Marine Chemistry in the Coastal Environment: Principles,Perspective and Prospectus

Marine chemistry of the coastal environment starts with principles of rock weathering that use carbonic acid to mobilize elements, only some of which comprise the majority of sea salt. The principle reason is reverse weathering, extensively represented in coastal waters, and returns most elements to newly formed colloids or minerals while recycling carbon dioxide to the atmosphere. This includes the deeper ocean expanse of sediment diagenesis, plus hydrothermal plumes and attendant low-temperature basalt alteration. Within the estuarine and extended shelf regimes, both conservative and non-conservative processes can be distinguished and modeled to determine proportions of weathered elements transmitted to the sea or consumed by reverse weathering. Conceptually, the steady-state processes that lead to the composition of seawater can be viewed as heterogeneous equilibria between dissolved constituents and solid mineral products taking hundreds of millennia. However, initial processes in the estuarine and coastal environment are characterized by shorter term scavenging associated with inorganic and organic colloids. These recycle both carbon and trace elements on timescales commensurate with estuarine flushing and coastal exchange with the ocean. The natural uranium and thorium decay series provide powerful tools for quantifying the rates of estuarine processes, including those within groundwater and the subterranean estuary. In the future, new mass spectrometric and nuclear magnetic resonance techniques will help to define the molecular nature of newly formed estuarine colloids as has been done for dissolved organic matter. As the coastal environment undergoes the forces of climate change in the form of warming and sea level rise, future research should address how these will impact chemistry of the coastal environment as a net source or sink of carbon dioxide and associated organic material.     

Assessment of soil erosion in a tropical mountain river basin of the southern Western Ghats,India using RUSLE and GIS

Revised Universal Soil Loss Equation(RUSLE) model coupled with transport limited sediment delivery(TLSD) function was used to predict the longtime average annual soil loss, and to identify the critical erosion-/deposition-prone areas in a tropical mountain river basin, viz., Muthirapuzha River Basin(MRB; area=271.75 km~2), in the southern Western Ghats, India. Mean gross soil erosion in MRB is 14.36 t ha~(-1) yr~(-1), whereas mean net soil erosion(i.e., gross erosion-deposition) is only 3.60 t ha~(-1) yr~(-1)(i.e., roughly 25% of the gross erosion). Majority of the basin area(~86%) experiences only slight erosion(5 t ha~(-1) yr~(-1)), and nearly 3% of the area functions as depositional environment for the eroded sediments(e.g., the terraces of stream reaches, the gentle plains as well as the foot slopes of the plateau scarps and the terrain with concordant summits). Although mean gross soil erosion rates in the natural vegetation belts are relatively higher, compared to agriculture, settlement/built-up areas and tea plantation, the sediment transport efficiency in agricultural areas and tea plantation is significantly high,reflecting the role of human activities on accelerated soil erosion. In MRB, on a mean basis, 0.42 t of soil organic carbon(SOC) content is being eroded per hectare annually, and SOC loss from the 4th order subbasins shows considerable differences, mainly due to the spatial variability in the gross soil erosion rates among the sub-basins. The quantitative results, on soil erosion and deposition, modelled using RUSLE and TLSD, are expected to be beneficial while formulating comprehensive land management strategies for reducing the extent of soil degradation in tropical mountain river basins.     

Enhanced residual mean circulation during the evolution of split type sudden stratospheric warming in observations and model simulations

Residual mean circulation changes during the evolution of sudden stratospheric warming (SSW) are investigated by composite analyses of 76 major warming events identified in a present day simulation performed with a coupled ocean–troposphere–stratosphere model from 299 winters. Their dynamical signatures are compared with the 17 SSW events identified from 35 years of Era-Interim data. The main difference is that, relative frequency of simulated SSW events is smaller than that obtained from reanalysis. SSW events are classified as displacement or split events based on the geopotential field values at 10 hPa. The geopotential field values identify 10 and 3 split events in simulation and observation respectively. The model quite accurately simulates some of the dynamical features associated with the major SSW. Residual mean circulation induced by EP-flux divergence, sum of advection and residual forcing are stronger in split events than in displacement type SSW has been confirmed by both simulation and observation. Moreover, the contribution of EP-flux divergence or planetary wave forcing is larger than the contribution of other types of forcing.     

China’s national carbon emissions trading scheme: lessons from the pilot emission trading schemes,academic literature,and known policy details

Upon completion, China’s national emissions trading scheme (C-ETS) will be the largest carbon market in the world. Recent research has evaluated China’s seven pilot ETSs launched from 2013 on, and academic literature on design aspects of the C-ETS abounds. Yet little is known about the specific details of the upcoming C-ETS. This article combines currently understood details of China’s national carbon market with lessons learned in the pilot schemes as well as from the academic literature. Our review follows the taxonomy of Emissions Trading in Practice: A Handbook on Design and Implementation (Partnership for Market Readiness & International Carbon Action Partnership. (2016). Retrieved from www.worldbank.org): The 10 categories are: scope, cap, distribution of allowances, use of offsets, temporal flexibility, price predictability, compliance and oversight, stakeholder engagement and capacity building, linking, implementation and improvements.

Key policy insights

• Accurate emissions data is paramount for both design and implementation, and its availability dictates the scope of the C-ETS.

• The stakeholder consultative process is critical for effective design, and China is able to build on its extensive experience through the pilot ETSs.

• Current policies and positions on intensity targets and Clean Development Mechanism (CDM) credits constrain the market design of the C-ETS.

