Four thousand years of environmental change and human activity in the Cochabamba Basin, Bolivia

The Cochabamba Basin (Bolivia) is on the ancient road network connecting Andean and lowland areas. Little is known about the longevity of this trade route or how people responded to past environmental changes. The eastern end of the Cochabamba valley system constricts at the Vacas Lake District, constraining the road network and providing an ideal location in which to examine past human-environmental interactions. Multi-proxy analysis of sediment from Lake Challacaba has allowed a c. 4000 year environmental history to be reconstructed. Fluctuations in drought tolerant pollen taxa and calcium carbonate indicate two periods of reduced moisture availability (c. 4000-3370 and c. 2190-1020 cal yr BP) compared to adjacent wetter episodes (c. 3370-2190 and c. 1020 cal yr BP-present). The moisture fluctuations broadly correlate to El Niño/Southern Oscillation variations reported elsewhere. High charcoal abundance from c. 4000 to 2000 yr ago indicates continuous use of the ancient road network. A decline in charcoal and an increase in dung fungus (Sporormiella) c. 1340-1210 cal yr BP, suggests that cultural changes were a major factor in shaping the modern landscape. Despite undisputable impacts of human populations on the Polylepis woodlands today, we see no evidence of woodland clearance in the Challacaba record.     

Increasing temperature and flow management alter mercury dynamics in East Fork Poplar Creek

East Fork Poplar Creek (EFPC) is a mercury (Hg) contaminated creek in east Tennessee, USA. Stream restoration activities included the initiation of a flow management programme in 1996 in which water from a nearby lake was pumped to the head of the creek. We conducted regular water sampling for 2 years along the length of EFPC during active flow management and for 5 years after flow management stopped. Total Hg and total monomethylmercury (MMHg) concentration and flux decreased in the uppermost reaches of EFPC that were closest to the point of water addition. Most water quality parameters, including DOC concentration, remained unchanged after flow management termination. Nevertheless, SUVA₂₅₄, a measure of dissolved organic matter (DOM) composition, increased and coincided with increased dissolved Hg (Hg_D) concentration and flux and decreased Hg solid-water partitioning coefficients throughout EFPC. Higher SUVA₂₅₄ and Hg_D concentration have potential implications for bioavailability and MMHg production. Total and dissolved MMHg concentrations increased in lower reaches of EFPC after the end of flow management and these increases were most pronounced during spring and early summer when biota are more susceptible to exposure and uptake. A general warming trend in the creek after active flow management ended likely acted in concert with higher Hg_D concentration to promote higher MMHg concentration. Total and dissolved MMHg concentrations were positively correlated with water temperature above a threshold value of 10°C. Concentration changes for Hg and MMHg could not be accounted for by changes in creek discharge that accompanied the cessation of flow management. In addition to the changing DOM composition in-stream, other watershed-scale factors likely contributed to the observed patterns, as these changes occurred over months rather than instantaneously after flow management stopped. Nevertheless, similar changes in MMHg have not been observed in a tributary to EFPC.     

Sphene (titanite)

Few people have heard of the mineral sphene (also called titanite), but it is nevertheless extremely widespread, occurring in most common rocks. It can be useful to the Earth scientist as it contains information on the timing, temperature and pressure of formation of many common rocks. It is also a source of titanium—and can sometimes be used as a gemstone.     

Lithium minerals

Lithium is a critical element in modern technology, and lithium minerals will play a key role in the fight against climate change. However, the demand for lithium-ion batteries is dependent on an expanding supply of primary resources. Lithium occurs in limited amounts on the Earth in a surprising diversity of mineral species, from pyroxenes to amphiboles, phyllosilicates to phosphates. This article examines the principal mineral groups likely to be a target for future exploitation.     

Identification of source of a marine oil-spill using geochemical and chemometric techniques

The current work aimed to identify the source of an oil spill off the coast of Maranhão, Brazil, in September 2005 and effect a preliminary geochemical survey of this environment. A combination of bulk analytical parameters, such as carbon isotope (δ¹³C) and Ni/V ratios, and conventional fingerprinting methods (High Resolution Gas Chromatography and Mass Spectrometry) were used. The use of bulk methods greatly speeded source identification for this relatively unaltered spill: identification of the likely source was possible at this stage. Subsequent fingerprinting of biomarker distributions supported source assignment, pointing to a non-Brazilian oil. Steranes proved the most useful biomarkers for sample correlation in this work. Distribution patterns of environmentally more resilient compound types, such as certain aromatic structures, proved inconclusive for correlation, probably in view of their presence in the background.     

