Quantitative models for reconstructing catchment ice-extent using physical-chemical characteristics of lake sediments

The physical characteristics of surface sediments from a suite of pristine lakes on Signy Island, maritime Antarctic, were used to develop a quantitative link between catchment ice-extent and lake-sediment response. Percentage dry weight, median particle size, percentage loss-on-ignition and wet density of the lakes' surface sediments were the most significant variables explaining contemporary catchment ice-extent. Two independent reconstruction models – Partial Least Squares (PLS) and a Modern Analog Technique (MAT) – were applied to dated sediment cores at two sites on Signy Island. The validity of the reconstructions was tested against historical information on catchment ice-extent. With sufficiently high sedimentation rates and sampling resolution, the models can predict sub-decadal changes in ice-extent. The model results are best regarded as indicators of erosion resulting from meltwater activity in the catchment. Comparison of results with Twentieth Century climate records affirms the hypothesis that climatic warming is the most likely cause for the ice retreat observed on Signy Island during the last 40 yrs. Similar reconstruction models using these simple sedimentary measures could be developed for analogous locations in the Antarctic and in Arctic and Alpine regions.     

A measurement of the O2 ultra-violet nightglow emission

New measurements of the Herzberg I emission height profile in the night airglow are reported and indicate a peak emission height near 96 km in agreement with previous measurements. Using an atomic oxygen concentration profile determined from the oxygen green line profile measured on the same rocket it is concluded that the O₂(A³Σ_u⁺) state is not excited in the direct three body recombination of atomic oxygen. It is suggested that the excitation mechanism is a two step process, similar to the Barth mechanism for the atomic oxygen green lineand that the excited intermediate state is C³Δ_u.     

The new gravity base net 1976 of the Federal Republic of Germany (DSGN 76)

A new gravity base net (“Schweregrundnetz 1976 der Bundesrepublik Deutschland”, DSGN 76) has been established in the Federal Republic of Germany, to meet the increased requirements of geophysics, geology, metrology and geodesy. The net comprises 21 stations with three excenters each. The gravity values were determined using 4 absolute stations, 11 IGSN71-stations and about 3000 relative gravity meter observations with 4 gravity meters. Instrumental investigations and special treatment of local tidal and atmospheric effects improved the data for the least squares adjustment, which was performed by the method of observation equations following the use of condition equations. The final adjustment showed a point r.m.s. error of about 10μGal[10^?8 ms^?2]. Detailed results will be published in the ”Veröffentlichungen der Deutschen Geodätischen Kommission”.     

Exploring the effects of urban and agricultural land use on surface water chemistry,across a regional watershed,using multivariate statistics

In this paper, the influence of anthropogenic activity on surface water chemistry is investigated. Base flow samples from dominant land use streams in the Muskegon River Watershed, Michigan, USA, were analyzed for nutrients, major ions, and trace elements. Principal component and hierarchical cluster analysis were used to investigate the processes controlling the effects of land use on the biogeochemistry of streams in this Watershed. Biogeochemical fingerprints of land use were developed based on the results of the cluster analysis. Spider diagrams which referenced the natural environment aided the identification of the individual contributions of urban and agricultural land uses to surface water chemistry. The biogeochemical fingerprints quantified support previous findings (Urb: Na, K, Cl/Ag: Ca, Mg) and produced new insights into the effects of land use on the behavior of nutrients (Ag: N and Urb: N, P) and trace elements (Urb: V, Cr, Co, Cu, Se, Rb, Mo, Sr, Cd, Pb and Ba/Ag: U and As). The higher correlations of urban than agricultural land uses with nutrients, specifically P, were not expected and may reflect the effects of fertilization and wastewater or the season the samples were taken. More study in different geologic and urban settings is needed to help refine these fingerprints, but it is becoming apparent that despite obscuring factors, land use produces consistent, quantifiable associations between biogeochemical analytes.     

Detrital iron-ore deposits in the Iron Ore Group of rocks,northern Orissa,eastern India

Detrital iron deposits (DID) are located adjacent to the Precambrian bedded iron deposit (BID) of Joda near the eastern limb of the horseshoe-shaped synclinorium, in the Bonai–Keonjhar belt of Orissa. The detrital ores overlie the Dhanjori Group sandstone as two isolated orebodies (Chamakpur and Inganjharan) near the eastern and western banks of the Baitarani River, respectively. The DID occur as pebble/cobble conglomerates containing iron-rich clasts cemented by goethite. Mineralogy, chemistry and lamination of these clasts are similar to that found in the nearby BID ores. Enrichment of trace and rare-earth elements in the DID relative to the BID is attributed to their concentration during the precipitation of cementing material. The detrital iron orebodies formed when Proterozoic weathering processes eroded pre-existing BID outcrops located on the Joda Ranges, and the resulting detritus accumulated in the paleochannels. In situ dissolution in association with abundant organic material produced Fe-saturated groundwater, which re-precipitated as goethite within the aggraded channel to cement the detritals. Growth of microplaty hematite in the goethite matrix suggests some level of subsequent burial metamorphism.     

