絮凝−真空−电渗联合加固滩涂软土的模型试验研究

针对真空预压作用下排水板淤堵与排水条件受限等问题,提出絮凝−真空−电渗联合加固法。首先通过沉降柱试验确定合适的有机絮凝剂,然后采用该絮凝剂,分别在 48 h（开始介入真空预压,固结度为0 ）、60 h（排水速率明显下降,固结度为60%）及 84 h（排水速率近乎 0,固结度为 80%）时介入电渗,开展不同电渗介入时间的絮凝−真空−电渗联合加固试验。试验从排水量、十字板剪切强度、含水率与孔压等对比分析联合加固的有效性,确定其最佳电渗介入时间。试验结果表明：当固结度为 80% 时介入电渗,絮凝−真空−电渗联合加固法能够有效地抑制排水速率减小的趋势,增长有效排水时间。同时,土体的抗剪强度和承载力亦得到大幅提升,孔压消散更加均匀。此外,在阳离子聚丙烯酰胺絮凝剂的作用下,初始排水速率快,在一定程度上使土体的渗透性得到提升,有效地解决了排水板淤堵问题,说明絮凝−真空−电渗联合加固法具有较强的优越性。     

黄豆脲酶诱导碳酸钙沉淀多变量试验研究

植物源脲酶诱导碳酸钙沉淀（enzyme induced carbonate precipitation,简称EICP）可以显著改善砂土的工程力学特性,但在具体操作时,参数取值无对应规范,固化效果有待提升。基于黄豆脲酶,研究了温度、脲酶浓度、尿素浓度、钙浓度、pH值、钙源种类等变量对脲酶活性与碳酸钙沉淀的影响,并进行了沉淀物（碳酸钙晶体）的扫描式电子显微镜（scanning electron microscope,简称SEM）与X射线衍射（X-ray diffraction,简称XRD）测试,在此基础上开展了黄豆脲酶固化砂的无侧限抗压强度与固化效果试验研究。结果表明：脲酶活性随脲酶浓度的增加而线性增长,但存在温度阈值,温度超过阈值后,脲酶将完全失活,且阈值随脲酶浓度的增大而降低;尿素浓度与pH值共同影响脲酶活性,二者存在一个最优组合,当尿素浓度在0.1～1.0 mol/L时最优pH值为7,当尿素浓度在1.0～1.5 mol/L时最优pH值为8。脲酶是沉淀反应的催化剂,脲酶浓度越高,反应越完全,碳酸钙沉淀率越高;尿素与钙溶液则主要通过掺入量影响碳酸钙沉淀量,掺量比例宜为1:1,且二者浓度与pH值可通过影响脲酶活性来影响碳酸钙的沉淀情况;不同钙源对碳酸钙沉淀量的影响幅度不大。不同钙源沉淀碳酸钙晶体的成分与密度基本相同,但晶体结构差异较大,氯化钙沉淀碳酸钙晶体以块状为主,表面分布球状、类球状晶体,胶结面大,可作为EICP技术中较为理想的钙源。基于黄豆脲酶和氯化钙钙源固化砂的无侧限抗压强度约为掺粉煤灰砂样的6倍,通过SEM图像可发现,沉淀碳酸钙晶体包裹并黏结砂粒成为整体,固化效果非常理想。     

1980-2019年青藏高原积雪深度时空差异性分析北大核心CSCD

积雪是地表特征的重要参数,其对辐射收支、能量平衡及天气和气候变化有重要影响。利用1980-2019年被动微波遥感积雪深度资料对青藏高原积雪时空特征进行分析,在此基础上将高原划分为东部、南部、西部及中部4个区域,并分区域讨论了多时间尺度积雪的变化特征及其与气温、降水的相关关系。结果表明:不同区域积雪深度在不同时间尺度的变化特征存在差异,高原东部积雪深度累积和消融的速率比西部快,南部积雪深度累积和消融速率比中部快。季节尺度上,冬季积雪高原东部最大,中部最小;春季积雪高原东部消融速率最大,西部积雪消融较慢但积雪深度最大;夏季高原西部仍有积雪存在。年际尺度上,各区域积雪深度在1980-2019年均呈现缓慢下降趋势,但东部积雪减少不显著;高原东部积雪深度在1980-2019年呈现出增加-减少-增加-减少的变化,其余3区均呈现出减少-增加-减少-增加-减少的变化。不同区域积雪深度对气温、降水的响应不同,高原东部和中部积雪深度与气温相关性较好;各区域积雪深度与降水呈不显著的正相关关系。     

