钛酸镧烧结物中游离氧化镧的测定

本文研究了La(Ⅲ)与甲基百里酚蓝和溴化十六烷基吡啶在pH7.8—11.0的NH_4OH-NH_4Cl介质中生成紫色络合物的显色反应,λ_(max)=628nm,ε=8.1×10~4,La量在0—90μg/25ml范围内遵循比尔定律,烧结物中一些常见的离子不干扰测定。本法用于烧结物中游离氧化镧的测定,结果满意。     

新疆库松木切克山喇嘛萨依式铜矿的勘查标志

本文通过对库松木切克山喇嘛萨依铜矿地质特征及控矿因素的研究,总结出该类矿床的若干勘查标志,其中地层层位、含矿岩相、地球化学异常、容矿岩石、围岩蚀变、活化脉体及同生断裂等最为明显。在区域内如能确定出这些标志,尤其是标志组合的存在,则将可能取得该类矿床找矿的新突破。     

新疆小热泉子铜矿区构造特征及成矿模式

新疆小热泉子铜矿区总体为一NW-SE走向的不协调短轴复背斜,后期有SN向次级褶皱叠加。区内NW向断裂发育,均为EW向大断裂之分支断裂,规模小,无推覆性质,主要矿床(Ⅰ号矿床)呈较为典型的立交桥式双层成矿模式。矿床成因类型为中温热液充填-交代型铜(锌)矿床。      

Geochronology and petrogenesis of the post-orogenic Cu–Ni sulfide-bearing mafic–ultramafic complexes in Jilin Province, NE China

Northeastern (NE) China is a well-documented example of a collisional zone characterized by widespread post-orogenic granites and mafic–ultramafic complexes. Based on a study of the Hongqiling and Piaohechuan Cu–Ni sulfide-bearing mafic–ultramafic complexes in central Jilin province, we present geological, petrological, geochemical and geochronological data which indicates their post-orogenic origin.The Hongqiling complex comprises pyroxenite, olivine websterite, lherzolite, gabbro and leucogabbro. Zircon U–Pb SHRIMP analyses on a leucogabbro of the Hongqiling complex yield a weighted mean ²⁰⁶Pb–²³⁸U age of 216±5 Ma. The Piaohechuan complex is composed of gabbro, pyroxenite and dolerite, exposed as dikes. A plagioclase-bearing pyroxenite has a U–Pb zircon weighted mean ²⁰⁶Pb–²³⁸U age of 217±3 Ma, identical to that of the Hongqiling complex. These ages are coeval with the emplacement of A-type granites in the area, but slightly younger than the regional metamorphism (240 Ma) and syn-orogenic granitic magmatism (246±4 Ma). This suggests that these mafic–ultramafic complexes are post-orogenic in origin. The age data also indicated a short period of lithospheric stabilization of about 30 Ma after cessation of orogenic activity.Geochemical investigation indicates that the primary mafic magma was a lithospheric mantle-derived basalt resulting from the upwelling of asthenosphere due to lithospheric delamination during post-orogenic processes. The magmatic source was contaminated by a small amount of crustal material, and subsequent crystal fractionation resulted in the Cu–Ni mineralization.The widespread occurrence of mafic–ultramafic complexes in the Xing'an–Mongolian Orogenic Belt of NE China and in the Altay–Tianshan–Junggar Orogenic Belt of Northern Xinjiang indicates that mafic intrusions are an important magmatic suite that evolved during post-orogenic processes. Portions of this mafic magma could have underplated the lower crust, and served as the heat source for associated late-stage granitic magmas.     

松辽盆地中央坳陷南部下白垩统泉头组四段沉积相

松辽盆地中央坳陷南部下白垩统泉头组四段沉积时期,松辽盆地地形平缓,基底沉降缓慢,在湖平面整体扩张及浅水背景下河流入湖成三角洲沉积。通过岩心观察、相标志与测井相研究,该区储层主要为岩屑长石砂岩和长石岩屑砂岩,识别出三角洲平原、三角洲前缘、前角洲3种亚相,以及分支河道、天然堤、决口扇、分支河道间湾、水下分支河道、水下决口扇、河口坝、远沙坝、水下分支河道间湾9种微相三角洲平原、三角洲前缘广泛发育,前三角洲不发育。三角洲平原分支河道通过填积和频繁的分叉改道,向湖盆中心方向长距离推进,在三角前缘的浅水区域发育了大量水下分支河道,分支河道与水下分支河道砂体相互切割、叠加,形成了平均宽度200~600 m、平均厚度3~8 m的道单砂体,（水下）分支河道砂体构成了油气富集的主要储集体。该区沉积相的精细研究,为进一步调整开发井网奠定了基础。     

Particle manifold method (PMM): A new continuum‐discontinuum numerical model for geomechanics

Particle manifold method (PMM) is a new extension of the numerical manifold method (NMM). PMM uses a mathematical cover system to describe the motion and deformation of a particle‐based physical domain. By introducing the concept of particle into NMM, PMM takes the advantages of easy topological and contact operations with particles. In this article, the methodology, formulations and implementation of the method are presented, together with modelling examples for validation. It is found that good solutions for both continuous and discontinuous problems are obtained by the new developed PMM. Due to the underlying coupled continuum‐discontinuum property of PMM, it has great potential for modelling of geomechanical problems. Copyright © 2012 John Wiley & Sons, Ltd.     