• Most critical is the nature of the cap. The currently discussed rate-based cap with ex post adjustment is risky. Instead, an absolute, mass-based emissions cap coupled with the conditional use of permits would allow China to maintain flexibility in the carbon market while ensuring a limit on CO₂ emissions.

     

Geological and geophysical studies of the Agoudal impact structure (Central High Atlas,Morocco): New evidence for crater size and age

Since the discovery of shatter cones (SCs) near the village of Agoudal (Morocco, Central High Atlas Mountains) in 2013, the absence of one or several associated circular structures led to speculation about the age of the impact event, the number, and the size of the impact crater or craters. Additional constraints on the crater size, age, and erosion rates are obtained here from geological, structural, and geophysical mapping and from cosmogenic nuclide data. Our geological maps of the Agoudal impact site at the scales of 1:30,000 (6 km²) and 1:15,000 (2.25 km²) include all known occurrences of SCs in target rocks, breccias, and vertical to overturned strata. Considering that strata surrounding the impact site are subhorizontal, we argue that disturbed strata are related to the impact event. Three types of breccias have been observed. Two of them (br1‐2 and br2) could be produced by erosion–sedimentation–consolidation processes, with no evidence for impact breccias, while breccia (br1) might be impact related. The most probable center of the structure is estimated at 31°59′13.73?N, 5°30′55.14?W using the concentric deviation method applied to the orientation of strata over the disturbed area. Despite the absence of a morphological expression, the ground magnetic and electromagnetic surveys reveal anomalies spatially associated with disturbed strata and SC occurrences. The geophysical data, the structural observations, and the area of occurrence of SCs in target rocks are all consistent with an original size of 1.4–4.2 km in diameter. Cosmogenic nuclide data (³⁶Cl) constrain the local erosion rates between 220 ± 22 m Ma^?1 and 430 ± 43 m Ma^?1. These erosion rates may remove the topographic expression of such a crater and its ejecta in a time period of about 0.3–1.9 Ma. This age is older than the Agoudal iron meteorite age (105 ± 40 kyr). This new age constraint excludes the possibility of a genetic relationship between the Agoudal iron meteorite fall and the formation of the Agoudal impact site. A chronolgy chart including the Atlas orogeny, the alternation of sedimentation and erosion periods, and the meteoritic impacts is presented based on all obtained and combined data.     

In situ U–Pb analysis of shocked zircon from the Charlevoix impact structure,Québec,Canada

Laser ablation inductively coupled plasma‐mass spectrometry (LA‐ICP‐MS) U–Pb geochronology of shocked zircon grains in a vesicular‐fluidal impact melt rock from the ≥54 km Charlevoix impact structure, Québec, Canada, suggests an Ordovician to Silurian age of 450 ± 20 Ma for the impact. This age is anchored by concordant U–Pb results of ~450 Ma for a U‐rich, cryptocrystalline zircon grain in the melt rock, interpreted as a recrystallized metamict zircon crystal; the U–Th–Pb system of the metamict grain was seemingly chronometrically reset by the Charlevoix impact, but withstood later tectonometamorphic events. The new zircon age for Charlevoix is in agreement with a stratigraphically constrained Late Ordovician maximum age of ~453 Ma and corroborates earlier suggestions that the impact occurred most likely in the Ordovician, and not ~100 Myr later, as indicated by previous K/Ar and ⁴⁰Ar/³⁹Ar geochronologic results. The latter may reflect postimpact thermal overprint of impactites during the Salinian (Late Silurian to Early Devonian) and/or Acadian (Late Devonian) orogenies. U–Pb geochronology of zircon crystals in anorthosite exposed in the central uplift of the impact structure yielded a Grenvillian crystallization age of 1062 ± 11 Ma. The preferred Ordovician age for the Charlevoix impact structure, which is partially overthrusted by the Appalachian front, suggests the impact occurred during a phase of Taconian tectonism and an episode of enhanced asteroid bombardment of the Earth. Our results, moreover, demonstrate that (recrystallized) metamict zircon grains may be of particular interest in impact geochronology.     

Ekman drift and vortical structures

In this article, the authors study the influence of a constant wind on the displacement of a vortex. The well known Ekman current develops in the surface layer and is responsible for a transport perpendicular to the wind: the Ekman drift.An additional process is, however, evidenced, whose importance is as strong as the Ekman drift. There indeed exists a curl of the wind-driven acceleration along isopycnic surfaces when they are spatially variable (they enter and leave the depth where the wind stress acts), which generates potential vorticity anomalies. This diabatic effect is shown to generate potential vorticity anomalies which acts on the propagation of vortical waves and non linear vortices.It is shown that this effect drastically reduces the effect of the Ekman drift for linear waves and surface intensified vortices, while extending its effect to subsurface vortices. It also generates along wind propagation, whose sign depends on the vortex characteristics.     

The Use of LiDAR in Digital Surface Modelling: Issues and Errors

Modelling and extracting 3D geographical data presents numerous challenges that require continual research to attempt to evolve an efficient, reliable and accurate solution. LiDAR data capture and analysis has become a preferred acquisition choice for elevation data because the resulting quality and level of detail far exceeds traditional methods for large survey areas. As with any data collection system, LiDAR is prone to errors. Analysing these errors, ascertaining causes and producing error correction strategies is vital if accurate and confident results are to be obtained. Eight years of LiDAR datasets (from 1998 to 2005) have been closely analysed for a large coastal area of South Wales. This article provides a detailed and accurate summary of the identified LiDAR data issues and subsequent errors which affect the accuracy of end products such as Digital Surface Models (DSMs).