Modelling suspended sediment concentration and load in a transport‐limited alluvial gully in northern Queensland,Australia

Alluvial gullies are often formed in dispersible sodic soils along steep banks of incised river channels. Field data collected by Shellberg et al. (Earth Surface Processes and Landforms 38: 1765–1778, 2013) from a gully outlet in northern Australia showed little hysteresis between water discharge and fine (<63 µm) and coarse (>63 µm) suspended sediment, indicating transport‐limited rather than source‐limited conditions. The major source of the fine (silt/clay) component was the sodic soils of upstream gully scarps, and the coarser (sand) component was sourced locally from channel bed material. In this companion paper at the same study site, a new method was developed for combining the settling velocity characteristics of these two sediment source components to estimate the average settling velocity of the total suspended sediment. This was compared to the analysis of limited sediment samples collected during flood conditions. These settling velocity data were used in the steady‐state transport limit theory of Hairsine and Rose (Water Resources Research 28: 237–243, 245–250, 1992) that successfully predicted field data of concentrations and loads at a cross‐section, regardless of the complexity of transport‐limited upstream sources (sheet erosion, scalds, rills, gullies, mass failure, bank and bed erosion, other disturbed areas). The analysis required calibration of a key model parameter, the fraction of total stream power (F ≈ 0.025) that is effective in re‐entraining sediment. Practical recommendations are provided for the prediction of sediment loads from other alluvial gullies in the region with similar hydrogeomorphic conditions, using average stream power efficiency factors for suspended silt/clay (F_w ≈ 0.016) and sand (F_s ≈ 0.038) respectively, but with no requirement for field data on sediment concentrations. Only basic field data on settling velocity characteristics from soil samples, channel geometry measurements, estimates of water velocity and discharge, and associated error margins are needed for transport limit theory predictions of concentration and load. This theory is simpler than that required in source‐limited situations. Copyright © 2015 John Wiley & Sons, Ltd.     

Forming a large disc galaxy from a z < 1 major merger

Using high-resolution SPH simulations in a fully cosmological Λ cold dark matter context, we study the formation of a bright disc-dominated galaxy that originates from a 'wet' major merger at   z = 0.8  . The progenitors of the disc galaxy are themselves disc galaxies that formed from early major mergers between galaxies with blue colours. A substantial thin stellar disc grows rapidly following the last major merger and the present-day properties of the final remnant are typical of early-type spiral galaxies, with an i -band bulge-to-disc ratio ∼0.65, a disc scalelength of 7.2 kpc,   g − r = 0.5 mag  , an H  i linewidth ( W ₂₀/2) of 238 km s⁻¹ and total magnitude   i =−22.4  . The key ingredients for the formation of a dominant stellar disc component after a major merger are (i) substantial and rapid accretion of gas through cold flows followed at late times by cooling of gas from the hot phase, (ii) supernova feedback that is able to partially suppress star formation during mergers and (iii) relative fading of the spheroidal component. The gas fraction of the progenitors' discs does not exceed 25 per cent at   z < 3  , emphasizing that the continuous supply of gas from the local environment plays a major role in the regrowth of discs and in keeping the galaxies blue. The results of this simulation alleviate the problem posed for the existence of disc galaxies by the high likelihood of interactions and mergers for galaxy-sized haloes at relatively low z .     

Response of chironomids to late Pleistocene and Holocene environmental change in the eastern Bolivian Andes

We present the first palaeolimnological investigation of chironomid larval assemblages from the Bolivian Eastern Cordillera. Taxonomic diagnoses are provided for the 10 chironomid taxa (subfamilies: Chironominae, Orthocladiinae and Tanypodinae) identified in the lake sediments. We compared changes in the chironomid assemblage from two Andean sites with previously reported palynological, charcoal and geochemical data, and highlight the potential of chironomid analysis to provide additional insights into environmental change in this region of high biodiversity over the last 18,000?years. At Lake Challacaba (17°33.257??S, 65°34.024??W; 3,400?m asl), the chironomid and geochemical data indicate periodic desiccation and hypersalinty of the basin c. 4,000?C3,460?cal?year BP. Increased abundance of Chironomus sp. at c. 1,000?cal?year BP suggests a change in human activity, supporting inferences from the pollen and spore records, which indicate elevated pastoral agriculture at this time. The greatest assemblage change in the chironomid record from Laguna Khomer Kocha Upper (17°16.514??S, 65°43.945??W; 4,153?m asl) occurred at c. 6,380?cal?year BP, concomitant with an increase in marsh woodland taxa, wetter conditions and a rising lake level at the end of a Holocene dry event. There is no apparent response in the chironomid assemblage to burning, however, at the onset of this dry event (c. 10,000?cal?year BP), which is the major transformative agent of the terrestrial vegetation. This study shows that chironomid assemblages in the tropical Andes responded to regional and local environmental changes, and in particular, that they were sensitive to adjustments in net moisture balance (water level fluctuations and salinity) and anthropogenic impacts (nutrient input). This suggests that within-lake processes are more important as drivers of chironomid assemblage composition than terrestrial vegetation or fire regime. Nevertheless, the full potential of subfossil chironomid analysis will only be realised once more modern autecological data are available.