Soil chemistry and shale weathering on a hillslope influenced by convergent hydrologic flow regime at the Susquehanna/Shale Hills Critical Zone Observatory

Soil chemistry data (major and REEs) are presented from a swale transect for comparison to similar measurements on a planar transect published previously for the Susquehanna/Shale Hills Critical Zone Observatory. Similar reaction fronts are observed: plagioclase dissolution is indicated by Na and Ca depletion and a negative Eu anomaly; clay dissolution followed by particle loss is accompanied by depletion of Mg, K, Fe, Al and Si. However, in contrast to the planar transect, soils along the swale transect, especially in the topographically depressed site, do not show smooth elemental profiles. This documents both residuum soils and accumulation of colluvium sediments. The soils in the swale transect are thicker and on average wetter than those along the planar transect; however, the Ce anomaly observed in the swale soils is consistent with a generally oxic environment. Thus, preferential flowpaths are an important mechanism for water transport, preventing swale soils from water saturation.     

Geochemical behaviors of different element groups during shale weathering at the Susquehanna/Shale Hills Critical Zone Observatory

Major and trace element concentrations were measured in bedrock, regolith and stream sediments from a first-order catchment developed entirely on grey shale in central Pennsylvania, USA. These elements can be classified into five major groups based on statistical data analysis. The presence of different elemental groups is due to the mineralogical origin, cycling processes, and geochemical properties of these elements during soil formation. A better understanding of the behaviors of these elements during chemical weathering would allow for their possible use as natural tracers in Critical Zone processes.     

Genetic diversity and structure of natural and transplanted eelgrass populations in the Chesapeake and Chincoteague Bays

The objective of this study was to gain baseline population data on the genetic diversity and differentiation of eelgrass (Zostera marïna L.) populations in the Chesapeake and Chincoteague bays. Natural and transplanted eelgrass beds were compared using starch gel electrophoresis of allozymes. Transplanted eelgrass beds were not reduced in genetic diversity compared with natural beds. Inbreeding coefficients (F_IS) indicated that transplanted eelgrass beds had theoretically higher levels of outcrossing than natural beds, suggesting the significance of use of seeds as donor material and of seedling recruitment following transplantation diebacks. Natural populations exhibited very great genetic structure (F_ST=0.335), but transplanted beds were genetically similar to the donor bed and each other. Genetic diversity was lowest in Chincoteague Bay, reflecting recent restoration history since the 1930s wasting disease and geographical isolation from other east coast populations. These data provide a basis for developing a management plan for conserving eelgrass genetic diversity in the Chesapeake Bay and for guiding estuary-wide restoration efforts. It will be important to recognize that the natural genetic diversity of eelgrass in the estuary is distributed among various populations and is not well represented by single populations.     

Geochemistry of the blue gem coal bed, Knox county, Kentucky

The Blue Gem coal bed (Middle Pennsylvanian Westphalian B, Breathitt Formation), has low-ash (with some sample sites having less than 1% ash) and low-sulfur contents through parts of Knox County, Kentucky. Most collection sites exhibit similar vertical elemental trends in ash geochemistry. The relatively high-ash (>1% ash) lower part of the bed displays enrichment in TiO₂, Zr, Cr, V and Ni; Co, Zn, Rb and Mn show enrichment at some sites. A low-ash (<1% ash) middle part of the bed displays enrichment in Sr, Ba and CaO; Fe₂O₃ is enriched in samples with carbonate minerals. The upper part of the bed contains >1% ash and a relative enrichment in SiO₂, K₂O and Rb and a relative decrease in Cu, Ni, Co, Ba and Mn when compared to the middle part of the bed. Principal components analysis indicates that the samples with an ash content 0.63–1.0% show associations for Ni, Cu, Cr and Co. Samples with between 1.01–2.0% ash display strong element associations that suggest increased clastic sediment contributions (TiO₂, Zr, K₂O, Rb, SiO₂). The low-ash content and the upwards decrease in trace concentrations both suggest that the Blue Gem peat swamp was ombrotrophic through at least a part of its geologic history.     

Lateglacial and early Holocene surface exposure ages of glacial boulders in the Taiwanese high mountain range

Glacial landforms and sediments mapped in three presently unglaciated mountain massifs, the Nanhuta Shan, the Hsueh Shan and the Yushan, support the concept of repeated, multi-stage glaciations in the Taiwanese high mountain range during the late Pleistocene. New results from surface exposure dating using in situ produced cosmogenic ¹⁰Be measured in samples taken from erratic and moraine boulders in Nanhuta Shan at altitudes between 3100 and 3500 m are presented here. The results confirm independent and previously reported Optically Stimulated Luminescence (OSL) ages and ¹⁰Be exposure ages from glacial deposits in the same area and suggest a Lateglacial and early Holocene glaciation, the so called Nanhuta glacier advance with two substages at about 12–15 ka and 9.5 ka BP. The respective equilibrium line altitudes (ELA) were calculated at 3340 m and 3440 m with corresponding ELA depressions of 610 ± 100 m and 510 ± 100 m relative to the present day (theoretical) ELA, which is estimated to be at about 3950 ± 100 m in Taiwan. Large-scale erosional landforms indicate a much wider glacier extent during an earlier stage, which is not dated in Nanhuta Shan so far. Luminescence dating from near Hsueh Shan suggests an age of marine isotope stage (MIS) 4 for this stage.     

