Weathering and polymerization of tektites: An x-ray photoelectron spectroscopy (XPS) investigation

Abstract— Tektites are natural glasses formed from terrestrial material that was melted and displaced by the impact of an extraterrestrial body. The surface and near-surface compositions of tektite glass results from fractionation during impact and ejection, and/or postsolidification weathering. The first goal of this study was to characterise the surface and near-surface (in the order of tens of angstroms) chemical composition of two tektites by x-ray photoelectron spectroscopy (XPS), and to estimate the importance of weathering vs. fractionation during flying. In order to separate the chemical modification due to weathering from that due to fractionation during ballistic flight, we studied two samples from the Australasian tektite strewn field. One of them was collected in a hot desert area (Nullarbor Plain, Australia) and the other, in a humid climate (Thailand). Our study reveals the presence of well-developed leached layers in both tektites. In the Australian tektite, Si is depleted in the topmost layers (a few tens of angstroms). A more complex chemical zoning is defined in the tektite from Thailand. These leached layers are comparable to those observed in weathered glasses, and therefore we conclude that weathering is responsible for the chemical composition of the surface and near-surface compositions. The second goal was to investigate the chemical environment of O, N and C in the glass. The O peak was resolved into two bridging O components (Si-O-Si and Al-O-Si) that are comparable to O environments in artificial glasses. The binding energy of the C_1s electron is typical for C-C and C-H bonds in hydrocarbons; minor organic acid components are also present. Nitrogen is only observed on the surface of the Thailand tektite. The binding energy of N_1s is comparable to that of ammonia, and the surface enrichment in N is interpreted as due to sorption related to interactions between glass and fluid buffered by the organic material in the soil.     

Evidence for Pleistocene wet aeolian dune and interdune accumulation,S. Pedro da Maceda,north‐west Portugal

Outcrops and cored/counter‐flushed boreholes in the coastal area between Espinho and Aveiro (north‐west Portugal) were investigated to reconstruct the changing patterns of sedimentation during the Late Pleistocene–Holocene. To obtain a common comparison basis, the grain‐size data from outcrop and borehole samples were analysed. The outcrops and the cored parts of the boreholes were dated by radiocarbon and optically stimulated luminescence. The results show that, on top of pebble‐rich beds of fluvial origin, a wet aeolian dune and interdune environment was active during the later part of the Pleistocene, turning to dry aeolian at the transition to the Holocene. The data indicate also that aeolian accumulation was controlled by vegetation changes (climate) and groundwater table fluctuations. During the Holocene, a podzol formed on the Pleistocene dunes and extensive vegetation precluded major aeolian accumulations. Remobilization of sand started again because of human deforestation and – last but not least – the Little Ice Age.     

Spectral surface albedo over Morocco and its impact on radiative forcing of Saharan dust

In May–June 2006, airborne and ground-based solar (0.3–2.2 μm) and thermal infrared (4–42 μm) radiation measurements have been performed in Morocco within the Saharan Mineral Dust Experiment (SAMUM). Upwelling and downwelling solar irradiances have been measured using the Spectral Modular Airborne Radiation Measurement System (SMART)-Albedometer. With these data, the areal spectral surface albedo for typical surface types in southeastern Morocco was derived from airborne measurements for the first time. The results are compared to the surface albedo retrieved from collocated satellite measurements, and partly considerable deviations are observed. Using measured surface and atmospheric properties, the spectral and broad-band dust radiative forcing at top-of-atmosphere (TOA) and at the surface has been estimated. The impact of the surface albedo on the solar radiative forcing of Saharan dust is quantified. In the SAMUM case of 19 May 2006, TOA solar radiative forcing varies by 12 W m⁻² per 0.1 surface-albedo change. For the thermal infrared component, values of up to +22 W m⁻² were derived. The net (solar plus thermal infrared) TOA radiative forcing varies between −19 and +24 W m⁻² for a broad-band solar surface albedo of 0.0 and 0.32, respectively. Over the bright surface of southeastern Morocco, the Saharan dust always has a net warming effect.     

