Evaluating indicators of marsh vulnerability to sea level rise along a historical marsh loss gradient

Sea level rise (SLR) is threatening coastal marshes, leading to large-scale marsh loss in several micro-tidal systems. Early recognition of marsh vulnerability to SLR is critical in these systems to aid managers to take appropriate restoration or mitigation measures. However, it is not clear if current marsh vulnerability indicators correctly assess long-term stability of the marsh system. In this study, two indicators of marsh stress were studied: (i) the skewness of the marsh elevation distribution, and (ii) the abundance of codominant species in mixtures. We combined high-precision elevation measurements (GPS), LiDAR imagery, vegetation surveys and water level measurements to study these indicators in an organogenic micro-tidal system (Blackwater River, Maryland, USA), where large-scale historical conversion from marshes to shallow ponds resulted in a gradient of increasing marsh loss. The two indicators reveal increasingly stressed marshes along the marsh loss gradient, but suggest that the field site with the most marsh loss seems to experience less stress. For the latter site, previous research indicates that wind waves generated on interior marsh ponds contribute to lateral erosion of surrounding marsh edges and hence marsh loss. The eroded marsh sediment might temporarily provide the remaining marshes with the necessary sediment to keep up with relative SLR. However, this is only a short-term alleviation, as lateral marsh edge erosion and sediment export lead to severe marsh loss in the long term. Our findings indicate that marsh elevation skewness and the abundance of codominant species in mixtures can be used to supplement existing marsh stress indicators, but that additional indices such as fetch length and the sediment budget should be included to account for lateral marsh erosion and sediment export and to correctly assess long-term stability of micro-tidal marshes. © 2020 John Wiley & Sons, Ltd.     

Assessment of Nanosecond Laser Ablation Multi‐Collector Inductively Coupled Plasma‐Mass Spectrometry for Pb and Sr Isotopic Determination in Archaeological Glass: Mass Bias Correction Strategies and Results for Corning Glass Reference Materials

This work presents an evaluation of various methods for in situ high‐precision Sr and Pb isotopic determination in archaeological glass (containing 100–500 μg g^?1 target element) by nanosecond laser ablation multi‐collector‐inductively coupled plasma‐mass spectrometry (ns‐LA‐MC‐ICP‐MS). A set of four soda‐lime silicate glasses, Corning A–D, mimicking the composition of archaeological glass and produced by the Corning Museum of Glass (Corning, New York, USA), were investigated as candidates for matrix‐matched reference materials for use in the analysis of archaeological glass. Common geological reference materials with known isotopic compositions (USGS basalt glasses BHVO‐2G, GSE‐1G and NKT‐1G, soda‐lime silicate glass NIST SRM 610 and several archaeological glass samples with known Sr isotopic composition) were used to evaluate the ns‐LA‐MC‐ICP‐MS analytical procedures. When available, ns‐LA‐MC‐ICP‐MS results for the Corning glasses are reported. These were found to be in good agreement with results obtained via pneumatic nebulisation (pn) MC‐ICP‐MS after digestion of the glass matrix and target element isolation. The presence of potential spectral interference from doubly charged rare earth element (REE) ions affecting Sr isotopic determination was investigated by admixing Er and Yb aerosols by means of pneumatic nebulisation into the gas flow from the laser ablation system. It was shown that doubly charged REE ions affect the Sr isotope ratios, but that this could be circumvented by operating the instrument at higher mass resolution. Multiple strategies to correct for instrumental mass discrimination in ns‐LA‐MC‐ICP‐MS and the effects of relevant interferences were evaluated. Application of common glass reference materials with basaltic matrices for correction of ns‐LA‐MC‐ICP‐MS isotope data of archaeological glasses results in inaccurate Pb isotope ratios, rendering application of matrix‐matched reference materials indispensable. Correction for instrumental mass discrimination using the exponential law, with the application of Tl as an internal isotopic standard element introduced by pneumatic nebulisation and Corning D as bracketing isotopic calibrator, provided the most accurate results for Pb isotope ratio measurements in archaeological glass. Mass bias correction relying on the power law, combined with intra‐element internal correction, assuming a constant ⁸⁸Sr/⁸⁶Sr ratio, yielded the most accurate results for ⁸⁷Sr/⁸⁶Sr determination in archaeological glasses     

Petrographic,fluid inclusion and isotopic study of the Dikulushi Cu–Ag deposit,Katanga (D.R.C.): implications for exploration

