A study of bernalite,Fe(OH)3, using Mössbauer spectroscopy,optical spectroscopy and transmission electron microscopy

To study the crystal chemistry of bernalite, Fe(OH)₃, and the nature of the octahedral Fe³⁺ environment, Mössbauer spectra were recorded from 80 to 350 K, optical spectra were recorded at room temperature and a sample was studied using transmission electron microscopy. The Mössbauer spectrum of bernalite consists of a single six-line magnetic spectrum at 80 K. A broadened six-line magnetic spectrum with significantly less intensity is observed at higher temperatures, and is attributed to a small fraction of bernalite occurring as small particles. The variation of hyperfine magnetic field data for bulk bernalite with temperature is well described by the Weiss molecular field model with parameters of H ₀ = 55.7±0.3 T and T _N = 427±5K. The centre shift data were fitted to the Debye model with parameters ₀=0.482±0.005 mm/s (relative to -Fe) and _M=492±30 K. The quadrupole shift is near zero at 300 K, and does not vary significantly with temperature. Absorption spectra in the visible and near infrared range show three crystal field bands of Fe³⁺ at 11 300, 16000 and 23 200 cm^-1, giving a crystal field splitting of 14 570 cm^-1 and Racah parameters of B=629 cm^-1 and C=3381 cm^-1. Infrared reflection spectra show two distinct OH-stretching frequencies, which could correspond to two structurally different types of OH groups. A band was also observed at 2250 cm^-1, suggesting the presence of molecular CO₂ in the large cation site. Analytical transmission electron microscopy indicates that Si occurs within the bernalite structure as well as along domain boundaries. Electron diffraction and imaging show that bernalite is polysynthetically twinned along {100} planes with twin domains ranging from 3 to 20 nm in thickness. Results are discussed with respect to the nature of the octahedral Fe³⁺ site, and compared with values for other iron oxides and hydroxides.     

Comparing Solar Minimum 23/24 with Historical Solar Wind Records at 1 AU

Based on the variations of sunspot numbers, we choose a 1-year interval at each solar minimum from the beginning of the acquisition of solar wind measurements in the ecliptic plane and at 1 AU. We take the period of July 2008??C?June 2009 to represent the solar minimum between Solar Cycles 23 and 24. In comparison with the previous three minima, this solar minimum has the slowest, least dense, and coolest solar wind, and the weakest magnetic field. As a result, the solar wind dynamic pressure, dawn?Cdusk electric field, and geomagnetic activity during this minimum are the weakest among the four minima. The weakening trend had already appeared during solar minimum 22/23, and it may continue into the next solar minimum. During this minimum, the galactic cosmic ray intensity reached the highest level in the space age, while the number of solar energetic proton events and the ground level enhancement events were the least. Using solar wind measurements near the Earth over 1995??C?2009, we have surveyed and characterized the large-scale solar wind structures, including fast-slow stream interaction regions (SIRs), interplanetary coronal mass ejections (ICMEs), and interplanetary shocks. Their solar cycle variations over the 15 years are studied comprehensively. In contrast with the previous minimum, we find that there are more SIRs and they recur more often during this minimum, probably because more low- and mid-latitude coronal holes and active regions emerged due to the weaker solar polar field than during the previous minimum. There are more shocks during this solar minimum, probably caused by the slower fast magnetosonic speed of the solar wind. The SIRs, ICMEs, and shocks during this minimum are generally weaker than during the previous minimum, but did not change as much as did the properties of the undisturbed solar wind.     