Constraints on the depth and variability of the lunar regolith

Abstract— Knowledge of regolith depth structure is important for a variety of studies of the Moon and other bodies such as Mercury and asteroids. Lunar regolith depths have been estimated using morphological techniques (i.e., Quaide and Oberbeck 1968; Shoemaker and Morris 1969), crater counting techniques (Shoemaker et al. 1969), and seismic studies (i.e., Watkins and Kovach 1973; Cooper et al. 1974). These diverse methods provide good first order estimates of regolith depths across large distances (tens to hundreds of kilometers), but may not clearly elucidate the variability of regolith depth locally (100 m to km scale). In order to better constrain the regional average depth and local variability of the regolith, we investigate several techniques. First, we find that the apparent equilibrium diameter of a crater population increases with an increasing solar incidence angle, and this affects the inferred regolith depth by increasing the range of predicted depths (from ～7–15 m depth at 100 m equilibrium diameter to ～8–40 m at 300 m equilibrium diameter). Second, we examine the frequency and distribution of blocky craters in selected lunar mare areas and find a range of regolith depths (8–31 m) that compares favorably with results from the equilibrium diameter method (8–33 m) for areas of similar age (～2.5 billion years). Finally, we examine the utility of using Clementine optical maturity parameter images (Lucey et al. 2000) to determine regolith depth. The resolution of Clementine images (100 m/pixel) prohibits determination of absolute depths, but this method has the potential to give relative depths, and if higher resolution spectral data were available could yield absolute depths.     

Vertical profiles of biospheric and fossil fuel-derived CO2 and fossil fuel CO2 : CO ratios from airborne measurements of Δ14C, CO2 and CO above Colorado, USA

Measurements of  Δ¹⁴C  in atmospheric CO₂ are an effective method of separating CO₂ additions from fossil fuel and biospheric sources or sinks of CO₂. We illustrate this technique with vertical profiles of CO₂ and  Δ¹⁴C  analysed in whole air flask samples collected above Colorado, USA in May and July 2004. Comparison of lower tropospheric composition to cleaner air at higher altitudes (>5 km) revealed considerable additions from respiration in the morning in both urban and rural locations. Afternoon concentrations were mainly governed by fossil fuel emissions and boundary layer depth, also showing net biospheric CO₂ uptake in some cases. We estimate local industrial CO₂:CO emission ratios using in situ measurements of CO concentration. Ratios are found to vary by 100% and average 57 mole CO₂:1 mole CO, higher than expected from emissions inventories. Uncertainty in CO₂ from different sources was ±1.1 to ±4.1 ppm for addition or uptake of −4.6 to 55.8 ppm, limited by  Δ¹⁴C  measurement precision and uncertainty in background  Δ¹⁴C  and CO₂ levels.     

RAPID ESTIMATION OF THE NUMBER OF COELUTING COMPONENTS IN LIQUID CHROMATOGRAPHY BY FACTOR ANALYSIS

Evaluation of the results of factor analysis of sets of spectroscopically detected chromatograms is carriedout by examining the shapes of the abstract factors.This is done either by visual inspection or by analysisof the power density spectra produced from them.Owing to constraints imposed by the column functionand the spectroscopic instrument function,the information content of the chromatograms necessarilyoccurs at low spatial frequencies.As a consequence,it appears as relatively broad features in the abstractchromatograms and as a peak in the low-frequency region of the corresponding power density plot.Onthe basis of examination of the power density distribution,a well-defined distinction is made betweenprimary and secondary abstract factors.The major uncertainty encountered in determining the numberof chemical components appears to arise from effects of contaminants in reagents.     

A Molecular Ring in the Liner Ngc 5218

High resolution OVRO CO 1–0 observations of the inner 30 in the LINER galaxy NGC 5218 reveal the presence of a double centrally peaked molecular concentration with extensions out to a radius of 12. The molecular mass detected is 2.4 × 10⁹ M and the gas surface density is high, 3000 M pc square in the inner 500 pc. The SFR is 2–3 M yr^–1 and the SFE is 13, which are low or moderate values for that gas surface density. We interpret the inner feature as a rotating molecular ring with a radius of 200 pc. We furthermore suggest that the LINER activity in NGC 5218 is not caused by an aging starburst, but by a buried AGN.     

