电子探针分析与系列矿物研究

本文论述以电子探针为主要测试手段对下述几种系列矿物的研究成果:(1)铂族元素系列矿物的研究(包括Ru-Os-Fe金属互化物矿物系列和RuAs_2-OsAs_2二元固溶体矿物系);(2)Au-Cu系列矿物的研究;(3)黝铜矿族矿物的研究。     

Downstream patterns of bed sediment-borne metals,minerals and organic matter in a stream system receiving acidic mine effluent: A preliminary study

Different downstream variation patterns were observed for a range of bed sediment-borne metals (aqua regia-extractable fraction) in a subtropical stream system receiving acid mine drainage. Mine-originated Fe tended to be deposited in the acidic (mean pH < 4.9) upstream reach in forms of goethite and/or hematite. In contrast, other metals tended to be transported farther downstream and settled in a low-gradient reach with high pH (mean pH > 5.6). The peak of sediment-borne Al, Be, Ca, Cd, Co, Cu, La, Mn, Ni and Zn corresponded very well with the peak of the sediment-borne organic matter, suggesting a close association between the water-borne organic colloids and the inorganic metal oxides/hydroxides during their transport. The marked increase in the sediment-borne Al and Pb started more upstream than the other metals, suggesting that the water-borne Al and Pb were more susceptible to pH rise-induced precipitation, as compared to the other metals. It appeared that the organic colloids played no important role in Pb transport and settlement. The iron precipitates had a limited role to play in affecting the transport and fates of other metals since they were predominantly formed and deposited in the acidic reach, which made them incapable of scavenging cationic metals by co-precipitation or adsorption.     

河流深槽沉积体与油气的关系——以辽河坳陷大25井区为例

河流深槽沉积体是河流沉积的一种特殊沉积体。辽河坳陷第三纪断裂活动强烈，火山岩广泛分布，形成了独特的地貌条件，具备形成河流深槽沉积体的地质条件。本文以辽河坳陷东部凹陷大２５井区为例，对河流深槽沉积体的成因及特征进行探讨，证实了大２５井区巨厚砂砾岩沉积是河流在火山岩古地形的限制下发生急转弯，在其变曲河段的深槽中沉积的深槽沉积体。该沉积体中发育良好的储集空间，有利于油气储集。该类储集体的发现，丰富了辽河坳陷的储层类型，为油气勘探提供了新的领域。     

膏盐岩脆塑性变形特征及封闭能力定量评价

膏盐岩盖层作为全球许多含油气盆地最重要的盖层之一,本身物性封闭能力毋庸置疑,野外观察和三轴试验证实随埋深的增加膏盐岩存在脆塑性转化的过程。为了明确其在不同脆塑性域的变形特征和封闭能力定量评价方法,本文以野外露头观测、三轴压缩试验和镜下观察为基础,从变形机制、破裂模式、力学行为和声发射等方面系统总结了不同脆塑性阶段膏盐岩的变形特征。应用莫尔—库伦准则、拜尔利摩擦定律和应力降规律厘定了膏盐岩脆塑性转化的围压和深度。研究结果表明:1针对脆性膏盐岩盖层,首先应用保持力定量评价水力破裂风险性,保持力越小,盖层发生水力破裂的风险就越大。同时利用断接厚度定量表征脆性盖层内断层垂向封闭性;2应用SSF定量评价脆—塑性膏盐岩盖层中涂抹型断裂的垂向封闭性,野外断层解剖确定出膏岩涂抹连续的临界SSF值为3.5~4;3塑性膏盐岩盖层具有流动特征,伴随断层逆冲滑动,膏盐岩沿断面流动,此阶段断层垂向是封闭的,但在差异压实作用下,盐岩流动形成缺失区——"盐窗"可以为油气沿断层向上运移提供通道。因此,膏盐岩盖层封闭性分析要综合考虑盖层脆塑性、不同脆塑性盖层内断裂变形机制及断裂带内部结构,从而完善盖层垂向封闭性评价体系。     

Water Self-Softening Processes at Waterfall Sites

Many rivers in tropical and subtropical karst regions are supersaturated with respect to CaCO3 and have high water hardness. After flowing through waterfall sites, river water is usually softened, accompanied by tufa formation, which is simply described as a result of water turbulence in fast-flowing water. In this paper, a series of laboratory experiments are designed to simulate the hydrological conditions at waterfall sites. The influences of air-water interface, water flow velocity, aeration and solid-water interface on water softening are compared and evaluated on a quantitative basis. The results show that the enhanced inorganic CO2 outgassing due to sudden hydrological changes occurring at waterfall sites is the principal cause of water softening at waterfall sites. Both air-water interface area and water flow velocity increase as a result of the "aeration effect", "low pressure effect" and "jet-flow effect" at waterfall sites, which greatly accelerates CO2 outgassing and therefore makes natural w     

中国东部断陷湖盆细粒沉积岩岩相划分方案探讨——以渤海湾盆地南部古近系细粒沉积岩为例

细粒沉积岩岩相研究是烃源岩和页岩油、致密油储层研究的重要基础,鉴于我国陆相断陷湖盆环境多变和细粒沉积岩类型多样、岩石组合类型复杂的特点,需要进行细粒沉积岩岩相分类。以渤海湾盆地南部古近系细粒沉积岩发育段为研究对象,通过厘米级岩芯观察描述、岩石薄片鉴定、激光共聚焦显微镜观察分析等技术,研究细粒沉积岩基本特征。陆相断陷湖盆细粒沉积岩岩相划分可以按照(1)宏观岩芯精细观察描述,归纳垂向岩石类型组合;(2)分析沉积微环境;(3)对不同岩石类型组合进行X射线全岩矿物衍射和TOC测试,划分岩石类型和岩相大类;(4)微观镜下剖析纹层叠置关系;(5)分析成因和形成机制,对岩亚类细分等5步进行。岩相大类划分要简洁,是为满足油田勘探工作易于操作、建立与常规测井资料之间关系等要求;亚类细分是便于研究微观源储关系、分析沉积微环境和储层微观结构等。     

灌注桩导管爆管与瘪管的原因分析

水下混凝土灌注是钻孔灌注桩施工中最关键工序之一,超深孔水下混凝土灌注的导管偶尔会出现爆管与瘪管现象。通过对导管受力分析,从理论上分析了造成爆管和瘪管现象的直接原因,从实践中罗列出可能导致爆管与瘪管的各种因素,并提出预防措施,有利于超深孔水下混凝土灌注质量的控制。