Redetermination of the transformation enthalpies of the xanthoconite–proustite, pyrostilpnite–pyrargyrite and trechmannite–smithite phase transitions

 We report here refined values of the transformation enthalpy for xanthoconite to proustite (54.81 kJ/mol) and pyrostilpnite to pyrargyrite (40.32 kJ/mol). Additionally, the enthalpy for the transformation of trechmannite to smithite (5.82 kJ/mol) has been determined. The refinement was possible by taking into account a previously unknown dependence of electrochemical signals on the amount of substance undergoing the reduction process. Received December 21, 1995/Revised, accepted June 29, 1996     

ELNES spectroscopy of mixed Si coordination minerals

 Si K- and L-edge ELNES spectroscopy and multiple-scattering (MS) calculations are used to examine mixed Si coordination compounds varying in Si^VI:Si^IV ratio. As in previous studies, the edges are influenced mainly by silicon coordination (tetrahedral vs. octahedral), as supported by the MS calculations. We demonstrate two methods semi-quantitatively to extract the value of Si^VI/(Si^VI+Si^IV): (1) A linear relationship between the L_2,3-L₁ splitting and Si^VI/(Si^VI+Si^IV) is observed, (2) a fitting method based on the coaddition of reference tetrahedral and octahedral Si spectra is applied to both Si K- and L-edge ELNES spectra. Received: February 10, 1997 / Revised, accepted: May 23, 1997     

Distribution of isomorphous cations within octahedral sheets in montmorillonite from Camp-Bertaux

 Ni-saturated montmorillonite from Camp-Bertaux heated at different temperatures has been studied by X-ray powder diffraction, X-ray absorption (EXAFS) and vibration IR spectroscopy. Analysis of the experimental data has shown that heating of samples at temperatures higher than 150° C was accompanied by migration of Ni cations into vacant cis-octahedra of 2:1 layers. In the octahedral sheet the Ni cation has two “heavy” (Fe) and four “light” (Al and Mg) nearest octahedral cations. A model for the octahedral cation distribution in Camp-Bertaux montmorillonite was proposed in which Fe and Mg octahedral cations are segregated in small clusters. Received July 7, 1996 / Revised, accepted August 23, 1996     

人地非线性相关作用的探讨

从自组织系统思想出发，提出了人地关系的基本特性，通过逻辑斯蒂听数学变换，分析了人地非线性相关作用的混沌特性，进而讨论了人地关系的分形性质。基于混 过程与分形结构的因果关系，指出：地球表层系统中的人文分形景观乃是人地非线性关系的混沌作用所致。     

中国汽车工业──改革开放后的重整与国际化

大规模的重整和广泛的国际化是改革开放后中国汽车工业发展的两个主要特征。作者首先从企业组织结构、生产能力与品种结构、规模经济和空间分布等四个方面分析了近二十年来中国汽车工业重整的效果及所形成的行业特征;其次根据利用的外资和技术的来源以及涉及的技术形态分析了其国际化的程度及在世界汽车工业中的位置;最后总结了中国汽车工业面临的若干问题,并提出在散乱的格局和跨国公司竞争的双重压力下,中国汽车工业正处于成长的关键时期。     

用GMS卫星资料反演复杂地形下的降水率

强降水主要由生命史短的中小尺度天气系统造成,对此类天气系统的预报,目前只有依靠卫星和雷达的实时监测并结合中系统的概念模式外推来完成。由于中国西北地区地形极为复杂,造成雷达盲区,影响其估算降水率。因此采用GMS-4卫星的红外和可见光展宽云图资料,经处理并转换后,再加入相应网格点上的数字化地形高度资料作为因子之一,用多级逐步判别模式估算逐时雨强等级,最后形成一套可在微机上对雨强场进行图像显示及处理的软件系统,满足了现时预报的需要。结果表明,小雨以上的降雨区域不论面积、形状均与实况基本一致。     

泥炭档案气候变化重建的定量模型

泥炭档案气候变化重建的定量模型＊陶发祥洪业汤（中国科学院地球化学研究所，贵阳５５０００２）李汉鼎冷雪天（东北师范大学地理系，长春１３００２４）关键词泥炭档案纤维素稳定同位素气候变化定量模型用泥炭档案定量重建大气ＣＯ２浓度的研究已取得重要进展［１］，但...     

