Multiscale characterization of a heterogeneous aquifer using an ASR operation

Heterogeneity in the physical properties of an aquifer can significantly affect the viability of aquifer storage and recovery (ASR) by reducing the recoverable proportion of low-salinity water where the ambient ground water is brackish or saline. This study investigated the relationship between knowledge of heterogeneity and predictions of solute transport and recovery efficiency by combining permeability and ASR-based tracer testing with modeling. Multiscale permeability testing of a sandy limestone aquifer at an ASR trial site showed that small-scale core data give lower-bound estimates of aquifer hydraulic conductivity (K), intermediate-scale downhole flowmeter data offer valuable information on variations in K with depth, and large-scale pumping test data provide an integrated measure of the effective K that is useful to constrain ground water models. Chloride breakthrough and thermal profiling data measured during two cycles of ASR showed that the movement of injected water is predominantly within two stratigraphic layers identified from the flowmeter data. The behavior of the injectant was reasonably well simulated with a four-layer numerical model that required minimal calibration. Verification in the second cycle achieved acceptable results given the model's simplicity. Without accounting for the aquifer's layered structure, high precision could be achieved on either piezometer breakthrough or recovered water quality, but not both. This study demonstrates the merit of an integrated approach to characterizing aquifers targeted for ASR.     

Concentration,composition and sources of PAHs in the coastal sediments of the exclusive economic zone (EEZ) of Qatar,Arabian Gulf

Surface sediments were collected from sixteen locations in order to assess levels and sources of polycyclic aromatic hydrocarbons (PAHs) in sediments of Qatar exclusive economic zone (EEZ). Samples were analyzed for 16 parent PAHs, 18 alkyl homologs and for dibenzothiophenes. Total PAHs concentration (∑PAHs) ranged from 2.6 ng g⁻¹ to 1025 ng g⁻¹. The highest PAHs concentrations were in sediments in and adjacent to harbors. Alkylated PAHs predominated most of the sampling locations reaching up to 80% in offshore locations. Parent PAHs and parent high molecular weight PAHs dominated location adjacent to industrial activities and urban areas. The origin of PAHs sources to the sediments was elucidated using ternary plot, indices, and molecular ratios of specific compounds such as (Ant/Phe + Ant), (Flt/Flt + Pyr). PAHs inputs to most coastal sites consisted of mixture of petroleum and combustion derived sources. However, inputs to the offshore sediments were mainly of petroleum origin.     

Changing depositional environment and factors controlling the growth of mudflat in a tropical estuary,west coast of India

Mudflats and associated mangroves are most important ecosystems of tropical coastal regions. Mangroves play a very important role in maintaining the environmental balance; thus in addition to mangrove reforestation and restoration, afforestation has also been practiced. We studied distribution of sediment components (sand, silt, clay) organic carbon (OC), heavy metals (Fe, Mn, Cu, Zn, Cr and Co) and pH in six cores collected from one of the largest mudflats of Mandovi estuary, west coast of India. The temporal distribution patterns of these proxies suggested that past changes in tidal energy conditions, fresh water inflow and anthropogenic activities over the last few decades, together helped in development of a middle tidal flat in this estuary. In cores collected from the mangroves, trapping and deposition of finer particles and organic matter were enhanced by a complex aerial mangrove root system in recent years. Mangroves were, therefore, suggested to enhance the buildup of mudflats in Mandovi estuary. Cores collected from mudflats also exhibited higher deposition of finer particles and organic matter (except MF2) in recent years, suggesting maturity and greater stability of the entire mudflat in recent years. Middle tidal flats (mudflats) of Mandovi estuary may, therefore, prove to be suitable substrates for mangrove proliferation in the near future. Finer sediments deposited mainly from mining activities in recent years exhibited lower pH and higher metal content. Organisms dwelling in these recently deposited sediments are, therefore, at higher risk of bioaccumulation and metal toxicity.     

