甘肃北山老金厂金矿床载金矿物特征、原位硫同位素组成及其对成矿的指示意义

老金厂金矿床是北山成矿南带最具代表性的中低温岩浆热液型金矿床之一,其规模为中型。依据脉体穿插、矿物共生组合和矿石结构构造等特征,将矿床矿化作用过程划分为石英-黄铁矿阶段（Ⅰ）、石英-含砷黄铁矿-毒砂阶段（Ⅱ）、石英-黄铁矿-多金属硫化物阶段（Ⅲ）和石英-方解石阶段（Ⅳ）。利用电子探针研究了不同成矿阶段载金矿物的元素组成及其分布规律。Ⅰ阶段：黄铁矿以粗粒自形立方体为主,粒度为0.50~1.50 mm,贫As、Au;毒砂含量极少,呈细粒他形。Ⅱ阶段：含砷黄铁矿周围常有大量毒砂产出,含砷黄铁矿多为立方体、五角十二面体,粒度为0.30~1.00 mm,富As、Au;该阶段矿化最为强烈,毒砂主要形成于此时期,多呈棱柱状、柱状、放射状集合体,显示富S亏As特征。Ⅲ阶段：多以黄铁矿-黄铜矿-闪锌矿共生组合脉的形式产出,黄铁矿多呈长条状,以富S、Cu、Zn、Au和贫Fe、As为特征。Ⅳ阶段：矿化作用极弱,毒砂、黄铁矿含量极少,为细粒他形。原位硫同位素组成显示：Ⅰ阶段黄铁矿δ³⁴S_V-CDT值为-3.8‰~-2.9‰,均值为-3.3‰;Ⅱ阶段黄铁矿和毒砂δ³⁴S_V-CDT值为-4.7‰~2.6‰,均值为-3.3‰;Ⅲ阶段黄铁矿和闪锌矿δ³⁴S_V-CDT值主要分布于-1.9‰~1.0‰之间,均值为0.1‰。此3个阶段硫同位素组成反映了成矿期硫主要来源于幔源岩浆,混入了部分地层硫。综合前人研究成果,认为成矿早期至晚期,成矿流体总体上由富S贫As向富As贫S演化。Ⅰ阶段体系处于中性稳定的环境,硫源充足;Ⅱ阶段为贫S富As的高氧逸度环境,由于大气降水对地层的淋滤渗透,混入富As流体,Au可能与As结合形成Au-As络合物,在成矿有利部位富集沉淀;Ⅲ阶段成矿元素种类丰富,体系为富S贫As的弱还原环境,Au很可能与HS^-、S^-形成络合物进入黄铁矿晶格。     

Indication of hydrogen and oxygen stable isotopes on the characteristics and circulation patterns of medium-low temperature geothermal resources in the Guanzhong Basin,China

Guanzhong Basin is a typical medium-low temperature geothermal field mainly controlled by geo-pressure in the west of China.The characteristics of hydrogen and oxygen isotopes were used to analyze the flow and storage modes of geothermal resources in the basin.In this paper,the basin was divided into six geotectonic units,where a total of 121 samples were collected from geothermal wells and surface water bodies for the analysis of hydrogen-oxygen isotopes.Analytical results show that the isotopic signatures of hydrogen and oxygen throughout Guanzhong Basin reveal a trend of gradual increase from the basin edge areas to the basin center.In terms of recharge systems,the area in the south edge belongs to the geothermal system of Qinling Mountain piedmont,while to the north of Weihe fault is the geothermal system of North mountain piedmont,where the atmospheric temperature is about 0.2℃-1.8℃in the recharge areas.The main factors that affect the geothermal waterδ18O drifting include the depth of geothermal reservoir and temperature of geothermal reservoir,lithological characteristics,water-rock interaction,geothermal reservoir environment and residence time.Theδ18O-δD relation shows that the main source is the meteoric water,together with some sedimentary water,but there are no deep magmatic water and mantle water which recharge the geothermal water in the basin.Through examining the distribution pattern of hydrogen-oxygen isotopic signatures,the groundwater circulation model of this basin can be divided into open circulation type,semi-open type,closed type and sedimentary type.This provides some important information for rational exploitation of the geothermal resources.     

