Rutile occurrence and trace element behavior in medium-grade metasedimentary rocks: example from the Erzgebirge, Germany

Metamorphic textures in medium-grade (~500–550°C) metasedimentary rocks from the Erzgebirge give evidence of prograde rutile crystallization from ilmenite. Newly-crystallized grains occur as rutile-rich polycrystalline aggregates that pseudomorph the shape of the ilmenites. In-situ trace element data (EMP and SIMS) show that rutiles from the higher-grade samples record large scatter in Nb content and have Nb/Ti ratios higher than coexisting ilmenite. This behavior can be predicted using prograde rutile crystallization from ilmenite and indicates that rutiles are reequilibrating their chemistry with remaining ilmenites. On the contrary, rutiles from the lowest grade samples (~480°C) have Nb/Ti ratios that are similar to the ones in ilmenite. Hence, rutiles from these samples did not equilibrate their chemistry with remaining ilmenites. Our data suggest that temperature may be one of the main factors determining whether or not the elements are able to diffuse between the phases and, therefore, reequilibrate. Newly-crystallized rutiles yield temperatures (from ~500 to 630°C, Zr-in-rutile thermometry) that are in agreement with the metamorphic conditions previously determined for the studied rocks. In quartzites from the medium-grade domain (~530°C), inherited detrital rutile grains are detected. They are identified by their distinct chemical composition (high Zr and Nb contents) and textures (single grains surrounded by fine grained ilmenites). Preliminary calculation, based on grain size distribution of rutile in medium-grade metapelites and quartzites that occur in the studied area, show that rutiles derived from quartzites can be anticipated to dominate the detrital rutile population, even if quartzites are a minor component of the exposure.     

An integrated object-based image analysis and CA-Markov model approach for modeling land use/land cover trends in the Sarab plain

The present paper is an attempt to integrate a semi-automated object-based image analysis (OBIA) classification framework and a cellular automata-Markov model to study land use/land cover (LULC) changes. Land use maps for the Sarab plain in Iran for the years 2000, 2006, and 2014 were created from Landsat satellite data, by applying an OBIA classification using the normalized difference vegetation index, salinity index, moisture stress index, soil-adjusted vegetation index, and elevation and slope indicators. The classifications yielded overall accuracies of 91, 93, and 94% for 2000, 2006, and 2014, respectively. Finally, using the transition matrix, the spatial distribution of land use was simulated for 2020. The results of the study revealed that the number of orchards with irrigated agriculture and dry-farm agriculture in the Sarab plain is increasing, while the amount of bare land is decreasing. The results of this research are of great importance for regional authorities and decision makers in strategic land use planning.     

Petrography and geochemistry of manganiferous rocks in the Mankwadzi area in the southern Kibi‐Winneba metavolcanic belt,Ghana: Implications for genesis of Mn formations in the Birimian of West Africa

Manganiferous rocks in the Mankwadzi area in the southernmost portion of the Kibi‐Winneba metavolcanic belt, one of several Mn occurrences in the Paleoproterozoic Birimian of Ghana, are hosted in hornblende schist and amphibolite. These rocks are, in places, intruded by hornblende dyke. In outcrop, the manganiferous rocks appear to be conformable with the host schist and amphibolite, are macroscopically dark, fine‐grained and structurally massive to distinctly banded. Observed alternating light and dark occasionally macro‐folded bands suggest post‐depositional deformation of both light and dark bands. Microscopic observations revealed that the light bands are dominantly Si‐rich and the dark bands mainly of opaque minerals. Whole rock analyses of the manganiferous rocks show high contents of MnO (16.75–27.4 wt%) suggesting that the opaque minerals are likely rich in Mn. The analyzed rock samples show moderate to strong enrichments in light rare earth elements compared to heavy rare earth elements. Whereas the manganiferous rocks show perceptibly negative Eu anomaly, host hornblende schist and hornblende dyke do not. Eu anomaly in amphibolite samples is, however, uncertain as the three samples analyzed gave positive, negative and no Eu anomalies. Based on the field characteristics, microscopic and geochemical features, we suggest that the Mn occurrence in the Mankwadzi area originated via sedimentary deposition and was later modified by metamorphism, hydrothermal and/or supergene processes similar to manganiferous occurrences at Nsuta and Tambao in the Birimian of West Africa.     