Modeling the temperature of the polar mesopause region: Part II—Intra-seasonal monthly oscillations

Measurements show that the polar mesospheric clouds (PMC) can vary, in the zonal mean, with periods around 1 month [Bailey et al., 2005. Observations of polar mesospheric clouds by the Student Nitric Oxide Explorer. J. Geophys. Res. 110, D13203, doi:10.1029/2004JD005422]. This observation has been the impetus for the present paper, where we describe corresponding temperature oscillations generated by the Numerical Spectral Model (NSM). Our numerical results are taken from the 3D and 2D versions of the NSM, which produce inter-annual and long-term variations in the polar mesopause region, as discussed in the accompanying paper (Part I). In the NSM, the intra-seasonal temperature variations with periods around 2 months are generated by the meridional winds that in turn are accelerated by the momentum deposition from small-scale gravity waves (GW) propagating north/south. The wave-driven dynamical process underlying the oscillations is intrinsically non-linear like that generating the quasi-biennial oscillation (QBO). Our analysis demonstrates that the seasonal annual and semi-annual variations excite the oscillation frequencies through non-linear cascading.     

周口店多足类化石

1932—1937年间在周口店中国猿人产地及其他地点采得八十馀件节足动物化石,多破碎,完整者极少。颜色不一,由乳白而棕黄,兼有呈半透明玻璃状者。经初步观察,应属节足动物门,多足纲,倍脚目,马陆科,计一属两种: 一、山马陆(Julus of.terrestris)此种在第一,三,十五地点及山顶洞均有发现。此与现生的山马陆无甚差异,仅肛板及由二肛板所成之肛门沟稍大。二、裴氏小马陆(Julus peii Chia & Liu(sp.nov.)此种於第一,四,十五地点及山顶洞均有发现。由身体及头部形态,身体环节数目(三十个以上),知其与山马陆同属。但其决非幼小山马陆,因其体节数目多於长成之山马陆。但与现生於日本的一种 Nipponoiulus truncatus 近似,惟後者体节数较少,尾端钝圆。关於马陆属化石,据现在所知最早发现於始新统地层中,直到现在仍有生存,变异极小。以上所述二种若非与其他脊椎动物化石共生於周口店地点,则其年代颇难鉴定,因其有以後爬入岩隙死後石化之可能,不过上述之标本不但有共生脊椎动物为证,且有的已埋藏於固结的砾岩中,其属於更新统时期可无疑义。     

A revised model for cycloid growth mechanics on Europa: Evidence from surface morphologies and geometries

Although a single model currently exists to explain the development of curved Europan cycloids, there have been no systematic studies of the range of morphologies and quantifiable geometric parameters of cycloidal features. We address variations in geometry along individual cycloid segments, characterizing differences in cusp styles and angles, and addressing the morphologic aspects of cycloid segments and cusps. In so doing, we illustrate how geometric and morphologic evidence imply a formation mechanism that differs from the existing model in several aspects. The current model states that cycloids are initiated as tensile fractures that grow in a curved path in response to rotating diurnal tidal stresses on Europa. However, the geometry of a cycloid cusp necessitates that shear stress was resolved onto the existing cycloid segment by the rotating diurnal stresses at the instant of cusp formation. Furthermore, we observe that cycloid cusps have a strikingly similar geometry to tailcracks that developed at the tips of many ridge-like strike-slip faults on Europa in response to shearing at the fault tip. We suggest that this similarity in geometries can be attributed to an identical formation mechanism whereby cycloid cusps form by a tailcracking process. We therefore present a revised, mechanically-based model for cycloid formation that retains the basic premise that crack growth is governed by diurnal stresses, but describes the development of cycloid cusps in response to resolved shear stresses at the tips of existing cycloid segments. The ratio of normal to shear stress at the time of tailcrack formation dictates the cusp angle and, over longer time periods, influences the morphologic evolution of the cycloid segment as it is repeatedly reworked by tidal stresses.     

Analytical models of contaminant transport in coastal aquifers

The Henry formulation, which couples subsurface flow and salt transport via a variable-density flow formulation, can be used to evaluate the extent of sea water intrusion into coastal aquifers. The coupling gives rise to nontrivial flow patterns that are very different from those observed in inland aquifers. We investigate the influence of these flow patterns on the transport of conservative contaminants in a coastal aquifer. The flow is characterized by two dimensionless parameters: the Péclet number, which compares the relative effects of advective and dispersive transport mechanisms, and a coupling parameter, which describes the importance of the salt water boundary on the flow. We focus our attention on two regimes – low and intermediate Péclet number flows. Two transport scenarios are solved analytically by means of a perturbation analysis. The first, a natural attenuation scenario, describes the flushing of a contaminant from a coastal aquifer by clean fresh water, while the second, a contaminant spill scenario, considers an isolated point source.     