Examination of diatom-based changes from a climatically sensitive prairie lake (Saskatchewan, Canada) at different temporal perspectives

Paleoclimatic records from the climatically sensitive Canadian prairies are relatively rare due to the scarcity of study sites with continuous Holocene stratigraphic sequences. Oro Lake, a meromictic lake in the dry grasslands of Saskatchewan (Canada), contains a continuous Holocene diatom record spanning the last 10,000 years. Here we present analyses at three different time scales and resolution: (1) 1–3 yr resolution of the past 80 years, (2) century-scale analysis of the Holocene, and (3) decadal-scale analysis of the past 7000 years. Recent changes in the diatom assemblages and their respective salinity inferences were significantly related to measured effective moisture (precipitation minus evaporation, P−ET). The droughts of the 1930s, and a wet period during the 1950s are clearly evident in the diatom record, suggesting the Oro Lake record contains a sensitive archive of past climatic conditions. Century-scale analysis of the diatom record during the Holocene is consistent with a cool and moist climate in the early Holocene (prior to ca 9700 cal yr BP, 8600 ¹⁴C yr BP). An abrupt increase in diatom-inferred salinity at 9600 cal yr BP (8500 ¹⁴C yr BP) indicates the onset of an arid climate, with continuing arid conditions throughout the mid-Holocene. Decadal-scale analysis of the past 7000 years suggests that the mid-Holocene was more complex, with extended periods of increased variability in precipitation, particularly between ca 5800–3600 cal yr BP (5000–3200 ¹⁴C yr BP) which is characterized by intervals of increased effective moisture. The past 2000 years is characterized by reduced salinities and generally wetter conditions in comparison to the mid-Holocene. The combination of the different scales of analyses in this study provides a detailed account of the dynamic nature of climate from sub-decadal to millennial scale in the Oro Lake region within the Palliser Triangle. Climate model predictions suggest that the Canadian prairie region may see a higher frequency of extreme droughts under projected global warming, potentially similar to the most arid periods seen during the mid-Holocene when many lake basins completely dried out.     

Rock avalanching into a landslide-dammed lake causing multiple dam failure in Las Conchas valley (NW Argentina) — evidence from surface exposure dating and stratigraphic analyses

Generally landslide dams which exist for several hundreds to thousands of years are considered as stable. We show with an example from the Argentine Andes that such dams can exist for several thousands of years but still may fail catastrophically. Multiple rock avalanches impounded two lakes with surface areas of ~8 km² and ~600 km², respectively, in Las Conchas valley, NW Argentina. Surface exposure dating (SED) by ¹⁰Be of the rock-avalanche deposits or landslide scars indicates that these landslides occurred at 15,300±2,000 yr and 13,550±900 yr. The dams were stable during a strong earthquake, as suggested by seismites within related lake sediments and by multiple coeval landslides in this region, which occurred at ~7.5 kyr. However, when a further rock-avalanche fell into the lower, smaller lake at 4,800±500 yr the dam downriver was destroyed, presumably by the resulting tsunami wave. The resulting flood also destroyed an additional rock-fall dam which had formed at ~5,630 yr ¹⁴C cal BP 30 km downriver. The new dam formed by the second rock avalanche was eroded prior to 3,630 yr ¹⁴C cal BP. This dam erosion coincides with an important climatic shift towards more humid conditions in the Central Andes. Our results show that instead of direct effects of strong seismicity on landslide dams, (1) landsliding into a landslide-dammed lake, (2) abrupt hydrological changes, and (3) climate change towards conditions related to enhanced run-off are processes which can produce failures of quasi-stable natural dams.     

Compositional and Isotopic Analytical Methods in Archaeological Micromorphology

Resin‐impregnated sediment blocks are a by‐product of micromorphological sample processing. These blocks can be further studied using a variety of destructive, nondestructive, and minimally destructive geochemical techniques. X‐ray fluorescence microanalyses conducted on sediment blocks yield semiquantitative major and trace elemental abundances that can be used to generate compositional maps, and to illustrate compositional change within or between archaeological strata and features. Sediment blocks can also be drilled to obtain small sediment samples for stable oxygen and carbon isotopic analyses. Both elemental and isotopic analyses can be conducted in conjunction with micromorphological analyses to yield a holistic picture of archaeological sediment composition, source, and depositional processes. The integration of micromorphological, compositional, and isotopic analyses is used here to aid in the differentiation of calcareous ash and lime plasters from the Neolithic site of Asıklı Höyük, Turkey.     

A new isogon-cleavage classification and its application to natural and model fold studies

Traditional methods of studying natural folds are reviewed. A new method of describing cleavage attitude in folds is presented; the β plot. The combined graph of dip isogon angle ϕ (Hudleston 1973) and cleavage angle β is proposed as a linked classification of fold and cleavage geometry. Plots of β and βϕ are given for three natural fold examples. The classification is extended to the geometry and strain attitude (βϕ₅) of two finite-element models and the classical folding models. Results are compared and some tentative conclusions drawn on the relationship of cleavage, the XY plane of strain and dip isogons.