Oceanic fine structure

Abstract

Measurements by free fall instruments, in the San Diego Trough, the Florida Current, and the central Pacific, reveal the detailed structure of the vertical component of the oceanic temperature gradient. The temperature changes are concentrated into regions on the order of a meter thick wherein the measured gradients are often more than ten times the average gradient. The horizontal extent of the regions of high gradient is greater than 750 meters in the seasonal thermocline off San Diego, but is only a few hundred meters at depths greater than 400 meters.

Fine scale measurements show that the layers of high gradient consist of even finer fluctuations in gradient which are only a few centimeters thick. Time scales of the thinnest of these regions of high gradient are of the order of five minutes. The data also yields an estimate of the entropy generation. According to the results of an idealized model relating entropy generation to the turbulent heat transport, only 240 to 700 ergs per cm.² per sec were transported in a 25 meter vertical section measured in the San Diego Trough. This value compared with 3600 ergs per cm.² per sec estimated from the mean gradient and an eddy coefficient of 1 cm.² per sec.     

Molecular and isotopic partitioning of low-molecular-weight hydrocarbons during migration and gas hydrate precipitation in deposits of a high-flux seepage site

Detailed knowledge of the extent of post-genetic modifications affecting shallow submarine hydrocarbons fueled from the deep subsurface is fundamental for evaluating source and reservoir properties. We investigated gases from a submarine high-flux seepage site in the anoxic Eastern Black Sea in order to elucidate molecular and isotopic alterations of low-molecular-weight hydrocarbons (LMWHC) associated with upward migration through the sediment and precipitation of shallow gas hydrates. For this, near-surface sediment pressure cores and free gas venting from the seafloor were collected using autoclave technology at the Batumi seep area at 845 m water depth within the gas hydrate stability zone.Vent gas, gas from pressure core degassing, and from hydrate dissociation were strongly dominated by methane (> 99.85 mol.% of ∑[C₁–C₄, CO₂]). Molecular ratios of LMWHC (C₁/[C₂ + C₃] > 1000) and stable isotopic compositions of methane (δ¹³C = ? 53.5‰ V-PDB; D/H around ? 175‰ SMOW) indicated predominant microbial methane formation. C₁/C₂₊ ratios and stable isotopic compositions of LMWHC distinguished three gas types prevailing in the seepage area. Vent gas discharged into bottom waters was depleted in methane by > 0.03 mol.% (∑[C₁–C₄, CO₂]) relative to the other gas types and the virtual lack of ¹⁴C–CH₄ indicated a negligible input of methane from degradation of fresh organic matter. Of all gas types analyzed, vent gas was least affected by molecular fractionation, thus, its origin from the deep subsurface rather than from decomposing hydrates in near-surface sediments is likely.As a result of the anaerobic oxidation of methane, LMWHC in pressure cores in top sediments included smaller methane fractions [0.03 mol.% ∑(C₁–C₄, CO₂)] than gas released from pressure cores of more deeply buried sediments, where the fraction of methane was maximal due to its preferential incorporation in hydrate lattices. No indications for stable carbon isotopic fractionations of methane during hydrate crystallization from vent gas were found. Enrichments of ¹⁴C–CH₄ (1.4 pMC) in short cores relative to lower abundances (max. 0.6 pMC) in gas from long cores and gas hydrates substantiates recent methanogenesis utilizing modern organic matter deposited in top sediments of this high-flux hydrocarbon seep area.     

Flux contribution of coherent structures and its implications for the exchange of energy and matter in a tall spruce canopy

The flux contribution of coherent structures to the total exchange of energy and matter is investigated in a spruce canopy of moderate density in heterogeneous, complex terrain. The study deploys two methods of analysis to estimate the coherent exchange: conditional averages in combination with wavelet analysis, and quadrant analysis. The data were obtained by high-frequency single-point measurements using sonic anemometers and gas analysers at five observation heights above and within the canopy and subcanopy, and represent a period of up to 2.5 months. The study mainly addresses the momentum transfer and exchange of sensible heat throughout the roughness sublayer, while results are provided for the exchange of carbon dioxide and water vapour above the canopy. The magnitude of the flux contribution of coherent structures largely depends on the method of analysis, and it is demonstrated that these differences are attributed to differences in the sampling strategy between the two methods. Despite the differences, relational properties such as sweep and ejection ratios and the variation of the flux contribution with height were in agreement for both methods. The sweep phase of coherent structures is the dominant process close to and within the canopy, whereas the ejections gain importance with increasing distance to the canopy. The efficiency of the coherent exchange in transporting scalars exceeds that for momentum by a factor of two. The occurrence of coherent structures results in a flux error less than 4% for the eddy-covariance method. Based on the physical processes identified from the analysis of the ejection and sweep phases along the vertical profile in the roughness sublayer, a classification scheme for the identification of exchange regimes is developed. This scheme allows one to estimate the region of the canopy participating in the exchange of energy and matter with the above-canopy air under varying environmental conditions.     

