Reply to comments by K.A. Goettel and J.S. Lewis

Uranium has been measured by homogenized fission track analysis in 34 samples of 22 achondrites. Potassium has been determined in aliquots of eleven of these. The results, combined with previous Al data, are not compatible with achondrite formation from chondritic material by previously suggested fractional melting or metal-sulfide segregation processes.     

Displacement Phenomenon of Slow and Fast Growing Species in Microorganisms Association

In the process of the biological treatment of sewage, the multicomponent system of the substrate is converted by an association of microorganisms. The composition of species of microorganisms in the system depends on the substrate available and on the conversion of substrate. For this, a mathematical model is presented, which describes the change of the composition of species according to the rate of growth of the individual species on the basis of load (substrate available/biomass). The diversity of the biological system increases with decreasing load. The model is tested by practical examples.     

Relationship between microseisms,geomagnetic activity and ionospheric absorption of radio waves

Summary Relatively good correlation between such remote phenomena as microseisms, geomagnetic activity and ionospheric absorption of radio waves has been observed. These phenomena are probably connected by a considerably increased penetration of energetic particles into the atmosphere under conditions of geomagnetic activity.     

Physical Libration of the Moon: An Extended Problem

Astronomy Reports - The work is devoted to the study of the physical libration of the Moon. Interest in the traditional topic related to the rotation of the Moon is stirred up by the activity of...     

Application of a square wave potentiometry technique for electroreductive sulfur removal from a thiophenic model fuel

Thiophene-containing solutions were electroreductively desulfurized by a dynamic method. Initially, cyclic voltammetry was utilized to study thiophene electroadsorption from aqueous solution onto a platinum electrode surface and also to investigate the thiophene electroreductive behavior. Then, the solution was desulfurized via a square wave potentiometry method. The objective of this study was to find the optimal conditions. In this regard, the best adsorption potential, electroreduction potential, and square wave frequency were found to be ?0.54 V, ?0.95 V, and 1 Hz, respectively. Finally, a model fuel (containing 294 part per millions thiophene) was desulfurized by the square wave potentiometry method. Gas chromatography and Fourier transform infrared spectroscopy were used to examine the feed and product solutions. Gas chromatographic measurements revealed that sulfur content decreased to 55 part per millions. Based on the acquired results, electroreductive desulfurization could be designated as an efficient superseded for the commercial hydrodesulfurization process. However, more studies must perform to overcome technical limitations of electroreductive desulfurization technique and to guarantee its reliability.     

Melanterite and szomolnokite as weathering products of pyrite from the Bazhenovo Formation

Weathering of pyrite in the core recovered from black shales of the Bazhenovo Formation (Upper Jurassic-Lower Cretaceous) in the West Siberian marine basin promoted the successive formation of melanterite (FeSO₄ · 7H₂O) and szomolnokite (FeSO₄ · H₂O). Szomolnokite was detected in West Siberia for the first time.     

Weathering of ilmenite from Chavara deposit and its comparison with Manavalakurichi placer ilmenite,southwestern India

The magnetic fractions of ilmenite from the beach placer deposit of Chavara, southwest India have been studied for mineralogical and chemical composition to assess the range of their physical and chemical variations with weathering. Chavara deposit represents a highly weathered and relatively homogenous concentration. Significant variation in composition has been documented with alteration. The most magnetic of the fractions of ilmenite, separated at 0.15 Å, and with a susceptibility of 3.2 × 10^?6 m³ kg^?1, indicates the presence of haematite–ilmenite intergrowth. An iron-poor, titanium-rich component of the ilmenite ore has been identified from among the magnetic fractions of the Chavara ilmenite albeit with an undesirably high Nb₂O₅ (0.28%), Cr₂O₃ (0.23%) and Th (149 ppm) contents. The ilmenite from Chavara is compared with that from the nearby Manavalakurichi deposit of similar geological setting and provenance. The lower ferrous iron oxide (2.32–14.22%) and higher TiO₂ (56.31–66.45%) contents highlight the advanced state of alteration of Chavara. This is also evidenced by the relatively higher Fe³⁺/Fe²⁺ ratio compared to Manavalakurichi ilmenite. In fact, the ilmenite has significantly been converted to pseudorutile/leucoxene.     

3d transition metal L-edge X-ray absorption studies of the dichalcogenides of Fe, Co and Ni

The X-ray absorption spectra of the transition metal L_3,2-edges of the dichalcogenides FeS₂ (pyrite), FeSe₂, FeTe₂, CoS₂, CoSe₂, CoTe₂, NiS₂, NiSe₂ and NiTe₂ have been studied. These spectra are compared with theoretical simulations make using the atomic multiplet approach assuming on octahedral site for the metal atoms. The Ni spectra can be closely simulated using this approach but the Fe and Co spectra show less good fits to the experimental data. The reasons for this and its implications for the use of L-edge spectra in the study of such minerals are discussed in terms of the covalency and the ground states of the compounds; these results indicate the mixing of the ground states increases in the order Ni<Co<Fe.