A DEFINITION OF DOMINANT DISCHARGE

ABSTRACT

The concept of dominant (stream) discharge in geomorphology has not been firmly defined. By defining it, on rational grounds, as that discharge at which, over a long period of time, most sediment has been transported, a definite value can be computed for a stream for which there are available duration-curve values of daily discharge and a sediment-rating curve. This has been done for 5 eastern and 4 western rivers. The dominant discharge, when expressed in terms of percentage duration, is remarkably consistent, and is found to be a lower discharge than has generally been considered as dominant.     

Vegetation and climate history in the Westeifel Volcanic Field (Germany) during the past 11 000 years based on annually laminated lacustrine maar sediments

Lakes Holzmaar and Meerfelder Maar are located in the Westeifel Volcanic Field less than 10 km apart. Both maar lakes are well known for their annually laminated (varved) sediments covering the past 15 000 years. Here, we focus on reconstructing the history of Holocene vegetation, human impact and climate using high-resolution pollen data. Detailed correlation between the two records using palynologically defined tie-points provides for the first time a test of the precision of the individual varve chronologies. The high-resolution pollen records of both Holzmaar and Meerfelder Maar show continuous natural successions of vegetation during the early and mid-Holocene controlled by the development of soil, climate, immigration and competitive expansion of thermophilous tree species. From 6500 varve yr BP onwards, human impact became an increasingly more important factor. Given the high chronological precision of both records, regional similarities, but also local differences of anthropogenically influenced vegetation changes, can be recognized. The reconstructed July temperature between 8500 and 5000 varve yr BP is around 1 °C higher than today, most likely in response to higher summer insolation related to orbital forcing. High variability of reconstructed July and January temperatures as well as annual precipitation around 5000 varve yr BP is a prominent climatic signal. This is consistent with other records in several areas of Europe which also identify this period as climatically highly variable.     

Testate amoebae as a proxy for reconstructing Holocene water table dynamics in southern Patagonian peat bogs

Testate amoebae are abundant and diverse in Sphagnum peat bogs and have been used extensively as indicators of past water table depths. Although these unicellular protists are widely dispersed with globally similar hydrological preferences, regional variations in communities demand region‐specific transfer functions. Here we present the first transfer function for southern Patagonian bogs, based on 154 surface samples obtained from transects in five bogs sampled in 2012 and 2013. Significant variance was explained by pH, electrical conductivity and, in particular, water table depth. Transfer functions for water table were constructed using weighted averaging and evaluated by cross‐validation and independent test sets. The optimal transfer function has predictive ability, but relatively high prediction errors given the wide range in sampled water tables. The use of independent test sets, as well as cross‐validation, allows a more rigorous assessment of model performance than most previous studies. For a subset of locations we compare surface and subsurface samples to demonstrate significant differences in community composition, possibly due to vertical zonation. Our results provide the first quantification of hydrological optima and tolerances for several rare species, which may include Southern Hemisphere endemics and pave the way for palaeohydrological reconstructions in southern Patagonian bogs.     

Controls on the alluviation of oxbow lakes by bed‐material load along the Sacramento River,California

Differences in the nature and quantity of sediment filling oxbow lakes have significant implications for the evolution of meandering rivers and the development of floodplains, influencing rates of meander migration and the valley width over which migration takes place. In an effort to identify the controls on the alluviation of oxbow lakes by coarse bed material, this study examined the sedimentary records stored within oxbow lakes of the Sacramento River of California, USA, and found that the volume of gravel in storage correlated negatively with the diversion angle separating flow between the river channel and the entrance into each lake. A method was devised for estimating the original channel bathymetry of the studied lakes and for modelling the hydraulic and sediment‐transport effects of the diversion angle within channels recently abandoned by meander cut‐off. The diversion angle determines the width of a flow separation within the abandoned‐channel entrance, reducing the discharge diverted from the river channel and thus limiting the ability of the abandoned channel to transport bed material. Aggradation rates are faster within entrances to abandoned channels with high diversion angles, resulting in the rapid isolation of lakes that store only a small volume of coarse‐grained sediment. Aggradation rates are slower within channel entrances where diversion angles are low, resulting in the slow transitioning of such channels into oxbow lakes with a larger and more extensive accumulation of coarse‐grained sediment. These findings compare well with observations in other natural settings and the mechanism which is described for the control of the diversion may explain why some oxbow lakes remain as open‐water environments for centuries, whereas others are filled completely within decades of cut‐off.     