Temporal trends of hydro‐climatic variables and runoff response to climatic variability and vegetation changes in the Yiluo River basin,China

The Yiluo River is the largest tributary for the middle and lower reaches of the Yellow River below Sanmenxia Dam. Changes of the hydrological processes in the Yiluo River basin, influenced by the climatic variability and human activities, can directly affect ecological integrity in the lower reach of the Yellow River. Understanding the impact of the climatic variability and human activities on the hydrological processes in the Yiluo River basin is especially important to maintain the ecosystem integrity and sustain the society development in the lower reach of the Yellow River basin. In this study, the temporal trends of annual precipitation, air temperature, reference evapotranspiration (ET₀) and runoff during 1961–2000 in the Yiluo River basin were explored by the Mann‐Kendall method (M‐K method), Yamamoto method and linear fitted model. The impacts of the climatic variability and vegetation changes on the annual runoff were discussed by the empirical model and simple water balance model and their contribution to change of annual runoff have been estimated. Results indicated that (i) significant upwards trend for air temperature and significant downwards trend both for precipitation and ET₀ were detected by the M‐K method at 95% confidence level. And the consistent trends were obtained by the linear fitted model; (ii) the abrupt change started from 1987 detected by the M‐K method and Yamamoto method, and so the annual runoff during 1961–2000 was divided into two periods: baseline period (1961–1986) and changeable period (1987–2000); and (iii) the vegetation changes were the main cause for change of annual runoff from baseline period to changeable period, and climatic variability contributed a little to the change of annual runoff of the Yiluo River. Copyright © 2009 John Wiley & Sons, Ltd.     

Geochemical characteristics of hadal sediment in the northern Yap Trench

Journal of Oceanology and Limnology - Two sediment cores were retrieved in the hadal zone of the Yap Trench, and their concentrations of six major elements Mg, Al, Ca, Ti, Mn and Fe and nine trace...     

基于MODIS数据的太湖浮游植物物候变化及其对水表温度的响应

浮游植物物候能够反映浮游植物的生长变化与湖泊生态系统的变化,水温、营养盐浓度等因素对物候有重要影响。太湖富营养化程度较高,水温的影响作用日趋显著,物候与水温关系的研究对理解、控制和改善太湖生态系统具有重要意义。本研究利用2003—2018年MODIS遥感数据计算浮游植物物候指标和湖泊水表温度（Temperature of Water Surface,LSWT）,通过分析太湖浮游植物物候时空变化特点探究了不同区域的物候特征,并结合LSWT揭示了浮游植物物候对LSWT变化的响应关系。结果表明：① 不同浮游植物物候指标具有不同空间分布特点,水华发生次数、峰值叶绿素a（Chla）浓度和水华总持续时间呈现由西部沿岸向湖心区递减的趋势;浮游植物生长开始时间和峰值Chla发生时间分布复杂但在沿岸区域相对较早;② 太湖可被划分为4种具有不同物候特征的区域,Ⅰ类区域主要位于贡湖湾、东部沿岸以及太湖中部开阔水域,该区Chla浓度范围为50~60 μg/L,且波动平缓,水华发生次数最少、开始最晚、持续时间最短;Ⅱ类区域主要分布于太湖西部沿岸,Chla浓度范围为50~90 μg/L且变化剧烈,该区水华发生次数最多、开始最早、持续时间最长;Ⅲ和Ⅳ类属于过渡区域,前者主要分布于梅梁湾、竺山湾及入湾口,后者主要位于南部沿岸以及太湖中部;③ 浮游植物物候对LSWT变化的响应受营养水平影响,当营养水平较高时,浮游植物的生长受LSWT的促进作用显著,LSWT年际变化的升高趋势对浮游植生长物候提前、生物量增加的影响明显,反之,则LSWT变化对浮游植物生长的影响减弱。     

天然气水合物开采储层出砂研究进展与思考

天然气水合物开采井眼出砂问题是当前水合物产业化急需突破的瓶颈之一,解决水合物开采时防砂与产能平衡问题是实现水合物安全高效、长期可控开采的关键.我国海域典型水合物储层属于弱固结的低渗泥质粉砂储层,其面临的防砂控泥与增产矛盾较为突出.厘清不同水合物储层和开采条件下的井眼出砂规律并揭示其机理,进而制定科学合理的防砂控泥措施以实现产能最大化是解决上述矛盾的途径所在.从理论分析、数值模拟、室内实验和现场试采4个角度介绍了世界范围内已开展的水合物出砂防砂情况,分析总结了水合物储层出砂影响因素及出砂机理,最后探讨了目前出砂研究存在的问题和挑战,并给出了相应的建议,旨在为后续水合物开采井眼出砂预测和防控研究提供思路和参考.     