Geology, Mineralogy, and Formation Environment of the Disseminated Gold-Silver Telluride Bulawan Deposit, Negros Occidental, Philippines

Abstract: The Bulawan deposit is located in the porphyry copper belt of southwest Negros island, Philippines. Propylitic, K–feldspar, sericitic, and carbonate alteration types can be distinguished in the deposit. Propylite alteration occurs mainly in Cretaceous-Eocene andesitic lavas and agglomerates while K–feldspar, sericite and carbonate alteration types occur mostly in the Middle Miocene dacite porphyry breccia pipes and stocks which were intruded into the andesites. K-feldspar zones occur in the inner parts of the sericitized zone. Sericite alteration overprinted the propylitized and K-feldspar alteration zones, at lower temperature than epidote and chlorite in the propylitized zone. Carbonate alteration is associated with the mineralization in the center of the breccia pipes and along faults. Mineralization consists of gold-silver telluride ores that are hosted by the carbonate– and sericite-altered dacite porphyry breccia pipes. The Bulawan ores occur mainly as disseminations, but unlike many epithermal gold deposits, lack classical epithermal colloform and crustiform quartz veins. The ore minerals are sphalerite, galena, chalcopyrite, pyrite and tetrahedite-tennantite with minor amounts of electrum, calaverite, petzite, sylvanite, hessite, tellurobismuthite, coloradoite, altaite, and rucklidgeite. Electrum and telluride minerals are associated mostly with calcite and dolomite-ankerite minerals. Fluid inclusions in quartz and calcite in clasts of propylitized andesite in the breccia pipes homogenize from about 300° to 400°C while fluid inclusions in quartz, calcite and sphalerite within the dacite porphyry breccia pipes homogenize between 300° to 310°C. The ores were formed around 300°C from hydrothermal solutions with salinity of about 6. 6 wt % NaCl equivalent. The presence of sylvanite and calaverite as intergrowths with each other, and the Ag content of calaverite are consistent with the above temperature estimate. Based on paragenesis, the Bulawan deposit formed in a pyrite-stable environment, with pH between 3. 4 and 5. 5, f_O2 between 10^-32 to 10^-30 atm, f_S2 between 10^-9.8 to 10^-7.8 atm, f_Te2 between 10^-8.9 to 10^-6.5 atm, and total sulfur content about 10^-2.8 molal. The dominant reduced sulfur species in the ore solutions may have been H₂S_(aq), and the likely aqueous tellurium species were H₂Te_(aq) and H₂TeO_3(aq). The ore minerals in the Bulawan deposit were probably formed by mixing of slightly saline and low salinity fluids.     

CCD photometry of five X-ray selected BL Lacertae objects

We present the results of the monitoring of a sample of 5 HBLs in the B, V and R bands during 2003–2008. All sources in our monitoring project show significant rapid optical variations, except 1ES 1959+650, however; for 1ES 1959+650, the gamma-ray variability on a timescale of ～7 hours has been observed by Holder et al. (Astrophys. J. 583:L9, 2003). Using these variability timescales, we estimate the black hole masses for each source with the Kerr black hole theory.     

The Stanley unconformity in Lake Huron basin: evidence for a climate-driven closed lowstand about 7900 <Superscript>14</Superscript>C BP,with similar implications for the Chippewa lowstand in Lake Michigan basin

J.L. Hough in 1962 recognized an erosional unconformity in the upper section of early postglacial lake sediments in northwestern Lake Huron. Low-level Lake Stanley was defined at 70 m below present water surface on the basis of this observation, and was inferred to follow the Main Algonquin highstand and Post-Algonquin lake phases about 10 ¹⁴C ka, a seminal contribution to the understanding of Great Lakes history. Lake Stanley was thought to have overflowed from the Huron basin through the Georgian Bay basin and the glacio-isostatically depressed North Bay outlet to Ottawa and St. Lawrence rivers. For this overflow to have occurred, Hough assumed that post-Algonquin glacial rebound was delayed until after the Lake Stanley phase. A re-examination of sediment stratigraphy in northwestern Lake Huron using seismic reflection and new core data corroborates the sedimentological evidence of Hough’s Stanley unconformity, but not its inferred chronology or the level of the associated lowstand. Erosion of previously deposited sediment, causing the gap in the sediment sequence down to 70 m present depth, is attributed to wave erosion in the shoreface of the Lake Stanley lowstand. Allowing for non-deposition of muddy sediment in the upper 20 m approximately of water depth as occurs in the present Great Lakes, the inferred water level of the Stanley lowstand is repositioned at 50 m below present in northwestern Lake Huron. The age of this lowstand is about 7.9 ± 0.3¹⁴C ka, determined from the inferred ¹⁴C age of the unconformity by radiocarbon-dated geomagnetic secular variation in six new cores. This relatively young age shows that the lowstand defined by Hough’s Stanley unconformity is the late Lake Stanley phase of the northern Huron basin, youngest of three lowstands following the Algonquin lake phases. Reconstruction of uplift histories for lake level and outlets shows that late Lake Stanley was about 25–30 m below the North Bay outlet, and about 10 m below the sill of the Huron basin. The late Stanley lowstand was hydrologically closed, consistent with independent evidence for dry regional climate at this time. A similar analysis of the Chippewa unconformity shows that the Lake Michigan basin also hosted a hydrologically closed lowstand, late Lake Chippewa. This phase of closed lowstands is new to the geological history of the Great Lakes. This is the ninth in a series of ten papers published in this special issue of Journal of Paleolimnology. These papers were presented at the 47th Annual Meeting of the International Association for Great Lakes Research (2004), held at the University of Waterloo, Waterloo, Ontario, Canada. P.F. Karrow and C.F.M Lewis were guest editors of this special issue.