The Dikulushi Cu–Ag vein-type deposit is located on the Kundelungu Plateau, in the southeastern part of the Democratic Republic of Congo (D.R.C.). The Kundelungu Plateau is situated to the north of the Lufilian Arc that hosts the world-class stratiform Cu–Co deposits of the Central African Copperbelt. A combined petrographic, fluid inclusion and stable isotope study revealed that the mineralisation at Dikulushi developed during two spatially and temporally distinct mineralising episodes. An early Cu–Pb–Zn–Fe mineralisation took place during the Lufilian Orogeny in a zone of crosscutting EW- and NE-oriented faults and consists of a sequence of sulphides that precipitated from moderate-temperature, saline H₂O–NaCl–CaCl₂-rich fluids. These fluids interacted extensively with the country rocks. Sulphur was probably derived from thermochemical reduction of Neoproterozoic seawater sulphate. Undeformed, post-orogenic Cu–Ag mineralisation remobilised the upper part of the Cu–Pb–Zn–Fe mineralisation in an oxidising environment along reactivated and newly formed NE-oriented faults in the eastern part of the deposit. This mineralisation is dominated by massive Ag-rich chalcocite that precipitated from low-temperature H₂O–NaCl–KCl fluids, generated by mixing of moderate- and low-saline fluids. The same evolution in mineralisation assemblages and types of mineralising fluids is observed in three other Cu deposits on the Kundelungu Plateau. Therefore, the recognition of two distinct types of (vein-type) mineralisation in the study area has a profound impact on the exploration in the Kundelungu Plateau region. The identification of a Cu–Ag type mineralisation at the surface could imply the presence of a Cu–Pb–Zn–Fe mineralisation at depth.     

Biomarker lipids of the freshwater fern Azolla and its fossil counterpart from the Eocene Arctic Ocean

Eocene sediments recovered from the Lomonosov Ridge in the central Arctic Ocean during Integrated Ocean Drilling Program Expedition 302 contain high amounts of fossil remains of the free floating freshwater fern Azolla. Both extant Azolla and the sediments from the Arctic Azolla interval were found to contain relatively high quantities of compounds identified as 1,ω20 C₃₀–C₃₆ diols. Furthermore, structurally related mid-chain hydroxy fatty acids, long chain n-alkanols and keto-ols were discovered. The different series have a common feature: there is always a hydroxy group at the ω20 position. In addition, structurally related C₂₉ ω20,ω21 diols, C₂₉ 1,20,21 triols, C₂₉ dihydroxy fatty acids as well as a series of wax esters containing these mono- and dihydroxy lipids are reported. Selective extraction of Azolla surface lipids revealed that these compounds are most likely present in the leaf waxes of the fern. The suite of long-chain, mid-chain ω20 hydroxy wax constituents is described for the first time. As they are well preserved in the Eocene sediments, these lipids may serve as palaeo-environmental indicators of the Arctic Azolla interval and as markers for the past occurrence of Azolla in general.     

On the potential of plant species invasion influencing bio‐geomorphologic landscape formation in salt marshes

Species invasions are known to change biotic and abiotic ecosystem characteristics such as community structure, cycling of materials and dynamics of rivers. However, their ability to alter interactions between biotic and abiotic ecosystem components, in particular bio‐geomorphic feedbacks and the resulting landscape configuration in tidal wetlands, such as tidal channels have not yet been demonstrated. We studied the impact of altered bio‐geomorphic feedbacks on geomorphologic features (i.e. tidal wetland channels), by comparing proxies for channel network geometry (unchanneled flow lengths, fractal dimension) over time between non‐invaded and invaded salt marsh habitats. The non‐invaded habitats (the south of eastern Chongming Island, Yangtze estuary, China) show little change in network geometry over time with a tendency for an increased drainage density. The invaded site (salt marshes in the north of eastern Chongming Island invaded by the exotic plant species Spartina alterniflora) showed a decreasing tendency in channel drainage density throughout and after the species invasion. This suggests that species invasions might not only affect biotic ecosystem characteristics, but also their ability to change bio‐geomorphic feedback loops, potentially leading to changes in existing geomorphologic features and therefore landscape configuration. Our results further suggest that the species invasion also altered sediment composition. Based on observations we propose a mechanism explaining the change in channel drainage density by an alteration in plant properties. The physical and physiological characteristics of the invading species Spartina alterniflora clearly differ from the native species Scirpus mariqueter, inducing different bio‐geomorphic feedback loops leading to the observed change in salt marsh channel configuration. Copyright © 2016 John Wiley & Sons, Ltd.     

