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91.
The calcium-isotope composition (δ44/42Ca) was analyzed in modern, Cretaceous and Carboniferous marine skeletal carbonates as well as in bioclasts, non-skeletal components, and diagenetic cements of Cretaceous and Carboniferous limestones. In order to gain insight in Ca2+aq-CaCO3-isotope fractionation mechanisms in marine carbonates, splits of samples were analyzed for Sr, Mg, Fe, and Mn concentrations and for their oxygen and carbon isotopic composition. Biological carbonates generally have lower δ44/42Ca values than inorganic marine cements, and there appears to be no fractionation between seawater and marine inorganic calcite. A kinetic isotope effect related to precipitation rate is considered to control the overall discrimination against 44Ca in biological carbonates when compared to inorganic precipitates. This is supported by a well-defined correlation of the δ44/42Ca values with Sr concentrations in Cretaceous limestones that contain biological carbonates at various stages of marine diagenetic alteration. No significant temperature dependence of Ca-isotope fractionation was found in shells of Cretaceous rudist bivalves that have recorded large seasonal temperature variations as derived from δ18O values and Mg concentrations. The reconstruction of secular variations in the δ44/42Ca value of seawater from well preserved skeletal calcite is compromised by a broad range of variation found in both modern and Cretaceous biological carbonates, independent of chemical composition or mineralogy. Despite these variations that may be due to still unidentified biological fractionation mechanisms, the δ44/42Ca values of Cretaceous skeletal calcite suggest that the δ44/42Ca value of Cretaceous seawater was 0.3-0.4‰ lower than that of the modern ocean. 相似文献
92.
Ewald Lüschen Daniela Borrini Helmut Gebrande Bernd Lammerer Karl Millahn Franz Neubauer Rinaldo Nicolich TRANSALP Working Group 《Tectonophysics》2006,414(1-4):9
The TRANSALP consortium, comprising institutions from Italy, Austria and Germany, carried out deep seismic reflection measurements in the Eastern Alps between Munich and Venice in 1998, 1999 and 2001. In order to complement each other in resolution and depth range, the Vibroseis technique was combined with simultaneous explosive source measurements. Additionally, passive cross-line recording provided three-dimensional control and alternative north–south sections. Profits were obtained by the combination of the three methods in sectors or depths where one method alone was less successful.The TRANSALP sections clearly image a thin-skinned wedge of tectonic nappes at the northern Alpine front zone, unexpected graben or half-graben structures within the European basement, and, thick-skinned back-thrusting in the southern frontal zone beneath the Dolomite Mountains. A bi-vergent structure at crustal scale is directed from the Alpine axis to the external parts. The Tauern Window obviously forms the hanging wall ramp anticline above a southward dipping, deep reaching reflection pattern interpreted as a tectonic ramp along which the Penninic units of the Tauern Window have been up-thrusted.The upper crystalline crust appears generally transparent. The lower crust in the European domain is characterized by a 6–7 km thick laminated structure. On the Adriatic side the lower crust displays a much thicker or twofold reflective pattern. The crustal root at about 55 km depth is shifted around 50 km to the south with respect to the main Alpine crest. 相似文献
93.
R. Thomas J.D. Webster D. Rhede W. Seifert K. Rickers H.-J. Frster W. Heinrich P. Davidson 《Lithos》2006,91(1-4):137-149
Fractional crystallization of peraluminous F- and H2O-rich granite magmas progressively enriches the remaining melt with volatiles. We show that, at saturation, the melt may separate into two immiscible conjugate melt fractions, one of the fractions shows increasing peraluminosity and the other increasing peralkalinity. These melt fractions also fractionate the incompatible elements to significantly different degrees. Coexisting melt fractions have differing chemical and physical properties and, due to their high density and viscosity contrasts, they will tend to separate readily from each other. Once separated, each melt fraction evolves independently in response to changing T/P/X conditions and further immiscibility events may occur, each generating its own conjugate pair of melt fractions. The strongly peralkaline melt fractions in particular are very reactive and commonly react until equilibrium is attained. Consequently, the peralkaline melt fraction is commonly preserved only in the isolated melt and mineral inclusions.
