高温高压下水流体pH值测量

高温高压下水流体的pH值是影响矿物-水流体相互作用平衡和动力学过程的一个重要参数。确定高温高压流体pH的方法主要包括电位势测量、化学分析与热力学计算及电导率方法。电位势测量在化学领域应用广泛,也被用来测量了洋中脊的热液流体的pH值。人们尝试了各种形式的电极,如氢电极、钯氢化物电极、金属-金属氧化物电极和钇稳定的氧化锆(YSZ)电极。玻璃电极只取得了有限的成果,通常用来测量常温及低温下的流体的pH值。对金属-金属氧化物电极在较宽的温度范围内进行了研究,但它需要利用合适的参比溶液来校正,与玻璃电极一样都表现出较大的偏移和误差以及不可回测性。陶瓷薄膜电极,如钇稳定的氧化锆(YSZ)电极,为测量相对较高温度下的pH值提供了一个可靠的方法。利用高温淬火水的化学分析和常温下的pH的测量,通过求解络合反应质量平衡与所有组分质量平衡的联立方程,来计算指定温度压力下pH值和水溶液种类的分布,是获得高温pH值的另一个重要而常用的方法,但热力学数据中的数值误差和不确定性以及分析误差能够影响计算出的高温溶液的pH值的精度。对高温高压超临界水流体的电导测量已经取得很大的成就,它被用来作为确定溶液内部离子反应平衡常数的一种最常用的方法,通过获得的这些反应的平衡常数,就可以得到在高温高压下流体的就位物质组成,这个方法可以测量更高温度压力下流体的pH值。     

不对称抽道集共反射面元叠加方法探讨

总结不对称抽道集共反射面元叠加方法的工作经验，提出自由观测面自由反射界面不对称抽道集共反射面元叠加方法的处理思路和计算方法。在自由观测面的条件下，反射界面可分为简单倾斜平面、规则曲面和自由反射界面三种情况，针对不同情况讨论共反射面元的叠加方法。综合一般情况下的共反射面元叠加方法，提出了“鳞片法”的处理思路。     

Holocene environmental change inferred from the loess–palaeosol sequences adjacent to the floodplain of the Yellow River, China

Chinese loess deposits are generally considered to be the product of dust storms and dust falls from the central Asia arid zones that were transported across China by the northwesterly continental monsoon. In contrast, the Zhengzhou Loess found southeast of the Loess Plateau, adjacent to the floodplain of the Yellow River, records a different eolian regime and dust source. The Zhengzhou Loess was investigated by field observations, measurements of magnetic susceptibility, particle-size distribution, loss-on-ignition, CaCO₃ and chemical contents. Both field observations and the laboratory results indicate that, during the last glacial, the Zhengzhou Loess was supplied by two different eolian regimes and dust sources, one was from the fresh flood deposits of the Yellow River driven by the northeast winds from the low-lying floodplain, and the other was from the dust storms and dust falls that traveled across the Loess Plateau driven by the northwesterly continental monsoon from the central Asian arid lands. The early Holocene, 11,500–8500 a BP, was a transition during the change in eolian regime and dust source because of the weakened northwesterly monsoon along with the global climatic amelioration. Following the retreat of the northwesterly monsoon from the onset of the mid-Holocene Climatic Optimum at 8500 a BP, dust supply from the drifting sand zone on the Yellow River floodplain became dominant because of the intensified strength of the northeast winds from the Bohai Sea. From 3100 a BP onwards, climatic aridity and extensive human disturbance have resulted in intensive eolian processes causing the incursion of the drifting sand into the Zhengzhou Loess zone. These results show that loess accumulation is more complex than traditionally assumed. The origin of loess deposits elsewhere outside the Loess Plateau may be related to dust sources derived from alluvial sediments of major river systems.     

柴达木盆地西部第三系咸水湖相原油地球化学特征

在系统分析柴达木盆地西部各油田40余个原油样品碳同位素和饱和烃、芳烃组成的基础上,全面剖析了该地区第三系湖相原油的地球化学特征.研究结果表明,这些原油具有特殊的碳同位素组成和异常的生物标志物分布.其全油碳同位素偏重(-26‰～-24‰);正构烷烃系列单体烃碳同位素分布曲线呈水平状,表现出类同于海相有机质的碳同位素组成特征.它们的生物标志物中正烷烃系列兼具奇碳和偶碳优势双重碳数分布模式;呈强植烷优势,Pr/Ph值大多<0.6;伽玛蜡烷普遍异常丰富,C35藿烷含量高,表征高盐、厌氧的咸水湖相沉积环境性质.芳烃组份以萘、菲系列为主,而二苯并噻吩等含硫有机化合物相对含量较低,反映该地区咸水湖相原油源岩沉积相的特殊性.柴西各油田原油地球化学参数在区域上呈规律性变化趋势,与其源岩沉积相的时空变迁相一致.     

