Geochemical features and origin of natural gas in heavy oil area of the Western Slope,Songliao Basin,China

The Western Slope of the Songliao Basin is rich in heavy oil resources (>70 × 10⁸ bbl), around which there are shallow gas reservoirs (∼1.0 × 10¹² m³). The gas is dominated by methane with a dryness over 0.99, and the non-hydrocarbon component being overwelmingly nitrogen. Carbon isotope composition of methane and its homologs is depleted in ¹³C, with δ¹³C₁ values being in the range of −55‰ to −75‰, δ¹³C₂ being in the range of −40‰ to −53‰ and δ¹³C₃ being in the range of −30‰ to −42‰, respectively. These values differ significantly from those solution gases source in the Daqing oilfield. This study concludes that heavy oils along the Western Slope were derived from mature source rocks in the Qijia-Gulong Depression, that were biodegraded. The low reservoir temperature (30–50 °C) and low salinity of formation water with neutral to alkaline pH (NaHCO₃) appeared ideal for microbial activity and thus biodegradation. Natural gas along the Western Slope appears mainly to have originated from biodegradation and the formation of heavy oil. This origin is suggested by the heavy δ¹³C of CO₂ (−18.78‰ to 0.95‰) which suggests that the methane was produced via fermentation as the terminal decomposition stage of the oil.     

静压桩承载力时间效应的研究进展

由于静压桩沉桩后桩周土重塑,静压桩承载力表现出随着休止期的延长而增长的特性。本文从静压桩沉桩后桩周土体内孔隙水消散固结的角度出发,对静压桩承载力时间效应的理论和试验分别进行归纳,结合孔隙水消散路径及固结模型,对桩周土体初始超静孔隙水压力大小及其分布特征进行总结,分析承载力各种测试方法的优缺点,对静压桩承载力的时效性进行深化研究,并探讨了不同地质条件、不同桩的类型对休止期内静压桩承载力的影响,进一步对基于实测数据得出的经验公式进行总结。讨论了基于不同本构关系模型的应力场及位移场解答和沉桩后孔隙水压力消散解答,在此基础上总结了桩基极限承载力理论公式;探讨了黏性土、砂土条件下,考虑超固结比、不排水抗剪强度和塑性指数比对桩基极限承载力系数A的影响,在此基础上归纳了桩基极限承载力经验公式。建议在经验公式基础上设置多重参数,以提升经验公式的精确度,并完善对不同桩、土类型的参数解答;利用BP神经网络,导入静压桩承载力相关参数,以得到针对不同地质条件、桩型、休止期的承载力最优解。     

Public cognition and response to earthquake disaster: from the 2008 Mw7.9 Wenchuan to the 2013 Mw6.6 Lushan earthquakes in Sichuan Province,China

Natural Hazards - China is one of the countries most affected by earthquakes. Improving public cognition and response to earthquake disaster (EDCR) is an effective means to reduce seismic risk and...     

Experimental Study on Mechanical Properties Degradation and Acoustic Emission Characteristics of Coal Rock Caused by CO2 Injection

Geotechnical and Geological Engineering - Geological sequestration of greenhouse gases has gained extensive attentions in recent years, but the degradation law of mechanical parameters and the...     

Numerical Analysis of Soft Surrounding Rock Deformation in Freezing Shaft Sinking based on Temperature Partition

Geotechnical and Geological Engineering - To master the deformation law of soft surrounding rock of well wall during freezing shaft sinking in water-rich area, the distribution of freezing...     

