The optical features and hydrocarbon-generating model of “barkinite” from Late Permian coals in South China

Leping coal is known for its high content of “barkinite”, which is a unique liptinite maceral apparently found only in the Late Permian coals of South China. “Barkinite” has previously identified as suberinite, but on the basis of further investigations, most coal petrologists conclude that “barkinite” is not suberinite, but a distinct maceral. The term “barkinite” was introduced by (State Bureau of Technical Supervision of the People's Republic of China, 1991, GB 12937-91 (in Chinese)), but it has not been recognized by ICCP and has not been accepted internationally.In this paper, elemental analyses (EA), pyrolysis-gas chromatography, Rock-Eval pyrolysis and optical techniques were used to study the optical features and the hydrocarbon-generating model of “barkinite”. The results show that “barkinite” with imbricate structure usually occurs in single or multiple layers or in a circular form, and no definite border exists between the cell walls and fillings, but there exist clear aperture among the cells.“Barkinite” is characterized by fluorescing in relatively high rank coals. At low maturity of 0.60–0.80%R_o, “barkinite” shows strong bright orange–yellow fluorescence, and the fluorescent colors of different cells are inhomogeneous in one sample. As vitrinite reflectance increases up to 0.90%R_o, “barkinite” also displays strong yellow or yellow–brown fluorescence; and most of “barkinite” lose fluorescence at the maturity of 1.20–1.30%R_o. However, most of suberinite types lose fluorescence at a vitrinite reflectance of 0.50% Ro, or at the stage of high volatile C bituminous coal. In particular, the cell walls of “barkinite” usually show red color, whereas the cell fillings show yellow color under transmitted light. This character is contrary to suberinite.“Barkinite” is also characterized by late generation of large amounts of liquid oil, which is different from the early generation of large amounts of liquid hydrocarbon. In addition, “barkinite” with high hydrocarbon generation potential, high elemental hydrogen, and low carbon content. The pyrolysis products of “barkinite” are dominated by aliphatic compounds, followed by low molecular-weight aromatic compounds (benzene, toluene, xylene and naphthalene), and a few isoprenoids. The pyrolysis hydrocarbons of “barkinite” are mostly composed of light oil (C₆–C₁₄) and wet gas (C₂–C₅), and that heavy oil (C₁₅⁺) and methane (C₁) are the minor hydrocarbon.In addition, suberinite is defined only as suberinized cell walls—it does not include the cell fillings, and the cell lumens were empty or filled by corpocollinites, which do not show any fluorescence. Whereas, “barkinite” not only includes the cell walls, but also includes the cell fillings, and the cell fillings show bright yellow fluorescence.Since the optical features and the hydrocarbon-generating model of “barkinite” are quite different from suberinite. We suggest that “barkinite” is a new type of maceral.     

Continental crust and lithospheric mantle interaction beneath North China: isotopic evidence from granulite xenoliths in Hannuoba, Sino-Korean craton

Mafic granulite and pyroxenite xenoliths from Cenozoic alkaline basalts at Hannuoba, Hebei Province, North China have been selected for a systematic geochemical and Sr–Nd–Pb isotopic study, which provides a unique opportunity to explore nature of the lower crust and the interaction between the continental crust and lithospheric mantle beneath an Archean craton. The major, compatible and incompatible elements and radiogenic isotopes of these xenoliths suggest great chemical heterogeneity of the lower crust beneath the Hannuoba region. Petrological and geochemical evidences indicate a clear cumulate origin, and most likely, they are related to basaltic underplating in different geological episodes. However, the Sr–Nd–Pb isotopic compositions of the xenoliths reveal a profound enriched source signature (EM I) with some influence of EM II, which implies that some portion of pre-existing, old metasomatized subcontinental lithospheric mantle could have played an important role in their genesis. It is suggested that the interaction between continental crust and subcontinental mantle as manifested by basaltic underplating would be closely related to regional tectonic episodes and geodynamic processes in the deep part of subcontinental lithospheric mantle.     

Integrated Two-Dimensional Modeling of Fluid Flow and Compaction in a Sedimentary Basin

In this paper we employ mixed finite elements and numerically study an integrated two-dimensional model of fluid flow and compaction in a sedimentary basin. This model describes a single phase incompressible flow in a two-dimensional section of a sedimentary basin with vertical compaction. At each time step, an iterative algorithm is used to solve this model. The determination of the grid movement is based on the mass conservation and movement of sediments in the basin, while the mixed method is utilized to solve the fluid flow over the moving grid. Numerical experiments are presented to verify this iterative algorithm and show representative solutions for the model under consideration.     