Biomarker characterisation and hydrous pyrolysis of bitumens from Tertiary volcanics, queen Charlotte islands, British Columbia, Canada

A number of bitumen samples have been recovered from vugs and fractures in outcropping Tertiary basalts of the Queen Charlotte Islands off the west coast of British Columbia, Canada. n-Alkanes and acyclic isoprenoids are not present and the polycyclic biomarker distribution of the four samples analyzed by GC and GC-MS has been altered. One sample contains no remaining recognizable biomarkers. Two bitumens were also obtained from Lower Jurassic potential source rocks, including one from the Sandilands Formation, which was considered previously to be the most likely source of the Tertiary bitumens. Although these two bitumens were also taken from outcrops, they are considerably less biodegraded. The Sandilands Formation bitumen contains 28, 30-bisnorhopanes and since these compounds were not detected in the Tertiary bitumens, there is no evidence from the initial results for a Sandilands Formation contribution to the hydrocarbons in the Tertiary basalts. The presence of 18α(H)-oleanane in the saturate fraction of two of the Tertiary bitumens from widely separated locations indicates that they are at least partially sourced from Tertiary organic matter.Because the distribution of biomarkers in some samples has been severely affected by biodegradation, the asphaltenes of the bitumens were hydrously-pyrolysed and the saturate fractions of the resulting pyrolysates analysed for possible additional information on the origin of the bitumens. The pyrolysates from the more degraded samples contain compounds not detected in the saturate fractions of the original bitumen and show some of the expected characteristics of the original non-degraded bitumen. However, the compounds most useful for correlation are not present in the pyrolysates apparently due to their non-incorporation into the kerogen macromolecule. Our results suggest that hydrous-pyrolysis of asphaltenes is of limited use in the correlation of biodegraded samples and in determining their origins.     

Shallow seismicity, stress distribution and crustal deformation pattern in the Andaman-West Sunda arc and Andaman Sea, northeastern Indian Ocean

Shallow seismicity and available source mechanisms in the Andaman–westSunda arc and Andaman sea region suggest distinct variation in stressdistribution pattern both along and across the arc in the overriding plate.Seismotectonic regionalisation indicates that the region could be dividedinto eight broad seismogenic sources of relatively homogeneousdeformation. Crustal deformation rates have been determined for each oneof these sources based on the summation of moment tensors. The analysisshowed that the entire fore arc region is dominated by compressive stresseswith compression in a mean direction of N23^°, and the rates ofseismic deformation velocities in this belt decrease northward from 5.2± 0.65 mm/yr near Nias island off Sumatra and 1.12 ±0.13 mm/yr near Great Nicobar islands to as much as 0.4 ±0.04 mm/yr north of 8^°N along Andaman–Nicobar islandsregion. The deformation velocities indicate, extension of 0.83 ±0.05 mm/yr along N343^° and compression of 0.19 ±0.01 mm/yr along N73^° in the Andaman back arc spreadingregion, extension of 0.18 ± 0.01 mm/yr along N125^° andcompression of 0.16 ± 0.01 mm/yr along N35^° in NicobarDeep and west Andaman fault zone, compression of 0.84 ±0.12 mm/yr N341^° and extension of 0.77 ± 0.11 mm/yralong N72^° within the transverse tectonic zone in the Andamantrench, N-S compression of 3.19 ± 0.29 mm/yr and an E-Wextension of 1.24 ± 0.11 mm/yr in the Semangko fault zone ofnorth Sumatra. The vertical deformation suggests crustal thinning in theAndaman sea and crustal thickening in the fore arc and Semangko faultzones. The apparent stresses calculated for all major events range between0.1–10 bars and the values increase with increasing seismic moment.However, the apparent stress estimates neither indicate any significantvariation with faulting type nor display any variation across the arc, incontrast to the general observation that the fore arc thrust events showhigher stress levels in the shallow subduction zones. It is inferred that theoblique plate convergence, partial subduction of 90^°E Ridge innorth below the Andaman trench and the active back arc spreading are themain contributing factors for the observed stress field within the overridingplate in this region.