MC-ICP-MS高精度测定Li同位素分析方法

以不同浓度Li元素标准样品和K、Ca、Na、Mg、Fe单元素标准样品的混合溶液为研究对象,采用3根阳离子交换树脂（AG 50W X8,200~400目）填充的聚丙烯交换柱和石英交换柱对Li进行分离富集,淋洗液分别为28 mol/L HCl、015 mol/L HCl以及05 mol/L HCl 30%乙醇,淋洗液体积小,仅为38 mL。分离回收率高,均大于976%。国际标样AGV 2（相对于IRMM 016）、BHVO 2（相对于IRMM 016）和IRMM 016（相对于L SVEC）的δ7Li值分别为(513±094)‰(2σ,n=10)、(408±060)‰(2σ,n=4)和(0038±073)‰(2σ,n=10),与前人分析结果吻合,分析精度与国际同类实验室水平相当。并对比了马里兰大学同位素实验室和笔者实验室对同种岩石矿物样品的分析结果,在误差范围内具有很好的一致性。此外,对美国地质调查局提供的准标样NKT 1霞石岩（相对于IRMM 016）给出了定值,δ7Li值为(871±046)‰(2σ,n=4)。因此,本方法可用于测定天然样品的Li同位素组成。     

Evaluation of petroleum hydrocarbon biodegradation in shallow groundwater by hydrogeochemical indicators and C, S-isotopes

Biodegradation is one of the main natural attenuation processes in groundwater contaminated with petroleum hydrocarbons. In this work, preliminary studies have been carried out by analyzing the concentrations of total petroleum hydrocarbons (TPH), dissolved inorganic carbon (DIC), dominant terminal electron accepters or donors, as well as δ ¹³C_DIC and δ ³⁴S_SO4, to reveal the biodegradation mechanism of petroleum hydrocarbons in a contaminated site. The results show that along groundwater flow in the central line of the plume, the concentrations of electron acceptors, pH, and E _h increased but TPH and DIC decreased. The δ ¹³C_DIC values of the contaminated groundwater were in the range of ?14.02 to ?22.28 ‰_PDB and ?7.71 to 8.36 ‰_PDB, which reflected a significant depletion and enrichment of ¹³C, respectively. The increase of DIC is believed to result from the non-methanogenic and methanogenic biodegradation of petroleum hydrocarbon in groundwater. Meanwhile, from the contaminated source to the downgradient of the plume, the ³⁴S in the contaminated groundwater became more depleted. The Rayleigh model calculation confirmed the occurrence of bacterial sulfate reduction as a biodegradation pathway of the petroleum hydrocarbon in the contaminated aquifers. It was concluded that stable isotope measurements, combined with other biogeochemical measurements, can be a useful tool to prove the occurrence of the biodegradation process and to identify the dominant terminal electron-accepting process in contaminated aquifers.     

Holocene palaeoflood events recorded by slackwater deposits along the lower Jinghe River valley,middle Yellow River basin,China

Palaeoflood slackwater deposits (SWDs), are the natural record of overbank flooding and are often found within aeolian loess‐soil profiles along the river valleys of the middle Yellow River basin. These pedo‐stratigraphic sequences are studied using a multi‐disciplinarily approach to reconstruct Holocene hydro‐climatic variations. Our field investigations along the lower Jinghe River valley have identified palaeoflood SWDs at several sites along the riverbanks based on sedimentological criteria. Analytical results, including magnetic susceptibility, particle‐size distribution and concentrations of chemical elements, indicate that these well‐sorted palaeoflood SWD beds were deposited from the suspended sediment load in floodwaters. We identify two episodes of extraordinary palaeoflood events along the Jinghe River valley. These hydro‐climatic events were dated to 4200–4000 and 3200–2800 a BP, by using the optically stimulated luminescence method in combination with archaeological dating of retrieved anthropogenic remains, and with pedo‐stratigraphic correlations with the previously studied Holocene pedo‐stratigraphy in the Jinghe River drainage basin. The flooding events are therefore considered to be a regional expression of known climatic events in the northern hemisphere and demonstrate Holocene climate was far from stable. This study provides important data in understanding the interactions between regional hydro‐climatic systems and global change in semi‐arid and sub‐humid regions. Copyright © 2012 John Wiley & Sons, Ltd.