燕辽地区火山热液型铀－金－多金属矿床成矿特征

燕辽地区位于华北地台北缘东段，是我国著名的中生代火山热液型铀、金、多金属矿床成矿区。研究结果表明，其成矿作用受统一的晚中生代大陆裂陷火山岩浆活动控制；成矿时代集中在晚侏罗世及早白垩世；成矿介质为火山岩浆水、变质水和大气水混合的中温、中低温火山热液；成矿物质主要来自富集型的上地幔及下地壳。     

Diatom assemblages from Costa Rican lakes: an initial ecological assessment

We compared the distributions of 59 diatom species in surface sediments of 25 Costa Rican lakes with 21 environmental variables using canonical correspondence analysis (CCA). The distribution of taxa was related to the chemical and physical characteristics of the lakes. The most influential chemical variables were cation concentrations (especially magnesium) and related variables such as water hardness, pH, and temperature. Lake area and lake depth were among the most important physical variables.A number of taxa were identified as potential environmental indicators. The diatoms Brachysira serians var. brachysira and Frustulia rhomboides seem to be associated with low values of alkalinity, hardness, Ca, Mg, and SiO2. Cymbella minuta var. silesiaca is associated with low to moderate values of alkalinity, hardness, Ca, and Mg. Nitzschia cf. amphibia may be an indicator of moderate-to-high concentrations of Mg. Pinnularia braunii var. amphicephala seems to prefer low values of hardness, Ca, Mg, and SiO2.In many closed lakes, these environmental variables (Mg/Ca/hardness/alkalinity) increase with effective evaporation. Consequently, these diatoms may be indirectly tracking P:E ratios. Results from this initial, small data set indicate the potential of diatoms for inferring lake paleochemistry, and perhaps P:E ratios, in Costa Rica.     

Diatoms in sediments of perennially ice-covered Lake Hoare, and implications for interpreting lake history in the McMurdo Dry Valleys of Antarctica

Diatom assemblages in surficial sediments, sediment cores, sediment traps, and inflowing streams of perennially ice-covered Lake Hoare, South Victorialand, Antarctica were examined to determine the distribution of diatom taxa, and to ascertain if diatom species composition has changed over time. Lake Hoare is a closed-basin lake with an area of 1.8 km², maximum depth of 34 m, and mean depth of 14 m, although lake level has been rising at a rate of 0.09 m yr^-1 in recent decades. The lake has an unusual regime of sediment deposition: coarse grained sediments accumulate on the ice surface and are deposited episodically on the lake bottom. Benthic microbial mats are covered in situ by the coarse episodic deposits, and the new surfaces are recolonized. Ice cover prevents wind-induced mixing, creating the unique depositional environment in which sediment cores record the history of a particular site, rather than a lake-wide integration. Shallow-water (<1 m) diatom assemblages (Stauroneis anceps, Navicula molesta, Diadesmis contenta var. parallela, Navicula peraustralis) were distinct from mid-depth (4–16 m) assemblages (Diadesmis contenta, Luticola muticopsis fo. reducta, Stauroneis anceps, Diadesmis contenta var. parallela, Luticola murrayi) and deep-water (26–31 m) assemblages (Luticola murrayi, Luticola muticopsis fo. reducta, Navicula molesta). Analysis of a sediment core (30 cm long, from 11 m water depth) from Lake Hoare revealed two abrupt changes in diatom assemblages. The upper section of the sediment core contained the greatest biomass of benthic microbial mat, as well as the greatest total abundance and diversity of diatoms. Relative abundances of diatoms in this section are similar to the surficial samples from mid-depths. An intermediate zone contained less organic material and lower densities of diatoms. The bottom section of core contained the least amount of microbial mat and organic material, and the lowest density of diatoms. The dominant process influencing species composition and abundance of diatom assemblages in the benthic microbial mats is episodic deposition of coarse sediment from the ice surface.