Petrography and geochemistry of manganiferous rocks in the Mankwadzi area in the southern Kibi‐Winneba metavolcanic belt,Ghana: Implications for genesis of Mn formations in the Birimian of West Africa

Manganiferous rocks in the Mankwadzi area in the southernmost portion of the Kibi‐Winneba metavolcanic belt, one of several Mn occurrences in the Paleoproterozoic Birimian of Ghana, are hosted in hornblende schist and amphibolite. These rocks are, in places, intruded by hornblende dyke. In outcrop, the manganiferous rocks appear to be conformable with the host schist and amphibolite, are macroscopically dark, fine‐grained and structurally massive to distinctly banded. Observed alternating light and dark occasionally macro‐folded bands suggest post‐depositional deformation of both light and dark bands. Microscopic observations revealed that the light bands are dominantly Si‐rich and the dark bands mainly of opaque minerals. Whole rock analyses of the manganiferous rocks show high contents of MnO (16.75–27.4 wt%) suggesting that the opaque minerals are likely rich in Mn. The analyzed rock samples show moderate to strong enrichments in light rare earth elements compared to heavy rare earth elements. Whereas the manganiferous rocks show perceptibly negative Eu anomaly, host hornblende schist and hornblende dyke do not. Eu anomaly in amphibolite samples is, however, uncertain as the three samples analyzed gave positive, negative and no Eu anomalies. Based on the field characteristics, microscopic and geochemical features, we suggest that the Mn occurrence in the Mankwadzi area originated via sedimentary deposition and was later modified by metamorphism, hydrothermal and/or supergene processes similar to manganiferous occurrences at Nsuta and Tambao in the Birimian of West Africa.     

Evaluating Subsurface Parameterization to Simulate Hyporheic Exchange: The Steinlach River Test Site

Hyporheic exchange is the interaction of river water and groundwater, and is difficult to predict. One of the largest contributions to predictive uncertainty for hyporheic exchange has been attributed to the representation of heterogeneous subsurface properties. Our study evaluates the trade-offs between intrinsic (irreducible) and epistemic (reducible) model errors when choosing between homogeneous and highly complex subsurface parameter structures. We modeled the Steinlach River Test Site in Southwest Germany using a fully coupled surface water-groundwater model to simulate hyporheic exchange and to assess the predictive errors and uncertainties of transit time distributions. A highly parameterized model was built, treated as a “virtual reality” and used as a reference. We found that if the parameter structure is too simple, it will be limited by intrinsic model errors. By increasing subsurface complexity through the addition of zones or heterogeneity, we can begin to exchange intrinsic for epistemic errors. Thus, the appropriate level of detail to represent the subsurface depends on the acceptable range of intrinsic structural errors for the given modeling objectives and the available site data. We found that a zonated model is capable of reproducing the transit time distributions of a more detailed model, but only if the geological structures are known. An interpolated heterogeneous parameter field (cf. pilot points) showed the best trade-offs between the two errors, indicating fitness for practical applications. Parameter fields generated by multiple-point geostatistics (MPS) produce transit time distributions with the largest uncertainties, however, these are reducible by additional hydrogeological data, particularly flux measurements.     

Application of common reflection angle migration for imaging deformation structures in an inner accretionary wedge,Nankai Trough,Japan

To better image deformation structures within the inner accretionary wedge of the Nankai Trough, Japan, we apply common reflection angle migration to a legacy two-dimensional seismic data set acquired with a 6 km streamer cable. In this region, many seismic surveys have been conducted to study the seismogenic zone related to plate subduction. However, the details of the accreted sediments beneath the Kumano forearc basin are still unclear due to the poor quality of seismic images caused by multiple reflections, highly attenuated signals, and possibly complex geological structures. Generating common image gathers in the subsurface local angle domain rather than the surface offset domain is more advantageous for imaging geological structures that involve complex wave paths and poor illumination. By applying this method, previously unseen structures are revealed in the thick accreted sediments. The newly imaged geometric features of reflectors, such as the folds in the shallow part of the section and the deep reflectors with stepwise discontinuities, imply deformation structures with multiple thrust faults. The reflections within the deep accreted sediments (approximately 5 km) are mainly mapped to far angles (30°–50°) in the common reflection angles, which correspond to the recorded offset distances greater than 4.5 km. This result indicates that the far offset/angle information is critical to image the deformation structures at depth. The new depth image from the common reflection angle migration provides seismic evidence of multiple thrust faults and their relationship with the megathrust fault that is essential for understanding the structure and evolution of the Nankai Trough seismogenic zone.     