Magmatic evolution of Li–F, rare-metal granites: a case study of melt inclusions in the Khangilay complex, Eastern Transbaikalia (Russia)

We report compositions of homogenized quartz-hosted melt inclusions from a layered sequence of Li-, F-rich granites in the Khangilay complex that document the range of melt evolution from barren biotite granites to Ta-rich, lepidolite–amazonite–albite granites. The melt inclusions are crystalline at room temperature and were homogenized in a rapid-quench hydrothermal apparatus at 200 MPa before analysis. Homogenization runs determined solidus temperatures near 550 °C and full homogenization between 650 and 750 °C. The compositions of inclusions, determined by electron microprobe and Raman spectroscopy (for H₂O), show regular overall trends of increasing differentiation from the least-evolved Khangilay units to apical units in the Orlovka intrusion. Total volatile contents in the most-evolved melts reach over 11 wt.% (H₂O: 8.6 wt.%, F: 1.6 wt.%, B₂O₃: 1.5 wt.%). Concentrations of Rb range from about 1000 to 3600 ppm but other trace elements could not be measured reliably by electron microprobe. The resulting trends of melt evolution are similar to those described by the whole-rock samples, despite petrographic evidence for albite- and mica-rich segregations previously taken as evidence for post-magmatic metasomatism.

Melt variation trends in most samples are consistent with fractional crystallization as the main process of magma evolution and residual melt compositions plot at the granite minimum in the normative Qz–Ab–Or system. However, melts trapped in the highly evolved pegmatitic samples from Orlovka deviate from the minimum melt composition and show compositional variations in Al, Na and K that requires a different explanation. We suggest that unmixing of the late-stage residual melt into an aluminosilicate melt and a salt-rich dense aqueous fluid (hydrosaline melt) occurred. Experimental data show the effectiveness of this process to separate K (aluminosilicate melt) from Na (hydrosaline melt) and high mobility of the latter due to its low viscosity and relatively low density may explain local zones of albitization in the upper parts of the granite.     

The Use of LiDAR in Digital Surface Modelling: Issues and Errors

Modelling and extracting 3D geographical data presents numerous challenges that require continual research to attempt to evolve an efficient, reliable and accurate solution. LiDAR data capture and analysis has become a preferred acquisition choice for elevation data because the resulting quality and level of detail far exceeds traditional methods for large survey areas. As with any data collection system, LiDAR is prone to errors. Analysing these errors, ascertaining causes and producing error correction strategies is vital if accurate and confident results are to be obtained. Eight years of LiDAR datasets (from 1998 to 2005) have been closely analysed for a large coastal area of South Wales. This article provides a detailed and accurate summary of the identified LiDAR data issues and subsequent errors which affect the accuracy of end products such as Digital Surface Models (DSMs).     

Using Strong Solar Coronal Emission Lines as Coronal Flux Proxies

We investigate the possibility that strong EUV lines observed with the Goddard Solar EUV Rocket Telescope and Spectrograph (SERTS) provide good proxies for estimating the total coronal flux over shorter wavelength ranges. We use coordinated SERTS and Yohkoh observations to obtain both polynomial and power-law fits relating the broad-band soft X-ray fluxes to the intensities of Fexvi 335 Ú and 361 Ú, Fexv 284 Ú and 417 Ú, and Mgix 368 Ú measured with SERTS. We found that the power-law fits best cover the full range of solar conditions from quiet Sun through active region, though not surprisingly the cooler Mgix 368 Ú line proves to be a poor proxy. The quadratic polynomial fits yield fair agreement over a large range for all but the Mgix line. However, the linear fits fail conspicuously when extrapolated into the quiet-Sun regime. The implications of this work for the Heii 304 Ú line formation problem are also briefly considered.