combined measurement of water pressure, electrical conductivity, and total dissolved gas pressure can provide information about the occurrence of FPG in groundwater wells. Measurement of these parameters at different depths can also provide information about relative depths and amounts of FPG within the well water column. This approach can be used for long-term monitoring of groundwater gases, managing gas-locking in production wells with gassy groundwater, and measuring fugitive greenhouse gas emissions from groundwater wells.     

Soil degradation in central Spain due to sheet water erosion by low‐intensity rainfall events

Runoff and sediment lost due to water erosion were recorded for 36 (1 m²) plots with varying types of vegetative cover located on sloping gypsiferous fields in the South of Madrid. 75% of the events had maximum 30‐minute intensity (I₃₀) less than 10 mm h^?1 in the period studied (1994–2005). As for the vegetative cover, maximum correlation between runoff and soil loss was found in the least protected plots (0–40% cover) during the most intense rainfall events; however, a significant positive correlation was also observed in plots with greater coverage (40–60%). If coverage exceeded 60%, rainfall erosivity declined. The average amount of sediment produced in high‐intensity events was significantly greater (approximately 7 g m^?2 per I₃₀ event >10 mm h^?1) than that produced in the rest of the moderate‐intensity events (approximately 3 g m^?2 per I₃₀ event <10 mm h^?1), but due to the high rate of occurrence of the latter throughout the year sediment loss during the period studied totaled 128 g m^?2. By comparison, only 40 g m^?2 was produced by the I₃₀ events greater than 10 mm h^?1. Even though the amount of soil lost is relatively insignificant from a quantitative standpoint, the organic matter content lost in the sediment (six times more than in the soil) is a permanent loss that threatens the development of the surface of the soil in this area when the vegetative cover is less than 40%. The soil here experiences a chronic loss of 0·02 mm annually as a consequence of frequent, moderate events, in addition to any loss produced by extraordinary events, which, though less frequent, are much more erosive. If moderate events are ignored, an important part of soil loss will be lost in the long run. Copyright © 2007 John Wiley & Sons, Ltd.     

Evaluation and modeling of runoff and sediment yield for different land covers under simulated rain in a semiarid region of Brazil

This paper quantifies the runoff and sediment yield for four different land covers in a semiarid region of Brazil. The WESP model, a distributed, event-oriented runoff-erosion model, was applied and its physical parameters, N_s and K_R, were adjusted based on observed runoff and sediment yield data using simulated rainfall with an average intensity of 53 mm h^-1. The sediment yield obtained was 53.02 kg ha^-1 (caatinga vegetation), 231.96 kg ha^-1 (bare soil), 309.75 kg ha^-1 (beans), and 847.38 kg ha^-1(corn). The results showed that caatinga cover yields the lowest erosion and runoff when compared to the other treatments. The results also show that the sediment yield and runoff values simulated with N_s, K_I, and K_R parameters were well calibrated, within acceptable deviations. The caatinga vegetation was more effective in protecting the soil, when compared to the other types of coverage. The beans and corn covers had the highest values of runoff and sediment yield, even higher than those observed for bare soil.