The First Results of U–Pb Isotope Dating of Detrital Zircons from the Upper Mesoproterozoic Gulliksenfellet Quartzite (Southern Part of Wedel Jarlsberg Land,Southwest Spitsbergen)

The first results of U–Pb isotopic dating (LA–ICP–MS) of detrital zircons from metasedimentary rocks of the pre-Devonian basement of the SW part of western Spitsbergen (from Upper Mezoproterozoic Gulliksenfellet quartzite) showed ages ranging from 1700 ± 25 to 2948 ± 27 Ma.     

Detection of Intermediate Mediterranean Waters in the Atlantic Ocean by ARGO Floats Data

Peculiarities of the spatial distribution of intermediate Mediterranean waters (MW), which are the main source to maintain the heat and salt budgets at depths of 600–1500 m in the Atlantic Ocean, have been studied using the ARGO floats measurements database. About 75000 temperature and salinity profiles recorded by 900 ARGO floats in 2005–2014 in the Atlantic Ocean for latitudes from 20° to 50° N were used. To process these data, we used the ARGO-Based Model for Investigation of the Global Ocean (AMIGO). This technique allowed us for the first time to obtain a complete set of oceanographic characteristics up to a depth of 2000 m for different time averaging intervals (month, season, years). Joint analysis of the temperature, salinity, and velocity distributions at 700–1000 m depths made it possible to revise the distribution of MW and their penetration into the western part of the ocean across the Mid-Atlantic Ridge (MAR). It is shown that at depths of 700 and 1000 m, the Mid-Atlantic Ridge is a barrier to advective propagation of salty waters (>35.5 PSU) to the west and is transparent to fragments of destroyed intrathermocline lenses (ITL) with lower salinity (<35.4 PSU). In the Atlantic region, from 20° to 35° N and from 30° to 70° W, individual lens profiles with an anomalous salinity distribution were sought using ARGO measurements to detect ITL and its separate fragments. About 24 000 measurements from 370 ARGO floats were analyzed, and only about 3% of them showed weak salinity anomalies at 800–1200 m depths. No ITL were found from these observations. Analysis of long-term drifting of individual floats recording temperature and salinity profiles with anomalous layers made it possible to study the nature of MW transport through the MAR.     

Toxic chemicals in Canadian fish-eating birds

Cross-country comparison of DDE and PCB residue levels in cormorant, gull and tern eggs in Canada reveal that bird populations at the Great Lakes are most contaminated with those pollutants. DDE levels have been correlated with reproductive failure in Double-crested Cormorants in the Great Lakes with eggshell thinning as a major factor. Low reproductive success in Herring Gull colonies at Lake Ontario is associated with high chlorinated hydrocarbon levels in eggs. Fish-eating birds in the Wabigoon River system, northwestern Ontario, are among the most known mercury contaminated birds. It is suggested that the effects of mercury on the reproduction of fish-eating birds should be further examined there.Fish-eating birds occupy the highest levels of the food web and magnification of toxic chemicals through prey organisms in this web makes those birds vulnerable to the effects of environmental contaminants. Since fish-eating birds are present everywhere in Canada's freshwater and marine habitats and occupy various niches there, they may serve as pollution indicators in various food chains of our aquatic environment. Colonial birds are especially valuable indicators as pollution effects on total bird populations can be studied. Baseline information on fish-eating bird populations should now be collected everywhere in Canada for measuring present and future effects of environmental pollutants, as well as other man-made disturbances on their populations.     

Study of Ni sorption onto Tio mine waste rock surfaces

Sorption phenomena are known to play significant roles in metal mobility in mine drainage waters. The present study focuses on sorption phenomena controlling Ni concentrations in contaminated neutral drainage issued from the waste rock piles of the Tio mine, a hematite–ilmenite deposit near Havre-Saint-Pierre, Québec, Canada exploited by Rio Tinto Iron and Titanium. Batch sorption tests were conducted on waste rock samples of different composition and degree of alteration, as well as on the main mineral phases purified from the waste rocks. Sorbed phases were submitted to sequential extractions, XPS and DRIFT studies for further interpretation of sorption phenomena. The results from the present study confirm that sorption phenomena play a significant role in the Tio mine waste rocks, and that the main sorbent phases are the residual ilmenite ore in waste rocks, as well as plagioclase, the main gangue mineral. Sequential extractions suggest that most sorption sites are associated with reducible fractions, and XPS results indicate that Ni is sorbed as the hydroxide Ni(OH)₂. The results from the present study provide useful information on sorption phenomena involved in the Tio mine waste rocks and enable further interpretation of Ni geochemistry in contaminated neutral drainage.     

Search for spatial variation in the jovian N/N ratio from Cassini/CIRS observations

We have used the spectra obtained by the Composite Infrared Spectrometer (CIRS) onboard the Cassini spacecraft to search for latitudinal variation in the ¹⁵N/¹⁴N ratio on Jupiter. We found no variations statistically significant given the observational and model uncertainties. The absence of latitudinal variations demonstrates that ¹⁵NH₃ is not fractionated in Jupiter's atmosphere, and that the measured ¹⁵N/¹⁴N represents Jupiter's global value. Our mean value for the global jovian ¹⁵N/¹⁴N ratio of (2.22±0.52)×10⁻³ agrees with previous measurements made by Fouchet et al. (2000, Icarus 143, 223-243) and Owen et al. (2001, Astrophys. J. 553, L77-L79). We argue that the jovian isotopic ¹⁵N/¹⁴N ratio must represent the solar nitrogen isotopic composition. The solar ¹⁵N/¹⁴N ratio hence significantly differs from the terrestrial value: (¹⁵N/¹⁴N)_⊕=3.68×10⁻³. This supports the proposition that terrestrial nitrogen originates from a nitrogen reservoir isolated from the main nitrogen reservoir in the proto-solar nebula. The origin and carrier of this isolated reservoir are still unknown.     