Latitudinally different responses of Tethyan shoal‐water carbonate systems to the Early Aptian oceanic anoxic event (OAE 1a)

Ocean‐wide anoxic events represent intensively investigated anomalies in the global carbon cycle. Most previous research has focussed on hemipelagic and pelagic settings and on the relationship between black‐shale deposition and carbon‐isotope excursions. The study of ocean‐wide anoxic events and coeval shallow‐water settings is now increasingly seen as an interesting complementary approach, but one that is not without problems. Whereas platform drowning characterizes the Early Aptian of the northern Tethyan margin, Lithocodium–Bacinella‐rich facies and ongoing shoal‐water sedimentation at the southern Tethyan margin (Oman) bears important information on potential causes of carbon‐cycle perturbations. The present paper seeks to test the supra‐regional relevance of the Oman data by investigating coeval central Tethyan limestones. Three Lower Aptian shoal‐water sections in Istria (Croatia), deposited on the isolated Adriatic Carbonate Platform, are investigated applying chemostratigraphy (carbon and strontium) and detailed sedimentological analysis. The focus is on peritidal to lagoonal facies characterized by mass occurrences of Lithocodium–Bacinella, an enigmatic microencruster community. Lithocodium–Bacinella facies occurs predominantly in layers ranging from one to several centimetres in stratigraphic thickness, with several layers merging to metre‐thick packages. Growth fabrics within the layers include oncoidal morphotypes, lumps, interconnected patches and columns, layers and rare nodular to massive bindstone facies. These growth patterns show a remarkable regional extent and consistency over study sites distributed several kilometres apart. This widespread distribution suggests that specific Lithocodium–Bacinella morphotypes might serve as regional stratigraphic markers. The high‐resolution carbon‐isotope chemostratigraphy presented here is based on pristine rudist shells and matrix micrite samples and calibrated against strontium‐isotope data obtained from screened rudist low‐Mg calcite. The chemostratigraphic data are consistent with existing biostratigraphic data and place the studied strata at the onset of Early Aptian oceanic anoxic event 1a. Moreover, results indicate the near‐coeval nature of Lithocodium–Bacinella bloom facies in Istria and Oman. The outcomes of this study point to latitudinally different responses of Tethyan shoal‐water carbonate systems (platform drowning versus Lithocodium–Bacinella blooms) to the ocean‐wide anoxic event 1a.     

Molecular identification of the extinct mountain goat, Oreamnos harringtoni (Bovidae)

Campos, P. F., Willerslev, E., Mead, J. I., Hofreiter, M. & Gilbert, M. T. P. 2009: Molecular identification of the extinct mountain goat, Oreamnos harringtoni (Bovidae). Boreas , 10.1111/j.1502-3885.2009.00111.x. ISSN 0300-9483.
Harrington's mountain goat ( Oreamnos harringtoni ), an extinct North American herbivore, is one of the least known mammals of the Pleistocene. Fossil specimens are predominantly known from dry cave localities throughout the arid American west – the Grand Canyon, Colorado Plateau, Nevada and Mexico. Morphological analysis of the recovered fossils suggests a close phylogenetic relationship between Harrington's mountain goat and the extant mountain goats from the American northwest ( Oreamnos americanus ). However, the degree of genetic similarity between the two species, and their overall placement within the Caprinae, is not clear. In this study, we recovered and sequenced the first DNA fragments from O. harringtoni in order to investigate these relationships. Genetic analysis further supports the morphological hypothesis that O. harringtoni and O. americanus are two distinct species.