Lake-groundwater relationships and fluid-rock interaction in the East African Rift Valley: isotopic evidence

The assessment of water resources in the Rift Valley environment is important for population, agriculture and energy-related issues and depends on a good understanding of the relationship between freshwater lakes and regional groundwater. This can be hampered by the amount of fluid-rock interaction which occurs throughout the rift, obscuring original hydrochemical signatures. However, O and H stable isotope ratios can be used as tracers of infiltration over sometimes considerable distances, while showing that the volcanic edifices of the rift floor have varying effects on groundwater flow patterns. Specific cases from Kenya and Ethiopia are considered, including Lakes Naivasha, Baringo, Awasa and Zwai.In addition to their physical tracing role, stable isotopes can reveal information about processes of fluid-rock interaction. The general lack of O isotope shifting in rift hydrothermal systems suggests a high water:rock ratio, with the implication that these systems are mature. Carbon isotope studies on the predominantly bicarbonate waters of the rift show how they evolve from dilute meteoric recharge to highly alkaline waters, via the widespread silicate hydrolysis promoted by the flux of mantle carbon dioxide which occurs in most parts of the rift. There appears to be only minor differences in the C cycle between Kenya and Ethiopia.     

Elasticity of CaTiO3, SrTiO3 and BaTiO3 perovskites up to 3.0 Gpa: the effect of crystallographic structure

Elasticity of CaTiO₃, SrTiO₃ and BaTiO₃ perovskites has been experimentally investigated as a function of pressure up to 3.0 GPa in a liquid-medium piston cylinder apparatus using a high precision ultrasonic interferometric technique. Specimens used are hot-pressed fine-grained (3–10 μm) polycrystalline aggregates with low porosity (<1.5%). Compressional and shear wave velocities and their pressure derivatives have been measured. The results are compared with previous studies on other perovskites and the role of structural transitions is examined. We find that the role of Ti-O₆ polyhedral tilting (such as observed in CaTiO₃) is small in the sense that a single well-defined general trend exists in perovskites with a wide range of tilting angles, although there is suggestion that cubic perovskites have slightly higher bulk modulus than orthorhombic perovskites. In contrast, cation-anion displacement that changes crystal symmetry from cubic to tetragonal in BaTiO₃ has very large effects on elasticity. This distortion significantly reduces the bulk modulus (but not much the shear modulus) and results in an unusually large pressure derivative of bulk modulus (dK/dP～10). A large change in elasticity in BaTiO₃ associated with the structural transition (without a significant volume change) is a clear example of the breakdown of the Birch's law between densities and elastic wave velocities.     

Starspots: The zebra effect

Recent observations of brightness variations on the Sun during the solar cycle have motivated us to re-examine the widely held view that cool, dark starspots, covering a significant fraction of the star, are the centers of magnetic activity on BY Dra stars. We propose that the magnetic regions are better described by a bright facular network, and that the dark areas which give rise to photometric rotational modulation are actually regions where the underlying quiet photosphere is seen. This interpretation is consistent with recent observations of late-type stars that show that bright areas covering much of the star have magnetic fields with strengths of several thousand gauss. It resolves several problems with the current model, including the size, location, and stability of the starspots required to match photometric and Doppler-imaging observations. It also has interesting observational implications for the correlation of photometric rotational modulation and long term brightness variations with other surface activity, and for the positions of magnetically active stars in the H-R diagram.Hubble Fellow.     

Spatial characterization of environmental gradients in a coastal lagoon, Chincoteague Bay

Spatial patterns of environmental processes are intrinsic yet complex components of estuaries. Spatial characterization of environmental gradients is a necessary step to better understand and classify estuarine environments. A geographic information system is developed to analyze the major abiotic environmental processes, to evaluate accuracy and spatial uncertainty, and to analyze potential zonation within the choked coastal lagoon of Chincoteague Bay in Maryland and Virginia, USA. Spatially extensive grid-based models of environmental gradients are constructed from existing geospatial and environmental databases, including tidal prism, bathymetry, salinity, wave exposure, and Secchi disk depth. Integration of wetland boundaries and bathymetric data provide for full basin analysis of flushing and tidal prism. Multivariate Principal Components Analysis demonstrates the covariation among gradients and provides an empirical approach to mapping multidimensional zones within the lagoon. The project documents the development of an estuarine geographic information system that can be used to analyze and compare estuarine environments and provide data for environmental decision making.     