We demonstrate that the differences between melt fractions that can be seen most clearly in differing melt inclusion compositions are also visible in the composition of the resulting ore-forming and accessory minerals, and are visible on scales from a few micrometers to hundreds of meters. 相似文献
94.
Thomas A. Vogel Timothy P. Flood Lina C. Patino Melissa S. Wilmot Raymond Patrick R. Maximo Carmencita B. Arpa Carlo A. Arcilla James A. Stimac 《Contributions to Mineralogy and Petrology》2006,151(3):267-281
Silicic volcanic deposits (>65 wt% SiO2), which occur as domes, lavas and pyroclastic deposits, are relatively abundant in the Macolod Corridor, SW Luzon, Philippines.
At Makiling stratovolcano, silicic domes occur along the margins of the volcano and are chemically similar to the silicic
lavas that comprise part of the volcano. Pyroclastic flows are associated with the Laguna de Bay Caldera and these are chemically
distinct from the domes and lavas at Makiling stratovolcano. As a whole, samples from the Laguna de Bay Caldera contain lower
concentrations of MgO and higher concentrations of Fe2O3(t) than the samples from domes and lavas. The Laguna de Bay samples are more enriched in incompatible trace elements. The silicic
rocks from the domes, Makiling Volcano and Laguna de Bay Caldera all contain high alkalis and high K2O/Na2O ratios. Melting experiments of primitive basalts and andesites demonstrate that it is difficult to produce high K2O/Na2O silicic magmas by fractional crystallization or partial melting of a low K2O/Na2O source. However, recent melting experiments (Sisson et al., Contrib Mineral Petrol 148:635–661, 2005) demonstrate that extreme
fractional crystallization or partial melting of K-rich basalts can produce these silicic magmas. Our model for the generation
of the silicic magmas in the Macolod Corridor requires partial melting of mantle-derived, evolved, moderate to K-rich, crystallized
calc-alkaline magmas that ponded and crystallized in the mid-crust. Major and trace element variations, along with oxygen
isotopes and ages of the deposits, are consistent with this model.
Electronic Supplementary Material Supplementary material is available for this article at 相似文献
95.
S. C. Choi Onyx W. H. Wai Thomas W. H. Choi X. D. Li C. W. Tsang 《Environmental Geology》2006,51(3):455-461
Partitioning of heavy metals (Cd, Cr, Cu, Pb, Zn) in marine sediments collected from various sites in Hong Kong waters were
determined using sequential extraction method. Sediments from Kellette Bank, located in Victoria Harbour, had higher metal
concentrations especially Cu and Zn than most other sites. Slightly over 20% of total Cu and Cr existed as readily available
forms in Peng Chau and Kellette Bank. At most sampling sites, over 15% of the Cu existed as the exchangeable form indicating
that Cu could be readily released into the aqueous phase from sediments. A significantly higher percentage of Pb and Zn was
associated with the three non-residual fractions. Hence, there is a greater environmental concern for remobilization of Pb
and Zn compared with Cr. The high amount of residual Cd (>50%) and the relatively lower Cd content indicate that little environmental
concern is warranted for the remobilization of Cd. Distribution of metals in sediments collected from different depth at Kellette
Bank shows that metal concentrations decreased with profile depth. The levels of Pb and Zn associated with the two readily
available fractions increased sharply in the surface sediment. These metals represented the pollutants, which were introduced
into the area in the mid-eighties through early nineties as a result of rapid economic and industrial development in the territory.
As significant portions of these metals were bound to the readily available phases in the surface sediments, metal remobilization
could be a concern.
An erratum to this article can be found at 相似文献
96.