Thermochronological insights into the structural contact between the Tian Shan and Pamirs,Tajikistan

Multi‐method thermochronology along the Vakhsh‐Surkhob fault zone reveals the thermotectonic history of the South Tian Shan–Pamirs boundary. Apatite U/Pb analyses yield a consistent age of 251 ± 2 Ma, corresponding to cooling below ~550–350°C, related to the final closure of the Palaeo‐Asian Ocean and contemporaneous magmatism in the South Tian Shan. Zircon (U–Th–Sm)/He ages constrain cooling below ~180°C to the end of the Triassic (~200 Ma), likely related either to deformation induced by the Qiangtang collision or to the closure of the Rushan Ocean. Apatite fission track thermochronology reveals two low‐temperature (<120°C) thermal events at ~25 Ma and ~10 Ma, which may be correlated with tectonic activity at the distant southern Eurasian margin. The late Miocene cooling is confirmed by apatite (U–Th–Sm)/He data and marks the onset of mountain building within the South Tian Shan that is ongoing today.     

Submerged macrophytes avoiding a negative feedback in reaction to hydrodynamic stress

In most aquatic ecosystems, hydrodynamic conditions are a key abiotic factor determining species distribution and aquatic plant abundance. Recently, local differences in hydrodynamic conditions have been shown to be an explanatory mechanism for the patchy pattern of Callitriche platycarpa Kütz. vegetation in lowland rivers. These local conditions consists of specific areas of increased shear zones, resulting in additional plant stress and erosion of the sediment on the one hand and local decreased shear zones resulting in zones favourable to plant growth and sedimentation of bed material on the other hand. In this study, the process of this spatial plant-flow-sedimentation interaction has been illustrated quantitatively by in situ flume measurements. By disturbing the incoming discharge on a single patch in such flume, we have quantified the behaviour and influence of a C. platycarpa patch under normal field conditions (base flow). Additionally, the behaviour of a C. platycarpa patch under different conditions of hydrodynamic stress has been examined in a laboratory flume. Indeed, flexible, submerged macrophytes are capable to adapt patch dimensions with changing stream velocities. At times of modest hydrodynamic stress, the species takes a position near the water surface and optimises its leaf stand, thereby maximising its photosynthetic capacity. At times of peak discharge, the patch will bend down towards the river bed and become more confined and streamlined, as such averting the stream velocity and diminishing the risk of breaking or being uprooted.In this paper, the processes of local hydrodynamic conditions on the patch and the patch’ intriguing life strategy of avoiding negative feedback was shown.     

Tectonics and geodynamics of Gorny Altai and adjacent structures of the Altai–Sayan folded area

Packages of Late Paleozoic tectonic nappes and associated major NE-trending strike-slip faults are widely developed in the Altai–Sayan folded area. Fragments of early deformational phases are preserved within the Late Paleozoic allochthons and autochthons. Caledonian fold-nappe and strike-slip structures, as well as accompanying metamorphism and granitization in the region, are typical of the EW-trending suture-shear zone separating the composite Kazakhstan–Baikal continent and Siberia. In the Gorny Altai region, the Late Paleozoic nappes envelop the autochthon, which contains a fragment of the Vendian–Cambrian Kuznetsk–Altai island arc with accretionary wedges of the Biya–Katun’ and Kurai zones. The fold-nappe deformations within the latter zones occurred during the Late Cambrian (Salairian) and can thus be considered Salairian orogenic phases. The Salairian fold-nappe structure is stratigraphically overlain by a thick (up to 15 km) well-stratified rock unit of the Anyui–Chuya zone, which is composed of Middle Cambrian–Early Ordovician fore-arc basin rocks unconformably overlain by Ordovician–Early Devonian carbonate-terrigenous passive-margin sequences. These rocks are crosscut by intrusions and overlain by a volcanosedimentary unit of the Devonian active margin. The top of the section is marked by Famennian–Visean molasse deposits onlapping onto Devonian rocks. The molasse deposits accumulated above a major unconformity reflects a major Late Paleozoic phase of folding, which is most pronounced in deformations at the edges of the autochthon, nearby the Kaim, Charysh–Terekta, and Teletskoe–Kurai fault nappe zones. Upper Carboniferous coal-bearing molasse deposits are preserved as tectonic wedges within the Charysh–Terekta and Teletskoe–Kurai fault nappe zones.Detrital zircon ages from Middle Cambrian–Early Ordovician rocks of the Anyui–Chuya fore-arc zone indicate that they were primarily derived from Upper Neoproterozoic–Cambrian igneous rocks of the Kuznetsk–Altai island arc or, to a lesser extent, from an Ordovician–Early Devonian passive margin. A minor age population is represented by Paleoproterozoic grains, which was probably sourced from the Siberian craton. Zircons from the Late Carboniferous molasse deposits have much wider age spectra, ranging from Middle Devonian–Early Carboniferous to Late Ordovician–Early Silurian, Cambrian–Early Ordovician, Mesoproterozoic, Early–Middle Proterozoic, and early Paleoproterozoic. These ages are consistent with the ages of igneous and metamorphic rocks of the composite Kazakhstan–Baikal continent, which includes the Tuva-Mongolian island arc with accreted Gondwanan blocks, and a Caledonian suture-shear zone in the north. Our results suggest that the Altai–Sayan region is represented by a complex aggregate of units of different geodynamic affinity. On the one hand, these are continental margin rocks of western Siberia, containing only remnants of oceanic crust embedded in accretionary structures. On the other hand, they are represented by the Kazakhstan–Baikal continent composed of fragments of Gondwanan continental blocks. In the Early–Middle Paleozoic, they were separated by the Ob’–Zaisan oceanic basin, whose fragments are preserved in the Caledonian suture-shear zone. The movements during the Late Paleozoic occurred along older, reactivated structures and produced the large intracontinental Central Asian orogen, which is interpreted to be a far-field effect of the colliding East European, Siberian, and Kazakhstan–Baikal continents.     

