Abundance and isotopic composition of noble gases in metal and graphite of the Bohumilitz IAB iron meteorite

Abstract— Abundances and isotopic compositions of noble gases in metal and graphite of the Bohumilitz IAB iron meteorite were measured. The abundance ratios of spallogenic components in metal reveal a ³He deficiency which is due to the diffusive loss of parent isotopes, that is, tritium (Tilles, 1963; Schultz, 1967). The diffusive loss likely has been induced by thermal heating by the Sun during cosmic‐ray exposure (～160 Ma; Lavielle et al, 1999). Thermal process such as impact‐induced partial loss may have affected the isotopic composition of spallogenic Ne. The ¹²⁹Xe/¹³¹Xe ratio of cosmogenic components in the metal indicates an enhanced production of epi‐thermal neutrons. The abundance ratios of spallogenic components in the graphite reveal that it contained small amounts of metal and silicates. The isotopic composition of heavy noble gases in graphite itself was obtained from graphite treated with HF/HCl. The isotopic composition of the etched graphite shows that it contains two types of primordial Xe (i.e., Q‐Xe and El Taco Xe). The isotopic heterogeneity preserved in the Bohumilitz graphite indicates that the Bohumilitz graphite did not experience any high‐temperature event and, consequently, must have been emplaced into the metal at subsolidus temperatures. This situation is incompatible with an igneous model as well as the impact melting models for the IAB‐IIICD iron meteorites as proposed by Choi et al. (1995) and Wasson et al (1980).     

基于Voronoi邻近的移动地图自适应裁剪模型

当前移动地图采用距离关系裁剪模型生成!无法根据地理对象的分布变化自动调整裁剪窗口的大小,导致突出的信息失衡问题!直接影响移动地图的易读性.针对这一问题!提出一种基于Voronoi邻近的移动地图自适应裁剪模型!即通过移动用户的Voronoi邻近关系自适应调整裁剪窗口的大小,以实现移动地图的信息自适应均衡.实验证明,模型可以有效地改善移动地图的信息均衡性.     

玉米深加工产业的循环经济模式研究

玉米深加工具有典型的替代能源及循环经济特征。目前玉米深加工行业面临的资源短缺和环境污染的双重制约。从促进经济与环境协调发展的角度,结合玉米深加工产业发展及环境治理现状,对玉米深加工产业的循环经济模式——玉米深加工生态产业园区建设进行了探索。通过对玉米深加工生态产业园上下游原料产业链的延伸、各环节废物的资源化分析、能源与水资源回收利用的设计和生态产业园区外围企业关系的研究,结果表明,通过实施清洁生产和延长产业链,构建闭合循环的玉米深加工生态产业链条,可实现资源、能源的有效节约和副产品、废弃物的综合利用,具有相应的环境、经济和社会效益,在增强企业绿色竞争力的同时可促进玉米深加工产业的可持续发展。该模式对吉林省及同类地区玉米深加工产业的可持续发展有指导和借鉴意义。     

川西石棉地区田湾与扁路岗岩体的锆石U-Pb定年

对扬子板块西缘石棉地区田湾闪长岩体与扁路岗花岗岩体开展了精细的单颗粒锆石Ｕ－Ｐｂ年代学研究。测试结果表明,田湾岩体中锆石的结晶年龄为８２３Ｍａ±１２Ｍａ,扁路岗岩体中锆石的结晶年龄为８７６Ｍａ±４０Ｍａ,表明石棉地区与扬子板块西缘其他地区一样,晋宁期岩浆活动也是相当强烈的。     

广西扶绥-崇左地区铝土矿矿产远景调查主要进展及成果

在龙州地区首次发现早石炭世的堆积型铝土矿矿源层,提出广西堆积型铝土矿至少存在早石炭世和晚二叠世两个时代的矿源层。探索运用高密度电阻率法寻找古风化壳沉积型铝土矿的有效性试验工作。提交新发现矿产地4处,探获新增铝土矿(3341)资源量5289.15万吨。重新厘定区域地层岩性及岩相特征,系统总结区内铝土矿矿床(点)的时空分布特征、控矿地质条件、成矿规律及找矿标志,建立了区域成矿模式和预测找矿模型,圈定成矿远景区5处,找矿靶区6处,开展区域矿产预测,初步评价了本区铝土矿资源潜力。为该地区下一步地质调查、矿产勘查规划和开发提供了丰硕的基础资料和有益参考。     

太原市城市复合生态系统调节服务时空格局演化及驱动机制研究

以太原市主城区为例,根据生态系统服务理论对太原不同土地利用类型所提供的正负生态系统调节服务价值分别进行测度计算,并综合分析城市复合生态系统调节服务的时空演化特征,最后,从直接原因(土地利用变化)和根本原因(空间城镇化、人口城镇化、产业空间组织与空间规划、政府相关政策与规划)2个方面,对太原市生态系统调节服务能力变化进行...     