Tracing the 850-Ma continental flood basalts from a piece of subducted continental crust in the North Qaidam UHPM belt,NW China

A Paleozoic ultrahigh-pressure metamorphic (UHPM) belt extends along the northern margin of the Qaidam Basin, North Tibetan Plateau. Eclogites in the Yuka eclogite terrane, northwest part of this UHPM belt, occur as blocks or layers of varying size intercalated with granitic and pelitic gneisses. These eclogites have protoliths geochemically similar to enriched-type mid-ocean ridge basalts (E-MORB) and oceanic island basalts (OIB). On the basis of Ti/Y ratios, they can be divided into low-Ti and high-Ti groups. The low-Ti group (LTG) eclogites exhibit relatively low TiO₂ (most <2.5 wt%) and Ti/Y (<500) but comparatively high Mg# (48–55), whereas the high-Ti group (HTG) eclogites have high TiO₂ (most >2.5 wt%) and Ti/Y (>500) but lower Mg# (46–52). Zircons from two eclogite samples gave a magmatic crystallization (protolith) age of ∼850 Ma and a UHPM age of ∼433 Ma. The occurrence, geochemical features and age data of the Yuka eclogites suggest that their protoliths are segments of continental flood basalts (CFBs) with a mantle plume origin, similar to most typical CFBs. Our observation, together with the tectonic history and regional geologic context, lend support for the large scale onset of mantle plume within the Rodinia supercontinent at ∼850 Ma. The Qaidam block is probably one of the fragments of the Rodinia supercontinent with a volcanic-rifted passive margin. The latter may have been dragged to mantle depths by its subducting leading edge of the oceanic lithosphere in the Early Paleozoic.     

内蒙古高原岩石圈构造研究

本文通过综合地球物理资料,对上、中、下地壳和岩石圈地幔属性的研究,来分析内蒙古高原岩石圈的三维构造和物质运动。地体拼合属于岩石圈挤压力较小而作用期较长的造陆作用,以内蒙古中部地区为典型代表。此区域现今包括南阿穆尔- 兴安地体西南部和锡林浩特两个元古宙地体,以及形成于太古宙的华北克拉通地体。索伦山- 西拉木伦河断裂是锡林浩特和华北克拉通地体的缝合带。发生在二叠纪的锡林浩特和华北克拉通两个地体的碰撞拼合,造成古亚洲洋南支的封闭,同时也在两个地体之间,形成了索伦山- 西拉木伦缝合带和华北克拉通北缘俯冲带。古亚洲洋封闭后,华北克拉通地体继续向锡林浩特地体下方陆- 岛俯冲,形成了宽度为60～120 km的华北克拉通北缘俯冲带。此俯冲带地层向北倾斜,上地壳变形严重,岩石圈地幔破裂充水。锡林浩特地体在石炭纪处于南阿穆尔- 兴安地体南方古亚洲洋北支俯冲的岛弧带位置,在二叠纪和华北拼合时又处于华南克拉通北方古亚洲洋南支俯冲的岛弧带位置,幔源岩浆侵入频繁。在中生代拼合后又处于地壳转变为拉张的阶段,幔源岩浆侵入作用有增无减。由于幔源岩浆侵入作用时间长久,岩浆化学分异会更加彻底,锡林浩特地体及其周边地区具有良好的成矿潜力。     

多频测深初探

在频率域测深的基础上,提出了多频测深方法,实现一机多频同时观测的目的,以提高观测速度。本文讨论了多频观测方法的理论依据及工作特点,并提示实现这种观测的方案。     

40Ar/39Ar dating constraints on the high-angle normal faulting along the southern segment of the Tan-Lu fault system: An implication for the onset of eastern China rift-systems

High-angle normal faulting in eastern China was an important tectonic process responsible for the rifting of the eastern Asian continental margin. Along the southern segment of the Tan-Lu fault system, part of the eastern China rift-system, 55–70° east-dipping normal faults are the oldest structures within this rift-system. Chlorite, pseudotachylite, and fault breccia are found in fault zones, which are characterized by microstructures and syn-deformation chlorite minerals aligned parallel to a down-dip stretching lineation. ⁴⁰Ar/³⁹Ar dating of syn-deformation chlorite and K-feldspar from the fault gouge zone yields cooling ages of ～75–70 Ma, interpreted as the timing of slip along the normal faults. This age is older than that of opening of the Japanese sea and back-arc extension in the west Pacific, but similar to the onset of the Indo-Asian (soft?) collision.