居住区典型地物热环境的日变化及其相互影响分析

居住区热环境状况是影响局地微气候变化的重要因素,研究居住区地物的热环境特征,对于了解和改善微气候具有重要意义。为了更好地揭示居住区热环境特征,本研究使用热红外成像仪对北京市某校园居住区进行观测,获取了夏季不同天气状况下（晴天、阴天、多云）的24 h热红外影像数据。依据各天气数据和地物属性,系统分析了各地物日变化规律,并通过垂线法判定邻近地物的温度边界范围,进而揭示出地物间温度交互特征。结果如下：① 太阳辐射是影响地物白天温度变化的主要因素,与地物温度呈正相关性;在多云天气下,地物的最高温度滞后至16:00出现,且地物温度曲线呈现连续的“锯齿状”升降趋势,云层的大量运动是导致多云天气下的地物温度波动变化的关键因素;沥青道路在夜间的温度均高于其他地物,并且夜间持续放热,提生周围环境温度;阴影能够有效减少地物吸收的太阳辐射量,降低地物表面温度;植被的冠层厚度与地物温度呈负相关性,因此增加居住区内绿植的冠层厚度,增大区域阴影面积有助于改善局地微气候;② 树木和裸土在06:00和14:00的温度交互作用强烈,表明在地物交界处,全天持续发生显著的热量交换;而夜间至凌晨,草坪与人行道持续进行热量交换,帮助降低路面温度,缓解周围高温状况。     

智能卡和出租车轨迹数据中蕴含城市人群活动模式的差异性分析

当前采用交通流数据量化城市人群活动模式研究已经取得了丰硕的研究成果,但是对于同一区域、同一时段不同类型交通流数据反映城市人群活动模式的共性与差异性仍然知之甚少,直接影响了城市人群活动模式挖掘结果的可解释性与实际应用效果。为此,本文旨在对目前广泛采用的智能卡数据（公交和地铁刷卡）和出租车轨迹数据2种重要的交通流数据,从时空分布模式的差异性、行程距离及距离衰减效应的差异性、空间社团结构的差异性3个方面,探索二者反映城市人群活动模式的差异性：① 采用北京市六环以内区域2016年5月9日至15日的智能卡和出租车轨迹数据进行实验分析,研究发现：① 2种交通流反映出行需求的空间分布呈现出高度相关性,但是在同一空间单元上,2种交通流反映出行需求的时间相关性较低;② 2种交通流的使用率在不同空间位置存在明显差异,仅在城市中心区域使用率较为均衡;③ 2种交通流反映人群行程距离的空间分布、距离衰减效应存在明显差异,公共交通对于促进长距离出行更为重要;④ 从2种交通流发现的空间社团结构都显示了城市的多中心结构特征,但是二者发现社团结构存在的差异性表明两种交通方式对城市空间交互起着不同的作用。本研究有助于深入理解多源交通流反映城市人群活动的内在机理,提升城市人群活动模式在城市规划、交通管理等领域的应用效果。     

低轨道人造卫星(CHAMP、GRACE、GOCE)与高精度地球重力场——卫星重力大地测量的最新发展及其对地球科学的重大影响

评述了卫星重力大地测量的最新发展及其对地球科学的重大影响。为了更好地理解地球内部物理构造与海洋动力学，以及大陆，冰川和海洋的相互作用，改善现有地球重力场模型（包括精度和空间解析度）是非常重要的。IUGG等国际组织对此已经强调了很多年。最近，由德国的GFZ（GeoForschungsZentrum)，美国的NASA（National Aeronautics and Space Adminitration)以及欧洲宇航局ESA（European Space Agency)开发研制了最先进的地球监测技术－SST（Satellite-to-Sateilite Tracking)。其主要特点是利用现有的GPS连续追踪新发射低轨道卫星，并由低轨道卫星对地球重力场作精密观测。已经发射和即将发射的卫星有3颗：GHAMP（Challenging Mini-Satellite Payload for Geophysical Research an Application)已经于2000年发射；GRACE（Gravity Recovery and Climate Experimert)定于2002年发射；GOCE（Gravity Field and Steady-state Ocean Cirulation Explorer)计划2004年发射，它们可以统称为重力卫星。载有SST技术的人造卫星的主要目的是获得具有前所未有的高精度和高空间解析度的全球重力场和大地水准面模型，加强人们对地球内部构造的理解并为海洋和气象研究提供更好地参考。上述3个重力卫星工作在有明显区别的不同波谱内，它们有不同的科学应用，仅有一小部分重合。所以，就应用而言它们是完全互补的。它们在地球科学中的应用将是广泛的，特别对于固体地球物理学，海洋学以及大地测量学等领域，它们将会带来革命性的变化，其意义不亚于GPS。     

Research progress of TiO2 photocathodic protection to metals in marine environment

Corrosion protection has become an important issue as the amount of infrastructure construction in marine environment increased.Photocathodic protection is a promising method to reduce the corrosion of metals,and titanium dioxide(TiO_2) is the most widely used photoanode.This review summarizes the progress in TiO_2 photo gene rated protection in recent years.Different types of semiconductors,including sulfides,metals,metal oxide s,polymers,and other materials,are used to design and modify TiO_2.The strategy to dramatically improve the efficiency of photoactivity is proposed,and the mechanism is investigated in detail.Characterization methods are also introduced,including morphology testing,light absorption,photoelectrochemistry,and protected metal observation.This review aims to provide a comprehensive overview of Ti02 development and guide photocathodic protection.