松辽盆地三肇凹陷葡萄花油层成藏模式初探

运用源控含油气系统理论与综合分析技术,按成藏“层次分析”方法,通过对生、储、盖、圈(闭)静态要素及其内生、排、运、聚、散(失)动态过程的综合研究,对松辽盆地中央坳陷的三肇凹陷葡萄花油层成藏条件进行探讨,提出了以次级凹陷为中心、不同类型的油气聚集带紧邻并围绕次级凹陷最低部位呈环带状分布的大型凹陷内成藏模式,并进一步提出永乐次级凹陷中心及其三级聚油环带及徐家围子次级凹陷以西为"网式"运聚特征;在凹陷级成藏模式的指导下,通过对大面积密井网开发区综合解剖,提出三级构造带中单个的局部构造圈闭(群)、单个的(局部构造——)岩性圈闭(群)控油和成藏规律,为认识本区基本控油单元、油水分布规律、油气勘探及扩大新探区提供重要的理论依据。     

甘肃北山老金厂金矿床载金矿物特征、原位硫同位素组成及其对成矿的指示意义

老金厂金矿床是北山成矿南带最具代表性的中低温岩浆热液型金矿床之一,其规模为中型。依据脉体穿插、矿物共生组合和矿石结构构造等特征,将矿床矿化作用过程划分为石英-黄铁矿阶段（Ⅰ）、石英-含砷黄铁矿-毒砂阶段（Ⅱ）、石英-黄铁矿-多金属硫化物阶段（Ⅲ）和石英-方解石阶段（Ⅳ）。利用电子探针研究了不同成矿阶段载金矿物的元素组成及其分布规律。Ⅰ阶段：黄铁矿以粗粒自形立方体为主,粒度为0.50~1.50 mm,贫As、Au;毒砂含量极少,呈细粒他形。Ⅱ阶段：含砷黄铁矿周围常有大量毒砂产出,含砷黄铁矿多为立方体、五角十二面体,粒度为0.30~1.00 mm,富As、Au;该阶段矿化最为强烈,毒砂主要形成于此时期,多呈棱柱状、柱状、放射状集合体,显示富S亏As特征。Ⅲ阶段：多以黄铁矿-黄铜矿-闪锌矿共生组合脉的形式产出,黄铁矿多呈长条状,以富S、Cu、Zn、Au和贫Fe、As为特征。Ⅳ阶段：矿化作用极弱,毒砂、黄铁矿含量极少,为细粒他形。原位硫同位素组成显示：Ⅰ阶段黄铁矿δ³⁴S_V-CDT值为-3.8‰~-2.9‰,均值为-3.3‰;Ⅱ阶段黄铁矿和毒砂δ³⁴S_V-CDT值为-4.7‰~2.6‰,均值为-3.3‰;Ⅲ阶段黄铁矿和闪锌矿δ³⁴S_V-CDT值主要分布于-1.9‰~1.0‰之间,均值为0.1‰。此3个阶段硫同位素组成反映了成矿期硫主要来源于幔源岩浆,混入了部分地层硫。综合前人研究成果,认为成矿早期至晚期,成矿流体总体上由富S贫As向富As贫S演化。Ⅰ阶段体系处于中性稳定的环境,硫源充足;Ⅱ阶段为贫S富As的高氧逸度环境,由于大气降水对地层的淋滤渗透,混入富As流体,Au可能与As结合形成Au-As络合物,在成矿有利部位富集沉淀;Ⅲ阶段成矿元素种类丰富,体系为富S贫As的弱还原环境,Au很可能与HS^-、S^-形成络合物进入黄铁矿晶格。     

滇西北金沙江带蛇绿岩,蛇绿混杂岩形成环境及时代

本文对滇西北金沙江带蛇绿岩及其混杂岩的产状、规模，岩石学及岩石化学特征等进行系统的综合研究，并根据大量的化石资料，将该区蛇绿岩的形成时代厘定为晚石炭世至二叠纪，蛇绿要岩的形成时代厘定为早、中三叠世，论证了本区蛇绿岩产于规模较小的洋盆环境之中，由于金沙江洋盆发育阶段较短暂，不具有隔离冈瓦纳及扬子两大古生物地理区系的作用，因此，金沙江缝合带不能构成古特提斯域的主缝合带。     

A simple hypoplastic model for normally consolidated clay

The paper presents a simple constitutive model for normally consolidated clay. A mathematical formulation, using a single tensor-valued function to define the incrementally nonlinear stress–strain relation, is proposed based on the basic concept of hypoplasticity. The structure of the tensor-valued function is determined in the light of the response envelope. Particular attention is paid towards incorporating the critical state and to the capability for capturing undrained behaviour of clayey soils. With five material parameters that can be determined easily from isotropic consolidation and triaxial compression tests, the model is shown to provide good predictions for the response of normally consolidated clay along various stress paths, including drained true triaxial tests and undrained shear tests.