Pressure-induced incipient amorphization of α-quartz and transition to coesite in an eclogite from Antarctica: a first record and some consequences

Monocrystalline quartz inclusions in garnet and omphacite from various eclogite samples from the Lanterman Range (Northern Victoria Land, Antarctica) have been investigated by cathodoluminescence (CL), Raman spectroscopy and imaging, and in situ X‐ray (XR) microdiffraction using the synchrotron. A few inclusions, with a clear‐to‐opalescent lustre, show ‘anomalous’ Raman spectra characterized by weak α‐quartz modes, the broadening of the main α‐quartz peak at 465 cm^?1, and additional vibrations at 480–485, 520–523 and 608 cm^?1. CL and Raman imaging indicate that this ‘anomalous’α‐quartz occurs as relicts within ordinary α‐quartz, and that it was preserved in the internal parts of small quartz inclusions. XR diffraction circular patterns display irregular and broad α‐quartz spots, some of which show an anomalous d‐spacing tightening of ～2%. They also show some very weak, hazy clouds that have d‐spacing compatible with coesite but not with α‐quartz. Raman spectrometry and XR microdiffraction characterize the anomalies with respect to α‐quartz as (i) a pressure‐induced disordering and incipient amorphization, mainly revealed by the 480–485 and 608‐cm^?1 Raman bands, together with (ii) a lattice densification, evidenced by d‐spacing tightening; (iii) the cryptic development of coesite, 520–523 cm^?1 being the main Raman peak of coesite and (iv) Brazil micro‐twinning. This ‘anomalous’α‐quartz represents the first example of pressure‐induced incipient amorphization of a metastable phase in a crustal rock. This issue is really surprising because pressure‐induced amorphization of metastable α‐quartz, observed in impactites and known to occur between 15 and 32 GPa during ultrahigh‐pressure (UHP) experiments at room temperature, is in principle irrelevant under normal geological P–T conditions. A shock (due to a seism?) or a local overpressure at the inclusion scale (due to expansion mismatch between quartz and its host mineral) seem the only geological mechanisms that can produce such incipient amorphization in crustal rocks. This discovery throws new light on the modality of the quartz‐coesite transition and on the pressure regimes (non‐lithostatic v. lithostatic) during high‐pressure/UHP metamorphism. In particular, incipient amorphization of quartz could favour the quartz‐coesite transition, or allow the growth of metastable coesite, as already experimentally observed.     

Isotope hydrological study of mean transit time in the granitic Strengbach catchment (Vosges massif,France): application of the FlowPC model with modified input function

Measurements of ¹⁸O concentrations in precipitation, soil solution, spring and runoff are used to determine water transit time in the small granitic Strengbach catchment (0·8 km²; 883–1146 m above sea level) located in the Vosges Mountains of northeastern France. Water transit times were calculated by applying the exponential, exponential piston and dispersion models of the FlowPC program to isotopic input (rainfall) and output (spring and stream water) data sets during the period 1989–95. The input function of the model was modified compared with the former version of the model and estimated by a deterministic approach based on a simplified hydrological balance. The fit between observed and calculated output data showed marked improvements compared with results obtained using the initial version of the model. An exponential piston version of the model applied to spring water indicates a 38·5 month mean transit time, which suggests that the volume in the aquifer, expressed in water depth, is 2·4 m. A considerable thickness (>45 m) of fractured bedrock may be involved for such a volume of water to be stored in the aquifer. Copyright © 2005 John Wiley & Sons, Ltd.     

Green Lake Landslide and other giant and very large postglacial landslides in Fiordland,New Zealand

Green Lake Landslide is an ancient giant rock slide in gneiss and granodiorite located in the deeply glaciated Fiordland region of New Zealand. The landslide covers an area of 45 km² and has a volume of about 27 km³. It is believed to be New Zealand's largest landslide, and possibly the largest landslide of its type on Earth. It is one of 39 known very large (10⁶–10⁷ m³) and giant (≥10⁸ m³) postglacial landslides in Fiordland discussed in the paper. Green Lake Landslide resulted in the collapse of a 9 km segment of the southern Hunter Mountains. Slide debris moved up to 2.5 km laterally and 700 m vertically, and formed a landslide dam about 800 m high, impounding a lake about 11 km long that was eventually infilled with sediments. Geomorphic evidence supported by radiocarbon dating indicates that Green Lake Landslide probably occurred 12 000–13 000 years ago, near the end of the last (Otira) glaciation. The landslide is described, and its geomorphic significance, age, failure mechanism, cause, and relevance in the region are discussed, in relation to other large landslides and recent earthquake-induced landslides in Fiordland. The slope failure occurred on a low-angle fault zone undercut by glacial erosion, and was probably triggered by strong shaking (MM IX–X) associated with a large (≥ M 7.5–8) earthquake, on the Alpine Fault c. 80 km to the northwest. Geology was a major factor that controlled the style and size of Green Lake landslide, and in that respect it is significantly different from most other gigantic landslides. Future large earthquakes on the Alpine Fault in Fiordland are likely to trigger more very large and giant landslides across the region, causing ground damage and devastation on a scale that has not occurred during the last 160 years, with potentially disastrous effects on towns, tourist centres, roads, and infrastructure. The probability of such an event occurring within the next 50 years may be as high as 45%.     