Uncertainty in stage–discharge rating curves: application to Australian Hydrologic Reference Stations data

The purpose of this paper is to determine uncertainty in the gauged range of the stage–gauged discharge relationship for 622 rating curves from 171 Australian Bureau of Meteorology Hydrologic Reference streamgauging Stations (HRS). Water agencies use many methods to establish rating curves. Here we adopt a consistent method across all stations and develop rating curves based on Chebyshev polynomials, and estimate uncertainties from standard regression errors in which residuals from the polynomials are adjusted to ensure they are homoscedastic and normally distributed. Uncertainty in input water level is also taken into account. The median uncertainties in mean response of the available gauged discharge relationship at median daily discharges for the HRS dataset range from +4.5 to ?4.2% (95% confidence band) and for individual gaugings from +29 to ?22% incorporating a water level uncertainty of ±4 mm. The uncertainties estimated are consistent with values estimated in Australia and elsewhere.     

Vertically Integrated Hydraulic Conductivity: A New Parameter for Groundwater-Surface Water Analysis

Numerical modeling of groundwater-surface water interactions provides vital information necessary for determining the extent of nutrient transport, quantifying water budgets, and delineating zones of ecological support. The hydrologic data that drive these models are often collected at disparate scales and subsequently incorporated into numerical models through upscaling techniques such as piecewise constancy or geostatistical methods. However, these techniques either use basic interpolation methods, which often simplifies the system of interest, or utilize complex statistical methods that are computationally expensive, time consuming, and generate complex subsurface configurations. We propose a bulk parameter termed “vertically integrated hydraulic conductivity” (K_V), and defined as the depth-integrated resistance to fluid flow sensed at the groundwater-surface water interface, as an alternative to hydraulic conductivity when investigating vertical fluxes across the groundwater-surface water interface. This bulk parameter replaces complex subsurface configurations in situations dominated by vertical fluxes and where heterogeneity is not of primary importance. To demonstrate the utility of K_V, we extracted synthetic temperature time series data from a forward numerical model under a variety of scenarios and used those data to quantify vertical fluxes using the amplitude ratio method. These quantified vertical fluxes and the applied hydraulic head gradient were subsequently input into Darcy's Law and used to quantify K_V. This K_V was then directly compared to the equivalent hydraulic conductivity (K_T) assuming an infinitely extending layer. Vertically integrated hydraulic conductivity allows for more accurate and robust flow modeling across the groundwater-surface water interface in instances where complex heterogeneities are not of primary concern.     

Mineralogical approaches to sourcing pipes and figurines from the eastern woodlands,U.S.A.

Provenance studies of stone artifacts often rely heavily upon chemical techniques such as neutron activation analysis. However, stone specimens with very similar chemical composition can have different mineralogies (distinctive crystalline structures as well as variations within the same mineral) that are not revealed by multielemental techniques. Because mineralogical techniques are often cheap and usually nondestructive, beginning with mineralogy allows the researcher to gain valuable information and then to be selective about how many samples are submitted for expensive and somewhat destructive chemical analysis, thus conserving both valuable samples and funds. Our University of Illinois team of archaeologists and geologists employs Portable Infrared Mineral Analyzer (PIMA) spectroscopy, X‐ray diffraction (XRD), and Sequential acid dissolution/XRD/Inductively coupled plasma (SAD‐XRD‐ICP) analyses. Two case studies of Hopewellian pipes and Mississippian figurines illustrate this mineralogical approach. The results for both studies identify sources relatively close to the sites where the artifacts were recovered: Sterling, Illinois (rather than Ohio) for the (Hopewell) pipes and Missouri (rather than Arkansas or Oklahoma) for the Cahokia figurines. © 2002 Wiley Periodicals, Inc.     

Distribution,sediment magnetism and geochemistry of the Saksunarvatn (10 180 ± 60 cal. yr BP) tephra in marine,lake, and terrestrial sediments,northwest Iceland

In 1997, seismic surveys in the troughs off northwest and north Iceland indicated the presence of a major, regional sub‐bottom reflector that can be traced over large areas of the shelf. Cores taken in 1997, and later in 1999 on the IMAGES V cruise, penetrated through the reflector. In core MD99‐2269 in Húnaflóaáll, this reflector is shown to be represented by a basaltic tephra with a geochemical signature and radiocarbon age correlative with the North Atlantic‐wide Saksunarvatn tephra. We trace this tephra throughout northwest Iceland in a series of marine and lake cores, as well as in terrestrial sediments; it forms a layer 1 to 25 cm thick of fine‐ to medium‐grained basaltic volcanic shards. The base of the tephra unit is always sharp but visual inspection and other measurements (carbonate and total organic carbon weight %) indicate a more diffuse upper boundary associated with bioturbation and with sediment reworking. Off northwest Iceland the Saksunarvatn tephra has distinct sediment magnetic properties. This is evident as a dramatic reduction in magnetic susceptibility, an increase in the frequency dependant magnetic susceptibility and ‘hard’ magnetisation in a −0.1T IRM backfield. Geochemical analyses from 11 sites indicate a tholeiitic basalt composition, similar to the geochemistry of a tephra found in the Greenland ice‐core that dates to 10 180 ± 60 cal. yr BP, and which was correlated with the 9000 ¹⁴C yr BP Saksunarvatn tephra. We present accelerator mass spectrometry ¹⁴C dates from the marine sites, which indicate that the ocean reservoir correction is close to ca. 400 yr at 9000 ¹⁴C yr BP off northwest Iceland. Copyright © 2002 John Wiley & Sons, Ltd.     

