Ammonium adsorption by tidal flat surface sediments from the Yangtze Estuary

Ammonium adsorption by sediments plays an important role in the cycle of nitrogen in the estuarine tidal flat ecosystem. Ammonium adsorption on tidal flat sediments from the Yangtze estuary was studied using the simulation experiment. The findings indicated that there was linear adsorption by the tidal flat sediments for the lower ammonium concentration (<10 mM) in the overlying waters. The adsorption coefficient of ammonium in the study area ranged from 3.81 to 9.00, and had a significant positive correlation with total organic carbon (r = 0.779, = 0.02284 , n=8), reflecting that organic matter might be one of the main factors controlling the behavior of ammonium adsorption. It also showed that salinity had a pronounced effect on ammonium adsorption, and that salinity affected the distribution of ammonium between the sediments and waters. The amount of ammonium adsorption on sediments gradually decreased with the increasing salinity. Especially within the range of lower salinity, just a little change of salinity had a dramatic influence on ammonium adsorption by sediments.     

广州市似大地水准面精化的研究

阐述广州市似大地水准面精化的目的及意义,明确该项目的总体目标,以及实施的技术方案.     

论内蒙大井铜-锡多金属矿区旋转构造体系

首次提出“旋转构造体系”在本区铜、锡的成矿上起着至关重要的作用,它控制着地层、岩脉、构造与矿脉的分布及产出.区内主要构造格架的特征表现为：在海西期构造的基础上,燕山期发生旋转,即在F1、F2等NE向压扭性左行断裂构造夹持的地块因剪切作用而发生整体顺时针的旋转;形成的配套构造包括呈羽状排布与同步剪切的近SN向的F3、F4、F5、F6压扭性断裂和NWW向张扭性断裂（矿脉主要充填于该组中）;同时造成矿区内地层、岩脉的走向与区域上的走向的极不协调.     

超高压变质岩物理性质的相关性对建立结晶岩区地球物理解释标尺的意义

大陆科学钻探为认识深部地壳的结构、组成、力学性质和物理状态提供了重要的基础数据。岩石物理性质的测量对于原位测井资料的校正和地表地球物理测量的解释具有重要意义,岩石物理性质和岩石学研究相结合,还能为岩石的变质作用以及变质过程中化学成分的迁移提供必要的约束。本文主要对CCSD100-3100m的综合岩石物理资料进行了相关性调查和聚类分析,并得出如下结论:(1)岩石物理性质中的地震波速度、密度、热导率之间具有强相关性,他们都受岩石中主要矿物的组成和含量所控制;(2)岩石的电阻率和磁化率受金属氧化物含量的控制,与岩性有相关性;孔隙度、渗透率与岩性没有相关性;(3)利用岩石的物理性质可以反演不同的岩性,其中地震波速度、密度和热导率对榴辉岩和片麻岩大类具有很好的分类效果,而结合磁化率和电阻率则能更好的区分出超基性岩、正片麻岩和副片麻岩。上述结论对综合地球物理解释中物理参数的选取和结晶岩区地球物理解释标尺的建立具有重要的意义。     

Three-dimensional ionospheric tomography by an improved algebraic reconstruction technique

An improved algebraic reconstruction technique (IART) is presented for the tomographic reconstruction of ionospheric electron density (IED). This method applies the total electron content (TEC) measurements to invert the spatial distribution of the IED from a set of apriori IED distributions. In this new method, a data-driven adjustment of the relaxation parameter is performed to improve the computation efficiency and image quality of the classical algebraic reconstruction technique (ART). In addition, the new algorithm is also combined with ionospheric space discretization technique to simplify the inversion of IED, and it applies CHAMP occultation data to improve the vertical resolution. A numerical simulation experiment is carried out to validate the reliability of the new method. It is then applied to the inversion of IED from real GPS data. Inverted results show that the IART algorithm has better accuracy and efficiency than the conventional ART algorithm. The reliability of the IART algorithm is also validated by ionosonde data recorded at Wuhan station.     

Investigations on the extraction of molybdenum and vanadium from ammonia leaching residue of spent catalyst