A critical state model for sands dependent on stress and density

An elastoplastic model for sands is presented in this paper, which can describe stress–strain behaviour dependent on mean effective stress level and void ratio. The main features of the proposed model are: (a) a new state parameter, which is dependent on the initial void ratio and initial mean stress, is proposed and applied to the yield function in order to predict the plastic deformation for very loose sands; and (b) another new state parameter, which is used to determine the peak strength and describe the critical state behaviour of sands during shearing, is proposed in order to predict simply negative/positive dilatancy and the hardening/softening behaviour of medium or dense sands. In addition, the proposed model can also predict the stress–strain behaviour of sands under three-dimensional stress conditions by using a transformed stress tensor instead of ordinary stress tensor. Copyright © 2004 John Wiley & Sons, Ltd.     

SHRIMP U–Pb ages of diagenetic and hydrothermal xenotime from the Archaean Witwatersrand Supergroup of South Africa

SHRIMP dating of xenotime overgrowths on detrital zircon grains can constrain maximum durations since diagenesis and therefore provide minimum dates of sediment deposition. Thus, xenotime dating has significant economic application to Precambrian sediment-hosted ore deposits, such as Witwatersrand Au–U, for which there are no precise depositional ages. The growth history of xenotime in the Witwatersrand Supergroup is texturally complex, with several phases evident. The oldest authigenic xenotime ²⁰⁷Pb/²⁰⁶Pb age obtained in sandstone underlying the Vaal Reef is 2764 ± 5 Myr (1 σ), and most likely represents a mixture of diagenetic and hydrothermal growth. Nevertheless, this represents the oldest authigenic mineral age yet recorded in the sequence and provides a minimum age of deposition. Other xenotime data record a spread of ages that correspond to numerous post-diagenetic thermotectonic events (including a Ventersdorp event at ≈ 2720 Ma) up to the ≈2020 Ma Vredefort event.     

The mass ratio of Nova Muscae 1991

We report intermediate resolution H spectroscopy of the black hole candidate Nova Muscae 1991 during quiescence. We classify the companion star as a K3-K4V which contributes 85±6 percent to the total flux from the binary. The photospheric absorption lines are broadened by 106±13 kms⁻¹ with respect to template field stars, leading to a system mass ratio of q =M₁/M₂ = 7.8_−2.0^+3.4. Doppler imaging of the H line shows strong emission coming from the secondary star (EW=3.1±0.6Å) which we associate with chromospheric activity. However, the hot-spot is not detected and this may indicate a lower mass transfer rate than in other X-ray transients of comparable orbital periods. The surface brightness distribution of the accretion disk in H follows a relation I∝R^−1.1, less steep than typically observed in cataclysmic variables. Updated system parameters are also presented.     

Spectral Study of Ionized Xenon Using a Capillary Pulsed Discharge

This work presents preliminaries spectroscopic results about ionized xenon and xenon-helium mixture using a capillary pulsed discharge under several experimental results.     

Porphyroblast inclusion-trail orientation data: eppure non son girate*!

Extensive examination of large numbers of spatially orientated thin sections of orientated samples from orogens of all ages around the world has demonstrated that porphyroblasts do not rotate relative to geographical coordinates during highly non-coaxial ductile deformation of the matrix subsequent to their growth. This has been demonstrated for all tectonic environments so far investigated. The work also has provided new insights and data on metamorphic, structural and tectonic processes including: (1) the intimate control of deformation partitioning on metamorphic reactions; (2) solutions to the lack of correlation between lineations that indicate the direction of movement within thrusts and shear zones, and relative plate motion; and (3) a possible technique for determining the direction of relative plate motion that caused orogenesis in ancient orogens.