Hydrogeochemical and isotopic evidence of groundwater salinization in a coastal aquifer: a case study in Jeju volcanic island, Korea

In order to identify the origin of saline groundwater in the eastern part of Jeju volcanic island, Korea, a hydrogeochemical and isotopic study has been carried out for 18 observation wells located in east and southeast coastal regions. The total dissolved solid contents of groundwaters are highly variable (77–21,782 mg/l). Oxygen, hydrogen, sulfur, and strontium isotopic data clearly show that the saline water results from mixing of groundwater with seawater. Strontium isotopic compositions and Br/Cl and I/Cl ratios strongly suggest that the source of salinity is modern seawater intrusion. Hydrogeochemical characteristics based on bivariate diagrams of major and minor ions show that changes in the chemical composition of groundwater are mainly controlled by the salinization process followed by cation-exchange reactions. The highly permeable aquifers at the east coastal region are characterized by low hydraulic gradient and discharge rate and high hydraulic conductivity as compared with other regions. These properties enhance the salinization of groundwater observed in the study area. Based on the Cl, Br, and δ¹⁸O data, seawater was determined to have intruded inland some 2.5 km from the coastline. Considering the poor correlation of sampling depth and Cl concentrations observed, the position of seawater-freshwater interface is not uniformly distributed in the study area, due to heterogeneities of the basaltic aquifers.     

Computation of Tsunamis in the East (Japan) Sea Using Dynamically Interfaced Nested Model

-- A study of 1983 and 1993 tsunami events in the East (Japan) Sea using multigrid dynamically-interfaced finite difference models was performed to produce detailed features of coastal inundations along the eastern coast of Korea. The computational domain is composed of several subregions with different grid sizes connected in parallel or inclined directions. The innermost subregion represents the coastal alignment reasonably well and has a grid size of about 30 meters. Numerical simulations have been performed in the framework of shallow-water equations (linear, as well as nonlinear) over the plane or spherical coordinate system, depending on the dimensions of the subregion. Results of simulations show the general agreements with the observed data of the runup height for both tsunamis. The evolution of the distribution function of tsunami heights is studied numerically and it shows a tendency to the log-normal curve for a long distance from the source.     

Confidence bounds on risk assessments for underground nuclear waste repositories

The estimation of risk confidence bounds is an important element of a comprehensive probabilistic risk assessment for a radioactive waste repository. Normal distribution bounds may be used in the asymptotic limit of a very large number of Monte Carlo simulations, but sharp skewness of the risk distribution may severely retard the convergence process. The Tchebycheff bounds are parameter-free and may be applied regardless of distribution, save for the finiteness of variance. These bounds may be generally applicable, but they are invariably very broad. Better parameter-free bounds for mean risk are presented here, based on an inequality originally derived by Guttman.     

Probabilistic analysis of rock slope stability and random properties of discontinuity parameters, Interstate Highway 40, Western North Carolina, USA

Probabilistic analysis has been used as an effective tool to evaluate uncertainty so prevalent in variables governing rock slope stability. In this study a probabilistic analysis procedure and related algorithms were developed by extending the Monte Carlo simulation. The approach was used to analyze rock slope stability for Interstate Highway 40 (I-40), North Carolina, USA. This probabilistic approach consists of two parts: analysis of available geotechnical data to obtain random properties of discontinuity parameters; and probabilistic analysis of slope stability based on parameters with random properties. Random geometric and strength parameters for discontinuities were derived from field measurements and analysis using the statistical inference method or obtained from experience and engineering judgment of parameters. Specifically, this study shows that a certain amount of experience and engineering judgment can be utilized to determine random properties of discontinuity parameters. Probabilistic stability analysis is accomplished using statistical parameters and probability density functions for each discontinuity parameter. Then, the two requisite conditions, kinematic and kinetic instability for evaluating rock slope stability, are determined and evaluated separately, and subsequently the two probabilities are combined to provide an overall stability measure. Following the probabilistic analysis to account for variation in parameters, results of the probabilistic analyses were compared to those of a deterministic analysis, illustrating deficiencies in the latter procedure. Two geometries for the cut slopes on I-40 were evaluated, the original 75° slope and the 50° slope which has developed over the past 40 years of weathering.     

Recent carbon and nitrogen uptake rates of phytoplankton in Bering Strait and the Chukchi Sea

Cruises to Bering Strait and the Chukchi Sea in US waters from late June in 2002 to early September in 2004 and the Russian–American Long-term Census of the Arctic (RUSALCA) research cruise in 2004 covered all major water masses and contributed to a better understanding of the regional physics, nutrient dynamics, and biological systems. The integrated concentration of the high nitrate pool in the central Chukchi Sea was greater in this study than in previous studies, although the highest nitrate concentration (∼22 μM) in the Anadyr Water mass passing through the western side of Bering Strait was consistent with prior observations. The chlorophyll-a concentrations near the western side of the Diomede Islands ranged from 200 to 400 mg chl-a m⁻² and the range in the central Chukchi Sea was 200–500 mg chl-a m⁻² for the 2002–2004 Alpha Helix (HX) cruises. Chlorophyll-a concentrations for the 2004 RUSALCA cruise were lower than those from previous studies. The mean annual primary production of phytoplankton from this study, using a ¹³C–¹⁵N dual-isotope technique, was 55 g C m⁻² for the whole Chukchi Sea and 145 g C m⁻² for the plume of Anadyr–Bering Shelf Water in the central Chukchi Sea. In contrast, the averages of annual total nitrogen production were 13.9 g N m⁻² (S.D.=±16.2 g N m⁻²) and 33.8 g N m⁻² (S.D.=±14.1 g N m⁻²) for the Chukchi Sea and the plume, respectively. These carbon and nitrogen production rates of phytoplankton were consistently two-or three-fold lower than those from previous studies. We suggest that the lower rates in this study, and consequently more unused nitrate in the water column, were caused by lower phytoplankton biomass in the Bering Strait and the Chukchi Sea. However, we do not know if the lower rate of production from this study is a general decreasing trend or simply temporal variations in the Chukchi Sea, since temporal and geographical variations are substantially large and presently unpredictable.     

