In recent years, research on spatial scale and scale transformation of eroded sediment transport has become a forefront field in current soil erosion research, but there are very few studies on the scale effect problem in Karst regions of China. Here we quantitatively extracted five main factors influencing soil erosion, namely rainfall erosivity, soil erodibility, vegetative cover and management, soil and water conservation, and slope length and steepness. Regression relations were built between these factors and also the sediment transport modulus and drainage area, so as to initially analyze and discuss scale effects on sediment transport in the Wujiang River Basin (WRB). The size and extent of soil erosion influencing factors in the WRB were gauged from: Advanced Spaceborne Thermal Emission and Reflection Radiometer Global Digital Elevation Model (ASTER GDEM), precipitation data, land use, soil type and Normalized Difference Vegetation Index (NDVI) data from Global Inventory Modeling and Mapping Studies (GIMMS) or Advanced Very High Resolution Radiometer (AVHRR), and observed data from hydrometric stations. We find that scaling effects exist between the sediment transport modulus and the drainage area. Scaling effects are expressed after logarithmic transformation by a quadratic function regression relationship where the sediment transport modulus increases before decreasing, alongside changes in the drainage area. Among the five factors influencing soil erosion, slope length and steepness increases first and then decreases, alongside changes in the drainage area, and are the main factors determining the relationship between sediment transport modulus and drainage area. To eliminate the influence of scale effects on our results, we mapped the sediment yield modulus of the entire WRB, adopting a 1 000 km2 standard area with a smaller fitting error for all sub-basins, and using the common Kriging interpolation method. 相似文献
Increased interest in the fractionation of Sn isotopes has led to the development of several techniques for preparing cassiterite (SnO2, the primary ore of Sn) for isotopic analysis. Two distinct methods have been applied in recent isotopic studies of cassiterite: (a) reduction to tin metal with potassium cyanide (KCN) at high temperature (800 °C), with subsequent dissolution in HCl, and (b) reduction to a Sn solution with hydriodic acid (HI) at low temperature (100 °C). This study compares the effectiveness and accuracy of these two methods and contributes additional methodological details. The KCN method consistently yielded more Sn (> 70% in comparison with < 5%), does not appear to fractionate Sn isotopes at high temperatures over a 2‐hour period and produced consistent Sn isotope values at flux mass ratios of ≥ 4:1 (flux to mineral) with a minimum reduction time of 40 min. By means of a distillation experiment, it was demonstrated that HI could volatilise Sn, explaining the consistently low yields by this method. Furthermore, the distillation generated Sn vapour, which is up to 0.38‰ per mass unit different from the starting material, the largest induced Sn fractionation reported to date. Accordingly, the HI method is not recommended for cassiterite preparation for Sn isotopic analysis. 相似文献
The runoff and sediment load of the Loess Plateau have changed significantly due to the implementation of soil and water conservation measures since the 1970s. However, the effects of soil and water conservation measures on hydrological extremes have rarely been considered. In this study, we investigated the variations in hydrological extremes and flood processes during different periods in the Yanhe River Basin (a tributary of the Loess Plateau) based on the daily mean runoff and 117 flood event data from 1956 to 2013. The study periods were divided into reference period (1956–1969), engineering measures period (1970–1995), and biological control measures period (1996–2013) according to the change points of the annual streamflow and the actual human activity in the basin. The results of the hydrological high extremes (HF1max, HF3max, HF7max) exhibit a decreasing trend (P?<?0.01), whereas the hydrological low extremes (HBF1min, HBF3min, HBF7min) show an increasing trend during 1956–2013. Compared with the hydrological extremes during the reference period, the hydrological high extremes increased during the engineering measures period at low (<?15%) and high frequency (>?80%), whereas decreased during the biological control measures period at almost all frequencies. The hydrological low extremes generally increased during both the engineering measures and biological control measures periods, particularly during the latter period. At the flood event scale, most flood event indices in connection with the runoff and sediment during the engineering measures period were significantly higher than those during the biological control measures period. The above results indicate that the ability to withstand hydrological extremes for the biological control measures was greater than that for the engineering measures in the studied basin. This work reveals the effects of different soil and water conservation measures on hydrological extremes in a typical basin of the Loess Plateau and hence can provide a useful reference for regional soil erosion control and disaster prevention policy-making.