Lithologic mapping of HED terrains on Vesta using Dawn Framing Camera color data

The surface composition of Vesta, the most massive intact basaltic object in the asteroid belt, is interesting because it provides us with an insight into magmatic differentiation of planetesimals that eventually coalesced to form the terrestrial planets. The distribution of lithologic and compositional units on the surface of Vesta provides important constraints on its petrologic evolution, impact history, and its relationship with vestoids and howardite‐eucrite‐diogenite (HED) meteorites. Using color parameters (band tilt and band curvature) originally developed for analyzing lunar data, we have identified and mapped HED terrains on Vesta in Dawn Framing Camera (FC) color data. The average color spectrum of Vesta is identical to that of howardite regions, suggesting an extensive mixing of surface regolith due to impact gardening over the course of solar system history. Our results confirm the hemispherical dichotomy (east‐west and north‐south) in albedo/color/composition that has been observed by earlier studies. The presence of diogenite‐rich material in the southern hemisphere suggests that it was excavated during the formation of the Rheasilvia and Veneneia basins. Our lithologic mapping of HED regions provides direct evidence for magmatic evolution of Vesta with diogenite units in Rheasilvia forming the lower crust of a differentiated object.     

Carbon-Oxidizing and Sulfate-Reducing Bacteria in Mozhaisk Reservoir Soils

The population and distribution of carbon-oxidizing and sulfate-reducing bacteria in the soils of the Mozhaisk Reservoir are studied.     

Phosphides in Volcanic Seamount Basalts in the Sea of Japan

Electron microprobe data on phosphide grains detected for the first time in basalts from volcanic edifices in the Sea of Japan are presented. The find of phosphides can testify to the endogenic source of phosphorus and, consequently, volcanogenic hydrothermal origin of phosphorites in the Sea of Japan.     

A Search for a Globular Cluster whose Passage Through the Galactic Disk Could Induce the Formation of the Gould Belt

The distribution of sites where globular clusters have crossed the Galactic disk during the last 100 million years has been analyzed using the most recent kinematic data for 133 globular clusters (GCs). ThreeGCs (NGC 6341, NGC 7078, and ω Cen) whose distances between the positions where they crossed the Galactic disk and trajectories of the Gould Belt are less than 20% of their heliocentric distances at the crossing time (82, 98, and 96 million years ago, respectively) have been identified. For each of the clusters, this was their next to last, rather than their last, crossing of the Galactic disk. The passage of any one of these three GCs through the disk could potentially have initiated the formation of the Gould Belt.     

DISASTER ANALYSIS AND COUNTERMEASURES OF LAND SUBSIDENCE CAUSED BY COAL CUTTING IN CHINA

In recent years, many coal-producing countries have paid great attention to the land subsidence causedby coal cutting. In China, because of the dense population in coalfield areas, the land subsidence hazard is more seri-ous. After a brief analysis on the mechanism of land subsidence, this paper gives a comprehensive and systematical ac-count on all kinds of hazards caused by the land subsidence in China. The study shows that land subsidence has endan-gered land, buildings, traffic and communication lines, dykes and dams. It also causes damage to ecological and socialenvironment. In order to lessen the hazard of land subsidence, preventive measures should be taken to reduce the col-lapse amount, such as extraction with stowing, banded mining system, succession and coordination mining system, orhigh-pressure mudflow between rock strata. Measures of reinforcing or moving certain buildings should also be taken toreduce the destructive degree. In order to harness the subsidence land and bring them under control for fanning, mea-sures should be taken such as filling with spoil or fine breeze, excavating the deeper and covering the shallower land.     

Paleoproterozoic Extensional Structure and Its Controlling on Mineralization in the East of Liaoning Province

IntroductionThe area of eastern Liaoning is an importantmetal and nonmetal metallogenetic district in China,and the Liaohe group is one of the most importantstrata that hosts Pb, Zn, Au, B and Mg etcstratabound deposits. Up to now many geo1ogistssuch as Z…     

The Singapore River thematic zone: sustainable tourism in an urban context

This paper explores the concept of sustainable tourism and how it applies to urban destinations such as Singapore. As tourism is an important industry in Singapore, in terms of employment, business activity and an income generator, the Singapore Tourism Board is continuously looking at potential avenues to make Singapore a competitive destination. We examine the use of thematic zones in Singapore as a strategy to achieve its ambition of becoming a tourism capital of the world. By focusing on a case study of the Singapore River thematic zone (one of the 11 thematic zones identified by the Singapore Tourism Board), we assess the viability of thematic zones in ensuring sustainable urban tourism. The paper closes with some theoretical reflections and policy implications arising from our key findings.