张八岭地区变质地层序列与构造型式

运用构造与地层相结合的理论和方法，通过对张八岭地区已完成和正在进行的１０幅１：５万地质填图资料分析和典型地区的构造追踪，初步认为：北将军（岩）组自下而上分为三段，时代置于中元古代，获铅同位素年龄样值为１８２１±４１６Ｍａ；西冷（岩）组自下而上分为三段，时代置于青白口纪。区内主要存在三期构造交形：早期为一系列呈ＮＷＷ－近ＥＷ向的紧闭同斜褶皱，中期以韧性剪切带发育为特征，晚期以ＮＮＥ向为主的宽缓褶皱。三期变形共同叠加，形成区内基本构造格架。并对变形机制作初步探讨。     

Origin of Natural Gas in Kekeya Field, Tarim Basin, China

This paper is mainly concentrated on the geochemical characteristics and origin of gas of Kekeya field in the Tarim basin, NW China. This study shows that Permian mudstone is the main source rock of oil and gas. Based on the carbon isotopes of C1--C4, the carbon isotope of gas in Kekeya field is a little heavier than that in the typical marine-derived gas. The relationship between carbon isotopes of methane and ethane is coincident with Faber equation of gas derived from organic matter Ⅰ/Ⅱ. The majority of gas maturity is estimated, based on the formula, at 1.8%-2.2% besides K2 and K18 wells. In addition, the gas derived from 0.9%-1.2% Ro source rocks may also bemixture. ^40Ar/^36Ar and ^3He/^4He ratios from the gas samples also support the mixing process. Moreover, the gas in this region is mainly generated from more mature source rocks although the low mature gas exists.     

三峡库区消落区土壤磷释放的环境影响因子

以三峡库区消落区万州段为试验基地,选取释磷能力较强的紫色冲积土,根据三峡水库消落带的"干湿交替"空间和时间特征,进行万州断面土壤磷释放的影响因子的实验室模拟试验和万州江面淹没的对照试验。研究发现,随着淹水时间的变化,各种形态的磷在前5~10d各形态磷变化有相当的差异,随后变化趋势趋于稳定。TP有降低的趋势,土壤磷有一定的释放。野外研究表明Olsen-P在淹水10周左右到达最大值,以后缓慢降低。淹水时土壤Olsen-P增加,干燥后降低。多次淹水时每次淹水后土壤的有效磷水平都略有增加,落干后相较上次落干后有效磷水平降低,最后一次淹水后相较与初始时Olsen-P水平低16.7%。随着淹水深度增加,土壤的Olsen-P水平在淹水时由淹水前20.53mg/kg提高到43.23mg/kg,增加110.6%。当上覆水磷浓度较低时(<2mg/L),磷吸附到达平衡的时间较短,约需要6周。当上覆水磷浓度较高(>2mg/L)时,磷吸附到达平衡的时间较长。微生物活动对淹水土壤的磷释放有一定影响,有微生物时磷的释放高于无微生物者0.048mg/L。种植植物的土壤在淹水后Olsen-P含量大于土壤直接淹没时的释放量,种植狗牙根(Cynodondactylon)和野地瓜藤(Ficustikoua)的土壤中Olsen-P分别较未种植物土壤释放量高出21.5%和12.7%。     

全球温度变化的热力学平衡和最新发现

本文提出了一种新的研究全球气候温度变化的思路。为发现全球气候变化的宏观规律,把生物圈系统作为一个整体的物质进行研究,从而把纷繁复杂的全球气候温度变化问题归纳成经典物理学的热量与温度变化问题。给出了广义生物圈的热平衡测量Q值和温度变化的热力学公式,并在实际数据的基础上通过计算发现人类使用矿物燃料和核能所排放的热量理论上可使全球海平面每年升高35 mm或者可使大气对流层温度每年升高011 ℃。该发现表明:能源热量因素已成为影响全球温度变化的重要因素。     

Levels, seasonal variations, and health risks assessment of ambient air pollutants in the residential areas

People living in the urban area and the surrounding suburban area have disparities in exposure and health risks due to different levels of ambient air pollutants. The main objective of this study is to investigate the concentrations, seasonal variations, and related health risks of ambient air pollutants (PM₁₀, NO₂, and SO₂) in urban and suburban areas of Ningbo, China. The results showed that the average PM₁₀, NO₂, and SO₂ concentrations in the urban area were 85.2, 49.3, and 37.4 μg/m³, which were 1.13, 1.25, and 1.41 times the values of the suburban area during the period of March 2009 to February 2010. For the potential health risk analysis, the residents have been divided into four age categories namely, infants, children (1 year), children (8–10 years), and adults. The analysis took into account age-specific breathing rates, body weights for different age categories. The results showed that the potential health risks to respiratory disease for all age categories living in urban area were higher than those in suburban area.     