利用中国静止气象卫星资料估算黄河源区蒸散发量

以黄河源区为研究区域,选取2009年9月该区域的中国静止气象卫星(FY-2D)观测资料,结合地面气象观测资料,基于能量平衡原理,估算了研究区域的逐时陆面蒸散发量。结果表明:在晴天条件下,利用陆表能量平衡系统模型求出蒸散发量的大小;在阴天条件下,利用FY-2D云顶反照率资料,根据太阳辐射在大气中的衰减过程,得出地表太阳辐射收支,进而求出蒸散发量的大小。卫星遥感估算的逐时蒸散发量与地面观测值相比,平均相对误差15.2%,估算误差在可接受的合理范围内,为实现陆面蒸散发量的业务化奠定了一定的基础。     

Trace-element mobilization during Ca-metasomatism along a major fluid conduit: Eclogitization of blueschist as a consequence of fluid-rock interaction

In the subduction complex of the Tianshan mountains, western China, massive blueschist is cross-cut by an eclogite-facies major fluid conduit surrounded by a reaction zone which is mainly composed of omphacite and garnet. Petrological as well as geochemical evidence suggest that formation of the vein and the eclogitic selvage around the vein was caused by fluid infiltration under peak metamorphic conditions of 21 ± 1.5 kbar and 510 ± 30 °C. The combination of whole-rock with mineral trace-element data as well as mass-balance calculations indicate that substantial differences exist between the unaltered host rock and the part of the system which was altered by fluid-rock interaction. These differences include: (1) depletion of mainly large-ion lithophile elements (LILE) and Li of up to 60% relative to their concentrations in the unaltered host rock; (2) an extreme enrichment of CaO (∼115%), Sr and Pb (>300%) in the altered parts of the vein-wall-rock system; (3) redistribution of heavy rare earth elements (HREE) from partly replaced rutile and recrystallized titanite in the blueschist-eclogite transition zone into newly grown garnet rims in the eclogitic selvage around the vein; (4) transformation of high Nb/Ta rutile into low Nb/Ta titanite which is associated with preferred mobilization of Nb over Ta; and (5) decoupling of Zr and Hf from Nb and Ta; the latter are depleted by ∼30% relative to the unaltered blueschist host rock whereas the former are depleted by only ∼10%. The prerequisite for the transformation of Ca-poor blueschist (6-7 wt.% CaO) into Ca-rich eclogite (up to 13 wt.% CaO) was the infiltration of a Ca-rich fluid. The release of trace elements can be attributed to partitioning of these elements into the passing fluid phase during dissolution-reprecipitation processes in the course of eclogitization. The reactivity of the precursor mineral assemblage and the chemical gradients between the reacting and passing fluid of the conduit are mainly responsible for trace-element mobilization in the studied samples. The suite of trace elements released upon fluid-induced eclogitization of the reactive wall-rock resembles that in island arc magmas showing strong enrichment of LIL elements, strong depletions in HFS elements and intermediate concentrations of REE.     

铁锰氧化物对苯酚氧化降解的实验研究

为了考察铁锰氧化物对酚类污染物的氧化降解能力,采用天然以及合成的铁锰氧化物对苯酚的氧化降解进行对比实验研究。土壤中铁锰氧化物样品分别为天然针铁矿及氧化锰,合成铁锰氧化物样品分别为合成针铁矿及软锰矿。结果表明：苯酚与铁锰氧化物发生氧化还原作用时,还可能与土壤中杂质发生吸附等作用;铁锰氧化物还原反应强度随着反应介质pH值的升高而迅速下降;可用零级反应动力学方程拟合铁氧化物还原溶解反应,针铁矿溶解反应的强度与介质的pH值呈负相关关系;天然针铁矿对酚类污染物的氧化降解能力明显高于合成针铁矿,pH值对天然针铁矿溶解反应影响较大;可用一级指数衰减方程拟合锰氧化物还原溶解反应,锰氧化物溶解反应的强度与介质的pH值呈指数衰减关系;pH值对软锰矿还原溶解反应的影响大于对土壤中氧化锰的影响,pH值越小,影响越显著;对比pH值对铁和锰还原作用的影响发现,在pH=6.5时,锰氧化物仍有较强的氧化性能。     

文峪金矿矿床成因讨论

流体包裹体测温表明 ,文峪金矿成矿温度 180～ 45 0℃ ,为中高温热液。成矿压力 1.0×10 5～ 1.4× 10 5k Pa,根据静岩压力推算的成矿深度为 3.6～ 5 .2 km。包裹体盐度特征显示出成矿场内流体以深源流体为主 ,混合的地表渗透水所占比例约 10 %～ 15 %。文峪金矿成矿过程中导致矿质沉淀的主要因素是温度下降及由此导致的 CO2 - H2 O不混溶现象。文峪及小秦岭地区金矿床的成矿热液来源于与文峪花岗岩同源演化的深部岩浆热液。金矿的成矿时代为中生代中晚期