Channel precipitation dynamics in a forested Pennsylvania headwater catchment (USA)

Seasonal and event variations in stream channel area and the contributions of channel precipitation to stream flow were studied on a 106‐ha forested headwater catchment in central Pennsylvania. Variations in stream velocity, flowing stream surface width and widths of near‐stream saturated areas were periodically monitored at 61 channel transects over a two‐year period. The area of flowing stream surface and near‐stream saturated zones combined, ranged from 0·07% of basin area during summer low flows to 0·60% of total basin area during peak storm flows. Near‐stream saturated zones generally represented about half of the total channel area available to intercept throughfall and generate channel precipitation. Contributions of routed channel precipitation from the flowing stream surface and near‐stream zones, calculated using the Penn State Runoff Model (PSRM, v. 95), represented from 1·1 to 6·4% of total stream flow and 2·5–29% of total storm flow (stream flow–antecedent baseflow) during the six events. Areas of near‐stream saturated zones contributed 35–52% of the computed channel precipitation during the six events. Channel precipitation contributed a higher percentage of stream flow for events with low antecedent baseflow when storm flow generated by subsurface sources was relatively low. Expansion of channel area and consequent increases in volumes of channel precipitation with flow increases during events was non‐linear, with greater rates of change occurring at lower than at higher discharge rates. Copyright © 1999 John Wiley & Sons, Ltd.     

Mars: The spectral albedo (0.3–2.5μ) of small bright and dark regions

A review of the available spectral geometric albedo measurements for Mars was presented earlier for the spectral region 0.3 to 1.1μ. A new observational study has greatly increased the store of data, especially for small Martian regions and for the infrared spectral region 1.0 to 2.5μ. Here we combine the new data with data both from the earlier review and, for the infrared spectral region, from the literature. We present a more complete picture of Martian spectral reflectivity properties than was available. This study should provide a more firm basis upon which models of Martian surface composition can be built. At visible wavelengths the Mars dark area Syrtis Major is red rather than green or grey in color; the bright area Arabia is even redder than Syrtis Major. Absorption bands, which differ between bright and dark areas, appear in the reflection curves. The 1μ absorption feature for dark areas is confirmed and more completely described. A previously unreported absorption band near 0.95μ for bright areas appears along with several absorption features in the infrared. The geometric albedo for Arabia reaches a maximum of about 0.43 at 1μ. The Bond albedo for this same area reaches a maximum of 60%. The bright area Arabia is occasionally three times brighter than the dark area Syrtis Major at red wavelengths. Published infrared reflection data available for Mars are not in complete agreement. Changes in brightness and color of Arabia are discussed which are not in agreement with traditional darkening wave theory.     

Are real-world shallow landslides reproducible by physically-based models? Four test cases in the Laternser valley,Vorarlberg (Austria)

In contrast to the complex nature of slope failures, physically-based slope stability models rely on simplified representations of landslide geometry. Depending on the modelling approach, landslide geometry is reduced to a slope-parallel layer of infinite length and width (e.g., the infinite slope stability model), a concatenation of rigid bodies (e.g., Janbu’s model), or a 3D representation of the slope failure (e.g., Hovland’s model). In this paper, the applicability of four slope stability models is tested at four shallow landslide sites where information on soil material and landslide geometry is available. Soil samples were collected in the field for conducting respective laboratory tests. Landslide geometry was extracted from pre- and post-event digital terrain models derived from airborne laser scanning. Results for fully saturated conditions suggest that a more complex representation of landslide geometry leads to increasingly stable conditions as predicted by the respective models. Using the maximum landslide depth and the median slope angle of the sliding surfaces, the infinite slope stability model correctly predicts slope failures for all test sites. Applying a 2D model for the slope failures, only two test sites are predicted to fail while the two other remain stable. Based on 3D models, none of the slope failures are predicted correctly. The differing results may be explained by the stabilizing effects of cohesion in shallower parts of the landslides. These parts are better represented in models which include a more detailed landslide geometry. Hence, comparing the results of the applied models, the infinite slope stability model generally yields a lower factor of safety due to the overestimation of landslide depth and volume. This simple approach is considered feasible for computing a regional overview of slope stability. For the local scale, more detailed studies including comprehensive material sampling and testing as well as regolith depth measurements are necessary.