Effects of capillary reflection in the performance of the collimator of the Large Area Detector on board LOFT

The Large Observatory For X-ray Timing (LOFT) is one of the candidate missions selected by the European Space Agency for an initial assessment phase in the Cosmic Vision programme. It is proposed for the M3 launch slot and has broad scientific goals related to fast timing of astrophysical X-ray sources. LOFT will carry the Large Area Detector (LAD), as one of the two core science instruments, necessary to achieve the challenging objectives of the project. LAD is a collimated detector working in the energy range 2-50 keV with an effective area of approximately 10 m ²at 8 keV. The instrument comprises an array of modules located on deployable panels. Lead-glass microchannel plate (MCP) collimators are located in front of the large-area Silicon Drift Detectors (SDD) to reduce the background contamination from off-axis resolved point sources and from the diffuse X-ray background. The inner walls of the microchannel plate pores reflect grazing incidence X-ray photons with a probability that depends on energy. In this paper, we present a study performed with an ad-hoc simulator of the effects of this capillary reflectivity on the overall instrument performance. The reflectivity is derived from a limited set of laboratory measurements, used to constrain the model. The measurements were taken using a prototype collimator whose thickness is similar to that adopted in the current baseline design proposed for the LAD. We find that the experimentally measured level of reflectivity of the pore inner walls enhances the off-axis transmission at low energies, producing an almost flat-top response. The resulting background increase due to the diffuse cosmic X-ray emission and sources within the field of view does not degrade the instrument sensitivity.     

Vulnerability assessment of rainfall-induced debris flows in Taiwan

A GIS-based decision support system, which incorporates local topographic and rainfall effects on debris flow vulnerability is developed. Rainfall at a scale compatible with the digital elevation model resolution is obtained using a neural network with a wind-induced topographic effect and rainfall derived from satellite rain estimates and an adaptive inverse distance weight method (WTNN). The technique is tested using data collected during the passage of typhoon Tori-Ji on July 2001 over central Taiwan. Numerous debris flows triggered by the typhoon were used as control for the study. Our results show that the WTNN technique outperforms other interpolation techniques including adaptive inversed distance weight (AIDW), simple kriging (SK), co-kriging, and multiple linear regression using gauge, and topographic parameters. Multiple remotely-sensed, fuzzy-based debris-flow susceptibility parameters are used to describe the characteristics of watersheds. Non-linear, multi-variant regressions using the WTNN derived rainfall and topography factors are derived using self-organizing maps (SOM) for the debris flow vulnerability assessment. An index of vulnerability representing the degrees of hazard is implemented in a GIS-based decision support system by which a decision maker can assess debris flow vulnerability.     

Computational model for the simulation of the shield tunneling process in cohesive soils

A two-dimensional computational model is developed here in order to simulate the continuous advance of the Earth Pressure Balance (EPB) Shield during the tunneling process in cohesive soils. The model is based on the combination of the plane strain “transverse–longitudinal” sections that can incorporate the three-dimensional deformation of the soil around and ahead of the shield face. This model is capable of prediciting the soil response due to the shield tunneling before the event, especially in soft ground conditions. An elasto-plastic finite element analysis that is based on the coupled theory of mixtures for inelastic porous media for finite deformation is used in this work to describe the time-dependent deformation of the saturated cohesive soils. The results of this model are compared with the in situ field measurements of the N-2 tunnel project excavated in 1981 in San Francisco using the EPB shield tunneling machine. Reasonable agreement is found between the observed field measurements and the predicted deformations of the soil using the proposed numerical simulation. Copyright © 1999 John Wiley & Sons, Ltd.     

Laboratory technique for quantitative thermal emissivity measurements of geological samples

Thermal infrared spectroscopy is a powerful technique for the compositional analysis of geological materials. The spectral feature in the mid-IR region is diagnostic of the mineralogy and spectral signatures of mixtures of minerals that add linearly, and therefore, can be used as an important tool to determine the mineralogy of rocks in the laboratory and remotely for planetary exploration. The greatest challenge in the emission measurement lies in the measurement of the weak thermal photons emitted from geological materials in a laboratory setup, and accurately records the temperature of the rock sample. The present work pertains to the details of a new Thermal Emission Spectrometer (TES) laboratory that has been developed under the ISRO Planetary Science and Exploration (PLANEX) programme, for emission related mineralogical investigations of planetary surfaces. The focus of the paper is on the acquisition and calibration technique for obtaining emissivity, and the deconvolution procedure to obtain the modal abundances of the thermal emission spectra in the range of 6–25 μm using Fourier Transform Infrared (FTIR) spectroscopy. The basic technique is adopted from the work of Ruff et al (1997). This laboratory at the Department of Earth Sciences, IIT-Bombay is currently developing pure end mineral library of mineral particulates (<65 μm), and adding new end members to the existing ASU spectral library. The paper argues the need for considering Lunar Orbiter Thermal Emission Spectrometer (LOTES) for future Indian Moon mission programme (Chandrayan-II) to determine evidences of varied lithologies on the lunar surface.     

Correction of Holloway's (1977) adaptation of the modified Redlich-Kwong equation of state for calculation of the fugacities of molecular species in supercritical fluids of geologic interest

Consideration of constraints imposed on fugacity coefficients by the Gibbs-Duhem equation and those inherent in the Redlich-Kwong equation of state (Redlich and Kwong, 1949) and its modification by de Santis et al. (1974) indicates that Holloway's (1977) adaptation of the Redlich-Kwong equation for calculating fugacity coefficients of molecular species in gas mixtures is in error. Revised calculations using the correct equation lead to much smaller departures from ideality than those generated by Holloway.