Extraction of molybdenum and vanadium from ammonia leaching residue (main chemical composition: 2.05% Mo, 0.42% V, 65.6% Al₂O₃ and 10.7% SiO₂) of spent catalyst was investigated by roasting the residue with soda carbonate, followed by hydrometallurgical treatment of the roasted products. In the roasting process, over 91.3% of molybdenum and 90.1% of vanadium could be extracted when a charge containing a sodium carbonate to spent catalyst ratio of 0.15 was roasted at 750 °C for 45 min and the roasted mass was leached with water (liquid to solid ratio of 2) at 80–90 °C for 15 min. After the purification of leach liquor, an extraction solvent consisting of 20 vol.% trialkylamine (N₂₃₅, commercialized in China) and 10 vol.% secondary octyl alcohol (phase modifier) dissolved in sulfonated kerosene was used to extract molybdenum and vanadium in leach liquor. 10 wt.% ammonia water was used as stripping agent. Adding 30 g/l NH₄NO₃ to the stripping solution and adjusting the pH to 7–8.5, over 99% of vanadium can be crystallized as ammonium metavanadate. Over 98% of molybdenum can be crystallized as ammonium polymolybdate when pH is between 1.5 and 2.5 (pH is adjusted by HNO₃). Ammonium metavanadate and ammonium polymolybdate were calcinated at 500–550 °C, the purity of MoO₃ and V₂O₅ was 99.08% and 98.06% respectively. In the whole process, 88.2% of molybdenum and 87.1% of vanadium could be achieved. The proposed roasting, leaching and separation steps give a feasible alternative for the processing of ammonia leaching residue of spent catalyst and can be applied in the comprehensive utilization of low grade molybdenum ores.     

地壳动力学在石油开发中的应用(六)——构造应力场与钻井稳定

构造应力场的作用是影响钻井稳定的主要原因,它造成井壁破坏、套管破损、油井出砂,以致停产报废,是对石油生产有一定负面影响的重要因素。     

2016年6月哈尔滨地区降水异常特征分析

2016年6月哈尔滨地区降水出现异常,比历年同期多一倍,全市月平均降水量为1961年以来同期第1位。本文利用地面月降水量资料及NCEP/NCAR再分析资料,对哈尔滨地区2016年6月降水异常特征、成因及30年来该地区6月降水量变化趋势进行了分析。结果表明：(1)鄂霍茨克海以西位置的阻塞高压的出现和发展是造成哈尔滨地区降水异常偏多的主要原因。(2)中高纬度和副热带高压之间的水汽输送的环流配置特征起到了关键的作用,为该地区降水异常偏多提供了有利水汽条件。(3)850hPa风场存在风向和风速的强辐合区,该动力结构特征更有利于产生强降水。(4)30年来哈尔滨地区6月降水量总体呈缓慢上升趋势,13个区、县(市)除了通河和依兰逐年减少外,其它区、县(市)逐年增加。     

区域尺度蒸散发遥感估算——反演与数据同化研究进展

遥感技术近年来在估算区域尺度蒸散发中应用广泛。不同方法在驱动数据、模型机理和适用范围往往存在很大差别。鉴于此,阐述了基于传统方法空间尺度扩展的遥感模型,经验统计公式,特征空间法,单源、双源垂向能量平衡余项法等几类的遥感蒸散发反演方法,简要介绍了三温模型、非参数化模型、半经验模型、集成模型等常用模型。同时,分析了遥感数据同化实现连续估算区域蒸散发的主要思路,综述了基于能量平衡和基于复杂过程模型的数据同化的原理、方法演进及常用同化算法等。最后,探讨了各类区域蒸散发遥感方法的优劣、展望了模型机理完善、不确定性研究、结果验证等与蒸散发直接反演和数据同化相关的研究方向。     

Impact of Megacity Shanghai on the Urban Heat-Island Effects over the Downstream City Kunshan

The impact of upstream urbanization on the enhanced urban heat-island (UHI) effects between Shanghai and Kunshan is investigated by analyzing seven years of surface observations and results from mesoscale model simulations. The observational analysis indicates that, under easterly and westerly winds, the temperature difference between Shanghai and Kunshan increases with wind speed when the wind speed \(<\) 5 m s \(^{-1}\) . The Weather Research and Forecasting (WRF) numerical model, coupled with a one-layer urban canopy model (UCM), is used to examine the UHI structure and upstream effects by replacing the urban surface of Shanghai and/or Kunshan with cropland. The WRF/UCM modelling system is capable of reproducing the surface temperature and wind field reasonably well. The simulated urban canopy wind speed is a better representation of the near-surface wind speed than is the 10-m wind speed at the centre of Shanghai. Without the urban landscape of Shanghai, the surface air temperature over downstream Kunshan would decrease by 0.2–0.4  \(^{\circ }\) C in the afternoon and 0.4–0.6  \(^{\circ }\) C in the evening. In the simulation with the urban landscape of Shanghai, a shallow cold layer is found above the UHI, with a minimum temperature of about \(-0.2\) to \(-\) 0.5  \(^{\circ }\) C during the afternoon hours. Strong horizontal divergence is found in this cold layer. The easterly breeze over Shanghai is strengthened at the surface by strong UHI effects, but weakened at upper levels. With the appearance of the urban landscape specific humidity decreases by 0.5–1 g kg \(^{-1}\) within the urban area because of the waterproof property of an urban surface. On the other hand, the upper-level specific humidity is increased because of water vapour transferred by the strong upward vertical motions.