Photospheric Network as the Energy Source for the quiet-Sun corona

We propose a mechanism for the formation of a magnetic energy avalanche based on highly dynamic phenomena within the ubiquitous small-scale network magnetic elements in the quiet photosphere. We suggest that this mechanism may provide constant mass and energy supply for the corona and fast wind. Constantly emerging from sub-surface layers, flux tubes collide and reconnect generating magneto-hydrodynamic shocks that experience strong gradient acceleration in the sharply stratified photosphere/chromosphere region. Acoustic and fast magnetosonic branches of these waves lead to heating and/or jet formation due to cumulative effects (Tarbell et al., 1999). The Alfvén waves generated by post-reconnection processes have quite a restricted range of parameters for shock formation, but their frequency, determined by the reconnection rate, may be high enough (0.1–2.5 s^–1) to carry the energy into the corona. We also suggest that the primary energy source for the fast wind lies far below the coronal heights, and that the chromosphere and transition region flows and also radiative transient form the base of the fast wind. The continuous supply of emerging magnetic flux tubes provides a permanent energy production process capable of explaining the steady character of the fast wind and its energetics.     

Contamination of water and soil by the Erdenet copper–molybdenum mine in Mongolia

As one of the largest copper–molybdenum (Cu–Mo) mines in the world, the Erdenet Mine in Mongolia has been active since 1978 and is expected to continue operations for at least another 30 years. In this study, the potential impacts of mining activities on the soil and water environments have been evaluated. Water samples showed high concentrations of sulfate, calcium, magnesium, Mo, and arsenic, and high pH values in the order of high to low as follows: tailing water > Khangal River > groundwater. Statistical analysis and the δ²H and δ¹⁸O values of water samples indicate that the tailing water directly affects the stream water and indirectly affects groundwater through recharge processes. Soil and stream sediments are highly contaminated with Cu and Mo, which are major elements of ore minerals. Based on the contamination factor (CF), the pollution load index (PLI), and the degree of contamination (C_d), soil appears to be less contaminated than stream sediments. The soil particle size is similar to that of tailing materials, but stream sediments have much coarser particles, implying that the materials have different origins. Contamination levels in stream sediments display a tendency to decrease with distance from the mine, but no such changes are found in soil. Consequently, soil contamination by metals is attributable to wind-blown dusts from the tailing materials, and stream sediment contamination is caused by discharges from uncontained subgrade ore stock materials. Considering the evident impact on the soil and water environment, and the human health risk from the Erdenet Mine, measures to mitigate its environmental impact should be taken immediately including source control, the establishment of a systematic and continuous monitoring system, and a comprehensive risk assessment.     

Spatial assessment of groundwater quality in the Jangseong region,South Korea

A total of 129 groundwater samples were collected in the Jangseong region of South Korea to characterize and evaluate groundwater quality and its suitability for irrigation and domestic uses. Samples were chemically analyzed for major ions, pH, electrical conductivity, and total dissolved solids following standard methods. The AquaChem 2014.2 model linked with PHREEQC was used for the statistical analysis and characterization of the hydrochemistry of the groundwater. The analysis showed that in all samples Ca–HCO₃ was the leading water type and that the abundance of major cations was in the order Ca > Na > Mg > K, and of anions in the order HCO₃ > Cl > SO₄ > F. According to the correlation analysis, Ca showed strong interdependence with HCO₃, suggesting that these parameters may have originated from common sources. Saturation index calculations indicated that all samples were undersaturated with respect to aragonite, calcite, dolomite, fluorite, gypsum, halite, and siderite, and oversaturated with respect to goethite and hematite. The irrigation suitability analysis revealed that groundwater in the Jangseong area can be used for irrigation without any restrictions based on EC, sodium adsorption ratio, percent sodium, residual sodium carbonate, Kelley ratio, permeability index, and the US Salinity Laboratory diagram analysis. The drinking water suitability analysis made for major parameters by comparison with the WHO guidelines indicates that the groundwater in the area is suitable for drinking except in some samples with high nitrate–N concentrations. The elevated nitrate concentrations in the groundwater are likely an indicator of agricultural pollution.     

Arsenic and metal contamination of water resources from mining wastes in Korea

 Water resources near a gold-mine waste site were studied for the distribution and contents of contaminants, and their behavior in the surface and groundwater systems. Arsenic, cadmium, and manganese were identified with levels exceeding the drinking water guidelines of WHO (World Health Organization), and their distribution depended upon the differences in source materials and in spatial pH variations. Originating from arsenopyrite, concentrations of dissolved arsenic were controlled by sorption with amorphous iron (Fe(OH)₃) and carbonate minerals. Cadmium and manganese were derived from the mineral phase including sphalerite (ZnS), otavite (CdCO₃), and rhodochrosite (MnCO₃); their concentrations in water resources were limited by the solubility of mineral phases. All of these processes are significantly pH-dependent, implying that a small decline in pH could result in a drastic increase in contaminant concentrations and become a pollution threat to the water resources of the Gubong area. Received: 13 December 1999 · Accepted: 21 March 2000