Nucleation and crystallization of otavite, witherite, calcite, strontianite, hydrozincite, and hydrocerussite by CO2 membrane diffusion technique

Otavite, witherite, calcite, strontianite, hydrozincite and hydrocerussite nucleation was induced by CO₂ diffusion through a polyethylene membrane into a metal bearing solution. Nucleation and ongoing precipitation was followed at 25 ± 1 °C by the chemical evolution of the solution and the consumption of sodium hydroxide (pH-stat conditions). X-ray diffraction patterns as well as FT-infrared and Raman spectra confirmed the formation of well crystallized solids, except for less crystalline hydrozincite. In several experiments simonkolleite and laurionite precipitated concurrently with hydrozincite and hydrocerussite. The carbonate end-member minerals, smithsonite and cerussite, however were not formed. Carbonate minerals crystallized as spherical aggregates of thin layered otavite, spherical orientated witherite needles, rhombohedral calcite, pseudo-hexagonal strontianite laths, fibrous lumps of hydrozincite and planar hexagonal hydrocerussite crystals. Crystal and aggregate sizes range between 1 and 100 μm. Nucleation occurred at well defined reaction times and distinct critical supersaturation indices (SI_crit). The time for nucleation at constant pH decreased as the initial metal concentration increased for a given solid. The SI_crit values decreased in the order of hydrocerussite (3.2), otavite (2.5), strontianite (1.6), witherite (0.9) and calcite (0.7).     

Study on Three-dimensional Visualization for Rock Structure

The visualization of rock structure is a very useful and important technique in many aspects in geological and geotechnical engineering such as investigating and evaluating the stability of a high rock slope. The conventional method used to visualize rock structure is limited to plotting the orientation of individual discontinuities by using the Schmidt stereographic net. The present paper shows a new technique to visualize the three-dimensional structure of rock masses. The fitting function for three-dimensional rock structure was established based on data gathered from field survey. Two fitting methods by which the discontinuous points gathered from a plane and discrete points from field survey were fitted respectively are suggested. The technique to visualize the three-dimensional structure of rock masses includes many aspects such as projection transformation, blanking and mutual cutting, are investigated. Based on the visualizing technique, the rock structure at the site of Xilupdu dam which is being built in Southwest of China was investigated.     

Investigating the effect of soil models on deformations caused by braced excavations through an inverse-analysis technique

In this study, a series of inverse-analysis numerical experiments was performed to investigate the effect of soil models on the deformations caused by excavation by using the finite element method. The nonlinear optimization technique that was incorporated into the finite element code was used for the inverse-analysis numerical experiments. Three soil models (the hyperbolic model, pseudo-plasticity model, and modified pseudo-plasticity model) were employed in the intended numerical experiments on a well-documented excavation case history. The results indicate that wall deflection due to excavation can be accurately back-figured by each of the three soil models, while the ground surface settlement can be reasonably optimized only by the pseudo-plasticity model and the modified pseudo-plasticity model. Importantly, the modified pseudo-plasticity model can yield more reasonable simulations when the wall deflection and the ground surface settlement are simultaneously back-figured. The results show that selection of an adequate soil model that is capable of adequately describing the stress–strain-strength characteristics of the soils is essentially crucial when predicting the excavation-induced ground response.     

研究地球化学机制的热动力学方法

章介绍了热动力学方法的研究历史，研究原理以及在研究地球化学机制中的应用，如石膏的脱水反应机制可分二步进行，ＣａＳｏ４．２Ｈ２Ｏ→ＣａＳＯ４．１／２Ｈ２Ｏ→ＣＳＯ４活化能Ｅ＝１１８．７ＫＪ／ｍｏｌ，脱水温度Ｔ＝３８０．６０，呱应速率Ｋ１＝４．４１×１０＾－４Ｓ＾－１方解石的溶解反应机制，在０－５０００Ｓ期间以溶解反应为主，嗣后，发生周期性的溶解反应，热谱图上表现为化学振荡。     

Umbral oscillations and penumbral waves in Hα

We present examples of umbral oscillations observed on Big Bear H filtergram movies and investigate the relation between umbral oscillations and running penumbral waves occurring in the same sunspot. Umbral oscillations near the center of the umbra are probably physically independent of the penumbral waves because the period of these umbral oscillations (150 s) is shorter than the penumbral wave period (270 s) but not a harmonic. We also report dark puffs which emerge from the edge of the umbra and move outward across the penumbra, and which have the same period as the running penumbral waves. We interpret these dark puffs to be the extension of chromospheric umbral oscillations at the edge of the umbra. It is suggested that the dark puffs and the running penumbral waves have a common source: photospheric oscillations just inside the umbra.