Combined Trace Element and Pb-Nd-Sr-O Isotope Evidence for Recycled Oceanic Crust (Upper and Lower) in the Iceland Mantle Plume

We present the results of a comprehensive major element, traceelement and Sr–Nd–Pb–O isotopic study of post-glacialvolcanic rocks from the Neovolcanic zones on Iceland. The rocksstudied range in composition from picrites and tholeiites, whichdominate in the main rift systems, to transitional and alkalicbasalts confined to the off-rift and propagating rift systems.There are good correlations of rock types with geochemical enrichmentparameters, such as La/Sm and La/Yb ratios, and with long-termradiogenic tracers, such as Sr–Nd–Pb isotope ratios,indicating a long-lived enrichment/depletion history of thesource region. ⁸⁷Sr/⁸⁶Sr vs ¹⁴³Nd/¹⁴⁴Nd defines a negative array.Pb isotopes define well-correlated positive arrays on both ²⁰⁶Pb/²⁰⁴Pbvs ²⁰⁷Pb/²⁰⁴Pb and ²⁰⁸Pb/²⁰⁴Pb diagrams, indicating mixing ofat least two major components: an enriched component representedby the alkali basalts and a depleted component represented bythe picrites. In combined Sr–Nd–Pb isotopic spacethe individual rift systems define coherent mixing arrays withslightly different compositions. The enriched component hasradiogenic Pb (²⁰⁶Pb/²⁰⁴Pb > 19·3) and very similargeochemistry to HIMU-type ocean island basalts (OIB). We ascribethis endmember to recycling of hydrothermally altered upperbasaltic oceanic crust. The depleted component that is sampledby the picrites has unradiogenic Pb (²⁰⁶Pb/²⁰⁴Pb < 17·8),but geochemical signatures distinct from that of normal mid-oceanridge basalt (N-MORB). Highly depleted tholeiites and picriteshave positive anomalies in mantle-normalized trace element diagramsfor Ba, Sr, and Eu (and in some cases also for K, Ti and P),negative anomalies for Hf and Zr, and low ¹⁸O_olivine values(4·6–5·0) below the normal mantle range.All of these features are internally correlated, and we, therefore,interpret them to reflect source characteristics and attributethem to recycled lower gabbroic oceanic crust. Regional compositionaldifferences exist for the depleted component. In SW Icelandit has distinctly higher Nb/U (68) and more radiogenic ²⁰⁶Pb/²⁰⁴Pbratios (18·28–18·88) compared with the NErift (Nb/U 47; ²⁰⁶Pb/²⁰⁴Pb = 18·07–18·47).These geochemical differences suggest that different packagesof recycled oceanic lithosphere exist beneath each rift. A thirdand minor component with relatively high ⁸⁷Sr/⁸⁶Sr and ²⁰⁷Pb/²⁰⁴Pbis found in a single volcano in SE Iceland (Öræfajökullvolcano), indicating the involvement of recycled sediments inthe source locally. The three plume components form an integralpart of ancient recycled oceanic lithosphere. The slope in theuranogenic Pb diagram indicates a recycling age of about 1·5Ga with time-integrated Th/U ratios of 3·01. Surprisingly,there is little evidence for the involvement of North AtlanticN-MORB source mantle, as would be expected from the interactionof the Iceland plume and the surrounding asthenosphere in formof plume–ridge interaction. The preferential samplingof the enriched and depleted components in the off-rift andmain rift systems, respectively, can be explained by differencesin the geometry of the melting regions. In the off-rift areas,melting columns are truncated deeper and thus are shorter, whichleads to preferential melting of the enriched component, asthis starts melting deeper than the depleted component. In contrast,melting proceeds to shallower depths beneath the main rifts.The longer melting columns also produce significant amountsof melt from the more refractory (lower crustal/lithospheric)component. KEY WORDS: basalts; trace element and Sr, Nd, Pb, O isotope geochemistry; Iceland plume; isotope ratios; oceanic crustal recycling; partial melting; plume–ridge interaction