Measuring proton energies and fluxes using EIT (SOHO) CCD areas outside the solar disk images

An indirect proton flux measuring tool based on discrimination of the energy deposited by protons in 128 × 128 pixel EIT CCD areas outside the solar disk images is presented. Single pixel intensity events are converted into proton incident energy flux using modeled energy deposition curves for angles of incidence ±60° in four EIT spatial areas with different proton stopping power. The extracted proton flux is corrected for both the loss of one‐pixel events in the range of angles of incidence as well as for the contribution to the single pixel events resulting from scattered middle‐energy protons (low‐energy or high‐energy particles are stopped by the EIT components or pass through them, accordingly). A simple geometrical approach was found and applied to correct for a non‐unique relation between the proton‐associated CCD output signal and the incident proton energy. With this geometrical approximation four unique proton incident energy ranges were determined as 45–49, 145–154, 297–335, and 390–440 MeV. The indirect proton flux measuring tool has been tested by comparing Solar Energetic Particles (SEP) flux temporal profiles extracted from the EIT CCD frames and downloaded from the GOES database for the Bastille Day (BD) of 2000 July 14 and the more recent 2005 January 20 events. The SEP flux temporal profiles and proton spectra extracted from the EIT in the relatively narrow energy ranges between 45 and 440 MeV reported here are consistent with the related GOES profiles. The four additional EIT extracted ranges provide higher energy resolution of the SEP data. (© 2006 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim)     

High-resolution spectroscopy of gamma-ray bursts

We report on results from the Goddard germanium Gamma-Ray Burst Spectrometer flown on the ISEE-3 spacecraft. Spectral and temporal studies of two events on 4 and 19 November, 1978 are presented. The power law spectral indices were found to be respectively –1.82 and –1.31, the latter being the hardest event thus far detected. Evidence for two lines in the 4 November event is presented — a broad feature at 420 keV and a narrower one at 740 keV. These are consistent with a common redshift if the parent lines are assumed to be the positron annihilation line (511 keV) and the first excited state of iron (847 keV). If this interpretation is correct, it is shown that additional lines from higher levels of iron and possibly other nuclei are expected and that they may represent a significant contribution to the total spectrum above 1 MeV.Paper presented at the Symposium on Cosmic-Ray Bursts, held at Toulouse, France, 26–29 November, 1979.     

Geostatistical characterization of soil moisture and chloride distribution in deep vadose profiles of the Badain Jaran Desert,Northwestern China

Geostatistical analysis of soil moisture and ion accumulation can provide a deep understanding of aspects of a region’s hydrology such as recharge rates and flow paths. By combining this approach with detrended canonical correspondence analysis, the present study investigated the vertical and spatial variation of soil moisture and chloride (Cl^?) in vadose profiles of megadunes near lakes in the southeastern Badain Jaran Desert, northwestern China. Soil moisture varied vertically within the dune profiles following exponential, logarithmic, or log-normal distributions at different sites as a result of regulation by different local controls. The main local controls for Cl^? concentration were slope and orientation of the dune. Cl^? was not affected by local controls at depths >5 m. Sills of spatial variation in soil moisture and Cl^? in the variogram analysis were highly sensitive to local controls in the top 4 m of the profiles, and the values were three times those at depths >4 m. The lag for soil moisture was insensitive to local controls, and was 50–60 m in the top 4 m of the profiles and 20 m in deeper layers, whereas the lag for Cl^? was about 20 m at all depths. The results demonstrate that understanding recharge rates using factors such as Cl^? accumulation requires a careful survey to ensure that the local controls that regulate these factors are adequately accounted for.     

The effect of tidal inlets on open coast storm surge hydrographs

Bridge scour modeling requires storm surge hydrographs as open ocean boundary conditions for coastal waters surrounding tidal inlets. These open coast storm surge hydrographs are used to accurately determine both horizontal and vertical circulation patterns, and thus scour, within the inlet and bay for an extreme event. At present, very little information is available on the effect that tidal inlets have on these open coast storm surge hydrographs. Furthermore, current modeling practice enforces a single design hydrograph along the open coast boundary for bridge scour models. This study expands on these concepts and provides a more fundamental understanding on both of these modeling areas.     

EVIDENCE FOR THE PRESENCE OF LOW MOLECULAR WEIGHT ALCOHOLS AND CARBONYL COMPOUNDS IN THE MURCHISON METEORITE†

Alcohols, aldehydes and ketones identified in the Murchison C2 chondrite include: methanol, ethanol, 2-propanol, butyl alcohols, formaldehyde, acetaldehyde, propionaldehyde, acetone, 2-butanone, 3-pentanone and 2-pentanone.