Volatilization properties of gasoline components in soils

Understanding the volatilization properties of gasoline components in soils is of fundamental importance in the field of geoenvironments. A series of experiments were performed to investigate the effects of temperature, soil water content, soil organic matter content, as well as mean particle size on volatilization rate of total petroleum hydrocarbons (TPH) and the paraffin (n-paraffin and isoparaffin), olefin, naphthene, and aromatic (PONA) components in four typical Japanese soils. The results of this study can be summarized as follows. (1) Volatilization rate of gasoline in a soil is concentration-dependent; extensive volatilization occurs above a certain threshold, while volatilization becomes very slow below this threshold. (2) Compared to other factors, temperature and soil organic matter content have greater effects on volatilization rate of gasoline in soils. The volatilization rate is proportional to temperature, but inversely related to soil organic matter content. (3) The characteristics of time-dependent decreases of TPH and PONA components in soils are similar. The volatilization rate of olefin is higher than those of other components. In addition, volatilization of olefin is also more sensitive to temperature as well as organic matter content.     

Discriminating residual and colluvial soils using topographic analysis in a small,forested catchment in Japan

Soil moisture plays an important role in hydrology. Understanding factors (such as topography, vegetation, and meteorological conditions) that influence spatio‐temporal variability in soil moisture, and how this influence is manifested, is important for understanding hydrological processes. A number of distributed (quasi‐)physical hydrological models have been developed to investigate this subject. Previous studies have shown that the spatial differences in the distribution of soil types (residual and colluvial soils) dominantly reflect spatio‐temporal fluctuations in soil moisture and runoff. We present a methodology for assessing the spatial distribution of residual and colluvial soils, which differ with respect to their physical characteristics, in a 0·88 km² forested catchment with complex topography and a complex land‐use history. Our method is based on penetration resistance profile data; in this data set, each data point represents soil physical characteristics within an area of about 25 m². If the spatial distribution of soils under similar meteorological, geological, historical land use, and other conditions could be characterized on the basis of similarity in topographic features, then the spatial distribution of soil could be predicted based on relationships between various topographic indices (e.g. topographic index and local slope). We tested whether our model correctly assessed the reference data. The model's results were 90·5% correct for residual soils and 87·3% correct for colluvial soils. Further studies will quantify the relationships between topographic features of land covered by residual and colluvial soils and changes in spatio‐temporal variations in the catchment (e.g. vegetation and land use) as a function of geology or meteorology. Copyright © 2007 John Wiley & Sons, Ltd.     

Mineral Components and Anti-oxidant Activities of Tropical Seaweeds

Seaweeds are known to hold substances of high nutritional value; they are the richest resources of minerals important to the biochemical reactions in the human body. Seaweeds also hold non-nutrient compounds like dietary fiber and polyphenols. However, there is not enough information on the mineral compounds of tropical seaweeds. Also we are interested in the antioxidant activities of seaweeds, especially those in the tropical area. In this study, Indonesian green, brown and red algae were used as experimental materials with their mineral components analyzed by using an atomic absorption spectrophotometer. The catechins and flavonoids of these seaweeds were extracted with methanol and analyzed by high performance liquid chromatography （HPLC） ; the anti-oxidant activities of these seaweeds were evaluated in a fish oil emulsion system. The mineral components of tropical seaweeds are dominated by calcium, potassium and sodium, as well as small amounts of copper, iron and zinc. A green alga usually contains epigallocatechin, gallocatechin, epigallocatechin gallate and catechin. However, catechin and its isomers are not found in some green and red algae. In the presence of a ferrous ion catalyst, all the methanol extracts from the seaweeds show significantly lower peroxide values of the emulsion than the control, and that of a green alga shows the strongest anti-oxidant extract of this alga, which is significantly different from activity. The highest chelation on ferrous ions is also found in the the other methanol extracts in both 3 and 24 h incubations.     

Construction of Wide Field Cryogenic Telescope

We constructed a wide field cryogenic telescope (WFCT) containing a whole Ritchey-Chrétien system and a focal plane array in a cryostat for near infrared observations to cover the field of view of 0.4°. The telescope has a primary mirror of 220 mm and an engineering grade 256 × 256 InSb array. The optical components such as two mirrors, filters, spiders, and radiation shield tube are cooled down to 180 K as well as the InSb array to 35 K by a mechanical refrigerator. We show the results of the background surface brightnesses and the limiting magnitudes at 3.3 and 3.67 μm measured at Sutherland, South Africa. We describe the on-going upgrade of this instrument, equipped with a 1024 × 1024 ALADDIN InSb science grade array. This revised version was published online in July 2006 with corrections to the Cover Date.     

Geospatial Information and Environmental Isotopes for Hydrogeological Evaluation: Ras Alam El Rum,Northwestern Coast of Egypt

The present study demonstrates the potential of the geospatial information as well as isotopes and chemical analyses to elucidate the hydrogeological setting of the study area. The main objective of this research is to identify factors affecting the occurrence and quality of groundwater in the study area. The Ras Alam El Rum is the pilot area chosen in the northwestern coast of Egypt to evaluate the carbonate aquifer with emphasis on the Middle Miocene aquifer, which has been explored recently. The average of annual precipitation and surface runoff amounts were estimated to indicate possibility of groundwater recharge, where the water-bearing rocks are mainly fractured. The isotope data indicate that the groundwater was derived from rainwater, the recharge source is local precipitation, and no indication of seawater intrusion was recorded. The salinity of the groundwater is attributed to interaction between the water and aquifer rocks represented by limestone, dolomitic limestone, and marl. The mineral indices obtained from the geochemical model reveal that the groundwater is over-saturated with aragonite, calcite, dolomite, strontianite, and barite. The hydrogeological evaluation of the study area led to recommendations to determine of the suitable areas for exploration of the Middle Miocene aquifer and to protect groundwater from deterioration.     