Genesis of sediment-hosted stratiform copper–cobalt mineralization at Luiswishi and Kamoto, Katanga Copperbelt (Democratic Republic of Congo)

The sediment-hosted stratiform Cu–Co mineralization of the Luiswishi and Kamoto deposits in the Katangan Copperbelt is hosted by the Neoproterozoic Mines Subgroup. Two main hypogene Cu–Co sulfide mineralization stages and associated gangue minerals (dolomite and quartz) are distinguished. The first is an early diagenetic, typical stratiform mineralization with fine-grained minerals, whereas the second is a multistage syn-orogenic stratiform to stratabound mineralization with coarse-grained minerals. For both stages, the main hypogene Cu–Co sulfide minerals are chalcopyrite, bornite, carrollite, and chalcocite. These minerals are in many places replaced by supergene sulfides (e.g., digenite and covellite), especially near the surface, and are completely oxidized in the weathered superficial zone and in surface outcrops, with malachite, heterogenite, chrysocolla, and azurite as the main oxidation products. The hypogene sulfides of the first Cu–Co stage display δ³⁴S values (−10.3‰ to +3.1‰ Vienna Canyon Diablo Troilite (V-CDT)), which partly overlap with the δ³⁴S signature of framboidal pyrites (−28.7‰ to 4.2‰ V-CDT) and have ∆³⁴S_SO4-Sulfides in the range of 14.4‰ to 27.8‰. This fractionation is consistent with bacterial sulfate reduction (BSR). The hypogene sulfides of the second Cu–Co stage display δ³⁴S signatures that are either similar (−13.1‰ to +5.2‰ V-CDT) to the δ³⁴S values of the sulfides of the first Cu–Co stage or comparable (+18.6‰ to +21.0‰ V-CDT) to the δ³⁴S of Neoproterozoic seawater. This indicates that the sulfides of the second stage obtained their sulfur by both remobilization from early diagenetic sulfides and from thermochemical sulfate reduction (TSR). The carbon (−9.9‰ to −1.4‰ Vienna Pee Dee Belemnite (V-PDB)) and oxygen (−14.3‰ to −7.7‰ V-PDB) isotope signatures of dolomites associated with the first Cu–Co stage are in agreement with the interpretation that these dolomites are by-products of BSR. The carbon (−8.6‰ to +0.3‰ V-PDB) and oxygen (−24.0‰ to −10.3‰ V-PDB) isotope signatures of dolomites associated with the second Cu–Co stage are mostly similar to the δ¹³C (−7.1‰ to +1.3‰ V-PDB) and δ¹⁸O (−14.5‰ to −7.2‰ V-PDB) of the host rock and of the dolomites of the first Cu–Co stage. This indicates that the dolomites of the second Cu–Co stage precipitated from a high-temperature, host rock-buffered fluid, possibly under the influence of TSR. The dolomites associated with the first Cu–Co stage are characterized by significantly radiogenic Sr isotope signatures (0.70987 to 0.73576) that show a good correspondence with the Sr isotope signatures of the granitic basement rocks at an age of ca. 816 Ma. This indicates that the mineralizing fluid of the first Cu–Co stage has most likely leached radiogenic Sr and Cu–Co metals by interaction with the underlying basement rocks and/or with arenitic sedimentary rocks derived from such a basement. In contrast, the Sr isotope signatures (0.70883 to 0.71215) of the dolomites associated with the second stage show a good correspondence with the ⁸⁷Sr/⁸⁶Sr ratios (0.70723 to 0.70927) of poorly mineralized/barren host rocks at ca. 590 Ma. This indicates that the fluid of the second Cu–Co stage was likely a remobilizing fluid that significantly interacted with the country rocks and possibly did not mobilize additional metals from the basement rocks.