Analysis and comparison of the tidal gravity observations obtained with LCR-ET20 spring gravimeter

Introduction The tidal variation signals of the solid Earth recorded with the modern measuring techniques can be used to provide effectively the means to cognize the Earths motion, deformation and structure character, especially to monitor the material motion in the Earths interior. In the recent 20 years, the distribution character of the global gravity field has made great progress since the continuous and deep theoretical studies in geophysics and geodesy domains. The successful manufactur…     

Expansion and contraction of Chinese deserts during the Quaternary

Episodic dune formations during the Quaternary are found in many deserts of China. The causes of desert expansions on different time scales are not the same. Desert extension at about 1.1 and 0.9 Ma ago were the response to the active tectonic movements, whereas the desert evolutions on the ten-thousand years time scale were the response to the orbital scale climatic changes. Spatial scale studies on desert evolution indicate that desert margins shifted greatly during the last glacial maximum (LGM) and the Holocene optimum, its changing from 125°E of the LGM to 105°E of the climatic optimum. Historical desertification in the semiarid China is not a response to climate drought but largely associated with the human impacts (mainly over-cultivation) since about 2300 years ago, which leads to the reworking of the underlying LGM sands.     

喉癌CT分型和CD44V6表达的意义

目的 探讨喉癌的CT分型和转移相关因子CD44V6表达的意义。方法 对39例喉鳞癌行术前常规CT检查，其术后标本进行CD44V6的表达检测，与术前CT片作对照分析。结果39例喉鳞癌CT检查；声门型24例，声门上型14例，跨声门型1例，声门下型0例；T1－2级22例，T3－4级17例；淋巴结转移组13例，非转移组26例，CD44V6总的阳性表达率为61．5％，对各组均采用秩次检验分析，CD44V6在喉癌的CT的T分级和淋巴结分组中存在显著性差异（P＜0．01）。而部位分区无明显差异。结论 喉癌的CT分型中的T分级、淋巴结分组与CD44V6的阳性表达密切相关。     

科技形变资料的管理模式

科学的进步使地形变监测事业得到长足发展，市场经济的繁荣催生出形变监测行业独有的管理之道。形变监测行业是个介于科研、IT及服务行业三者之间的特殊行业，因此，它的发展必须具有一定的科学性、前瞻性和服务性。     

Study of the Earth’s free core nutation by tidal gravity data recorded with international superconducting gravimeters

By stacking high-precision tidal gravity observations obtained with superconducting gravimeters at six stations in China, Japan, Belgium, France, Germany and Finland, the local systematical discrepancies in the parameter fitting, caused by atmospheric, oceanic tidal loading and the other local environmental perturbations, are eliminated effectively. As a result, the resonance parameters of the Earth’s free core nutation are accurately determined. In this study, the eigenperiod of free core nutation is given as 429.0 sidereal days, which is in agreement with those published in the previous studies. It is about 30 sidereal days less than those calculated in theoretical models (about 460 sidereal days), which confirms the real ellipticity of the fluid core of the Earth to be about 5% larger than the one expected in assumption of hydrostatic equilibrium. The quality factor (Q value) of free core nutation is given as about 9543, which, compared with those determined before based on the body tide observations, is much larger, but more close to those obtained using the VLBI observations. The complex resonance strength is also determined as (−6.10×10⁻⁴, −0.01 ×10⁻⁴)°/h, which can principally describe the deformation characteristics of an anelastic mantle.     

青藏高原大气—植被相互作用的模拟试验——Ⅰ.物理通量和参数

在原大气-植被相互作用模式AVIM的基础上作了改进，包括对值被生理过程，如（1）光合作用：（2）呼吸；（3）分配和（4）物候等新的描述方法。对青藏高原上30个站点进行模拟计算，给出了高压上地表辐射及水热物理通量以及地表拖曳系数和地面反照率的分布特征。模拟结果表明净辐射和感热通量由东南和西北增加，高原西北部地表反照率较高，东南部地表反照率较低。     

青藏高原大气—植被相互作用的模拟试验Ⅱ.植被叶面积指数和净初级生产力

利用大气－植被相互作用模式AVIM对青藏高原上30个站点进行模拟计算，给出了青藏高原上植被叶面积指数和净初级生产力的分布特征。模拟结果表明，高原上叶面积指数、净初级生产力由东南向西北减少，模拟和观测的分布相一致。分析指出，青藏高原净初级生产力的分布决定于水热条件的共同作用，降水充沛、温度适宜的青藏高原东南部净初级生产力较高，而青藏高原西北部由于降水过少或温度过低，初级生产力很低。