James L. Crowley Mark D. Schmitz Samuel A. Bowring Michael L. Williams Karl E. Karlstrom 《Contributions to Mineralogy and Petrology》2006,151(3):313-330
Zircon from lower crustal xenoliths erupted in the Navajo volcanic field was analyzed for U–Pb and Lu–Hf isotopic compositions
to characterize the lower crust beneath the Colorado Plateau and to determine whether it was affected by ∼1.4 Ga granitic
magmatism and metamorphism that profoundly affected the exposed middle crust of southwestern Laurentia. Igneous zircon in
felsic xenoliths crystallized at 1.73 and 1.65 Ga, and igneous zircon in mafic xenoliths crystallized at 1.43 Ga. Most igneous
zircon has unradiogenic initial Hf isotopic compositions (ɛHf=+4.1–+7.8) and 1.7–1.6 Ga depleted mantle model ages, consistent with 1.7–1.6 Ga felsic protoliths being derived from “juvenile”
Proterozoic crust and 1.4 Ga mafic protoliths having interacted with older crust. Metamorphic zircon grew in four pulses between
1.42 and 1.36 Ga, at least one of which was at granulite facies. Significant variability within and between xenoliths in
metamorphic zircon initial Hf isotopic compositions (ɛHf=−0.7 to +13.6) indicates growth from different aged sources with diverse time-integrated Lu/Hf ratios. These results show
a strong link between 1.4 Ga mafic magmatism and granulite facies metamorphism in the lower crust and granitic magmatism and
metamorphism in the exposed middle crust. 相似文献
97.
Thomas O. Graff 《The Professional geographer》2006,58(1):54-64
The three largest discount chains, Kmart, Target, and Wal‐Mart, have adopted the supercenter format for expansion. This article examines the locations of and the competition among these supercenters. Wal‐Mart has the greatest number of supercenters and is driving the expansion of the supercenter format. Both Kmart and Target have clustered their supercenters in a small number of metropolitan markets. In contrast to Wal‐Mart and Kmart, Target has focused on a middle‐class rather than a blue‐collar clientele. Now Kmart is struggling following a declaration of bankruptcy. Wal‐Mart has largely defeated its supercenter competitors and now is confronting the major grocery chains for grocery sales. 相似文献
98.
99.
Potential of High-Resolution Satellite Data in the Context of Vulnerability of Buildings 总被引:1,自引:2,他引:1
High-resolution space-borne remote sensing data are investigated for their potential to extract relevant parameters for a
vulnerability analysis of buildings in European countries. For an evaluation of large earthquake scenarios, the number of
parameters in models for vulnerability is reduced to a minimum of relevant information such as the type of building (age,
material, number of storeys) and the geological and spatial context. Building-related parameters can be derived from remote
sensing data either directly (e.g. height) or indirectly based on the recognition of the urban structure type in which the
buildings are located. With the potential of a fully- or semi-automatic inventory of the buildings and their parameters, high-resolution
satellite data and techniques for their processing are a useful supporting tool for the assessment of vulnerability. 相似文献
100.
Márian Urban Rainer Thomas Vratislav Hurai Patrik Koneèný Martin Chovan 《Mineralium Deposita》2006,40(8):867-873
CO2 inclusions with density up to 1,197 kg m−3 occur in quartz–stibnite veins hosted in the low-grade Palaeozoic basement of the Gemericum tectonic unit in the Western Carpathians. Raman microanalysis corroborated CO2 as dominant gas species accompanied by small amounts of nitrogen (<7.3 mol%) and methane (<2.5 mol%). The superdense CO2 phase exsolved from an aqueous bulk fluid at temperatures of 183–237°C and pressures between 1.6 and 3.5 kbar, possibly up to 4.5 kbar. Low thermal gradients (∼12–13°C km−1) and the CO2–CH4–N2 fluid composition rule out a genetic link with the subjacent Permian granites and indicate an external, either metamorphogenic (oxidation of siderite, dedolomitization) or lower crustal/mantle, source of the ore-forming fluids.According to microprobe U–Pb–Th dating of monazite, the stibnite-bearing veins formed during early Cretaceous thrusting of the Gemeric basement over the adjacent Veporic unit. The 15- to 18-km depth of burial estimated from the fluid inclusion trapping PT parameters indicates a 8- to 11-km-thick Upper Palaeozoic–Jurassic accretionary complex overlying the Gemeric basement and its Permo-Triassic autochthonous cover. 相似文献