http://www.sciencedirect.com/science/article/pii/S1674987112001284

This study deals with the biogeography of Antarctic microflora （Antarctica acts as best model to study microbial biogeography） such as cyanobacteria and selected halophiles with special emphasis on Halomonas variabilis and Bacillus licheniformis.Halophiles are known to be resistant not only to salt stress,but also to extreme temperature,pressure,and aridity and they are capable of surviving in harsh environments such as polar regions,deep-sea habitats,and deserts.Many microbes are known to be resistant to hostile environmental conditions,and are capable of surviving in harsh environments.Our group has isolated 444 strains belonging to 28 genera of halophiles from various environments around the world.The 16S rRNA gene sequences revealed that many of the isolated strains from geographically distant habitats having different environmental conditions,were closely related to each other,with some strains possessing 100％ identical sequences.Organisms possessing survival mechanism such as spore formation are usually ubiquitous.The genus Halomonas is represented by potentially endemic strains and the ubiquitous H.variabilis,while spore-forming B.licheniformis showed cosmopolitan distribution.One potentially endemic （moderate endemicity that is regional and/or continental distribution） strain was reported from Syowa station,East Antarctica,and Mario Zucchelli station,West Antarctica,which are geographically separated by 3000 km.Moreover,15 strains having 100％ similarity with B.licheniformis were considered cosmopolitans.The results of this work provide support for the middle-ground model that some microbes have moderate endemicity and others have cosmopolitan distribution.These results will contribute to a greater understanding of microbial biogeography with special emphasis on Antarctica.     

Seismic activity beneath the Nankai trough revealed by DONET ocean-bottom observations

We conducted a detailed investigation of seismic activity from January 2011 to February 2013 along the Nankai trough off the Kii Peninsula, central Japan, by using data obtained from the DONET ocean-bottom observation network. The hypocenters are mostly within the subducting Philippine Sea (PHS) plate, although a few are along the plate boundary or in the sedimentary wedge below the Kumano forearc basin. The seismic activity can be separated into events above and below 20 km depth, which corresponds approximately to the Moho. The hypocenter distributions are distinctly different for these groups. The seismic activity in the oceanic crust can be further separated into three clusters. Most of the seismic activity recorded in our data represents aftershocks of the 2004 off the Kii Peninsula earthquakes (M _JMA = 7.1, 7.4, and 6.5), which occurred in the PHS plate. The hypocenter distribution in the oceanic crust correlates well with the location of the Paleo-Zenisu ridge, which is formed by a chain of seamounts that is subducting beneath the forearc basin. The hypocenters in the uppermost mantle are aligned on a plane dipping to the southeast, consistent with the existence of a thrust fault cutting through the lithosphere of the oceanic plate. The focal mechanisms of the earthquakes show that the axis of compressive stress in the PHS plate is oriented N–S, almost perpendicular to the direction of plate convergence, indicating a complex tectonic regime in this region. These results suggest that intraplate shortening may be occurring in the subducting oceanic plate.     

The self-organizing map,a new approach to apprehend the Madden–Julian Oscillation influence on the intraseasonal variability of rainfall in the southern African region

The Madden–Julian Oscillation (MJO) is the major mode of intraseasonal variability (30–60 days) in the tropics, having large rainfall impacts globally, and possibly on southern Africa. However, the latter impact is not well understood and needs to be further explored. The life cycle of the MJO, known to be asymmetric, has been nevertheless analyzed usually through methods constrained by both linearity and orthogonality, such as empirical orthogonal function analysis. Here we explore a non-linear classification method, the self-organizing map (SOM), a type of artificial neural network used to produce a low-dimensional representation of high-dimensional datasets, to capture more accurately the life cycle of the MJO and its global impacts. The classification is applied on intraseasonal anomalies of outgoing longwave radiation within the tropical region over the 1980–2009 period. Using the SOM to describe the MJO is a new approach, complimentary to the usual real-time multivariate MJO index. It efficiently captures this propagative phenomenon and its seasonality, and is shown to provide additional temporal and spatial information on MJO activity. For each node, the subtropical convection is analyzed, with a particular focus on the southern Africa region. Results show that the convection activity over the central tropical Indian Ocean is a key factor influencing the intraseasonal convective activity over the southern African region. Enhanced (suppressed) convection over the central Indian Ocean tends to suppress (enhance) convection over the southern African region with a 10-day lag by modulating the moisture transport.     

Effects of Snowfall on Drifting Snow and Wind Structure Near a Surface

Wind-tunnel and numerical experiments were performed to investigate the effects of snowfall on the wind profile and the development of drifting snow. Wind profiles and mass-flux profiles of drifting snow were measured with and without artificial snowfall over a snow surface within the tunnel. Wind and shear-stress profiles and the impact speeds of the snowflakes during snowfall were also investigated numerically. During snowfall, snowflakes transfer part of their horizontal momentum to the air, which increases the stress close to the snow surface; however, the resultant modifications of the wind profiles are small. Because snowflakes have large momentum, the decomposed snow crystals that result from their collision with a surface can form a saltation layer, even over a hard snow surface where entrainment of the grains from the surface does not occur. Additionally, during snowfall, the threshold friction velocity can be lower than the impact threshold because snowflake fragmentation facilitates snow drifting. The broken crystals contribute to the increase in the number of drifting snow grains, even below the impact threshold.