TBM机施工隧道瞬变电磁超前探测研究

在隧道掘进机(TBM)施工隧道内,传统瞬变电磁的装置形式受到了TBM机械的限制,TBM自身的金属构件对二次场衰减电压的采集产生了强烈的电磁干扰.为了克服瞬变电磁法在TBM施工隧道内遇到的困难,在前人工作的基础上,尝试提出了一种基于电性源激发、电场分量采集的施工隧道瞬变电磁超前探测装置形式.针对钻爆法与TBM施工隧道各自不同的工况,利用三维时域有限差分法对单个电性源激励下隧道前方瞬变电磁场的分布规律与响应特征进行了正演模拟.通过对瞬变电磁场的分布规律以及响应特征进行分析,认为所述的电性源发射装置不仅可以在钻爆法施工隧道内使用,并且具有在TBM施工隧道内进行隧道超前预报的能力.     

北大巴山早古生代辉绿岩地球化学特征及其地质意义

对南秦岭北大巴山地区广泛分布的一套基性岩墙群中的辉绿岩进行采样,并进行了锆石U-Pb年代学、全岩地球化学分析。结果显示,岩石形成年龄为435～433 Ma,为早志留世晚期岩浆活动产物。这些辉绿岩具低硅、高碱、高钛的碱性岩特征。岩石微量及稀土元素具板内玄武岩特征,轻稀土元素相对富集,轻重稀土元素分异明显,富集不相容元素Ba、Nb、Ta,而K、Y、Yb相对亏损; K及Rb的负异常表明岩石源区残留角闪石或金云母,部分熔融模拟结果显示岩石起源于尖晶石角闪石岩高程度部分熔融。综合地球化学特征及前人研究结果,认为北大巴山地区在早古生代处于大规模伸展裂陷背景下,岩石圈的拉张诱发了低熔点的交代岩石圈地幔熔融,进而形成了这条碱性岩浆带。     

土钉与土体相互作用的仿真试验分析

运用快速拉格朗日元(FLAC3D)数值法,考虑土钉的加固作用及土钉与土体的相互作用,模拟土钉支护施工过程.选择能够反映开挖特点的土的本构关系、开挖支护模拟过程及双弹簧土钉单元,建立数值分析模型.分析了基底、基坑壁土体的变形响应及土钉在开挖、使用阶段的力学响应.结果表明:①开挖引起基坑壁变形,并导致拉伸与剪切破坏;对于拉伸破坏,应使土钉长度超过滑移面;对于剪切破坏,可增大土钉在剪出口位置的密度;②开挖完毕后,各层土钉轴力沿长度方向的分布不均匀,土钉轴力最大值位置可表征潜在滑动面的位置.FLAC3D能够对基坑分步开挖及支护进行模拟,建立的数值模型能够反映土钉支护基坑的真实情况,为基坑土钉支护技术的设计与施工提供指导.     

喀喇昆仑地体甜水海地区102Ma辉长岩的发现及其对区域中生代构造演化的约束

喀喇昆仑地体是青藏高原的重要构造单元。近来,我们对其中的林济塘中生代盆地地层进行了调查,并在喀喇昆仑地体甜水海地区褶皱的中侏罗统龙山组灰岩中发现了辉长岩侵入体。辉长岩具有高Al2O3(15.07%~15.32%)与TiO2(1.31%~1.34%)、贫P2O5(0.19%~0.21%)和低碱(Na2O+K2O=3.49%~3.72%)的特征,明显富集轻稀土(La/Yb=6.17~7.39),富集Th、La、Nd与Tb,亏损Rb、Sr、P与Y,辉长岩Sr-Nd同位素表现出富集的特征(εNd(t)值分别为-5.8与-5.9)。LA-ICP-MS锆石U-Pb测年结果显示辉长岩岩浆锆石206Pb/238U年龄为102±1Ma(MSWD=0.92;n=14),指示岩体形成于早白垩世晚期。辉长岩中含有大量继承锆石,38颗继承锆石年龄分布在2450~232Ma之间,其中16颗为前寒武纪年龄锆石,意味着该地区可能存在前寒武纪基底。这些特征意味着辉长岩在形成的过程中经历壳源物质的强烈混染(Nb/U、Ta/U、Ce/Pb分别为26.6~29.1、1.69~1.76、9.72~11.3)。这种经历壳源物质的强烈混染岩浆的形成可能与软流圈上涌有关,即102Ma辉长岩形成时甜水海地区处于伸展背景。结合区域地质特征,指出102Ma时研究区进入新的伸展与海盆发育阶段,并建立了喀喇昆仑地体中生代三阶段构造演化模型,即侏罗纪-早白垩世早期的正常俯冲与弧盆演化、早白垩世的平板俯冲与造山阶段及晚白垩世的正常俯冲与弧盆演化。     

南秦岭早古生代玄武岩的岩浆源区及演化过程

南秦岭地区早古生代玄武岩中发育的大量单斜辉石斑晶为研究火山岩的深部演化过程及源区属性提供了重要的载体。本文通过对早古生代玄武岩及其中的单斜辉石斑晶进行矿物学、岩石学及地球化学分析,讨论火山岩的演化历程及源区属性。电子探针分析结果表明玄武岩中单斜辉石斑晶属于透辉石,其成分与全岩成分并不平衡,暗示岩石经历了单斜辉石的堆晶作用。通过质量平衡计算得到了与单斜辉石斑晶平衡的熔体并计算了单斜辉石结晶的温压条件,结果显示单斜辉石斑晶结晶压力为7.6~14.0kbar,温度为1201~1268℃。高压下的分离结晶作用导致了单斜辉石成为主要的结晶相。重建后的玄武岩具有高镁、高钙、富钛,富集高场强元素Nb、Ta,亏损Rb、K、Sr和P,Dy/Yb比值高的地球化学特征,指示其源区为含单斜辉石、磷灰石及石榴石的交代岩石圈地幔。同地区发现的玄武质角砾也具高镁及高钙的特征,其富集Ba、Nb、Ta、Ti及低Dy/Yb比值表明源区为含单斜辉石、角闪石及尖晶石的交代岩石圈地幔。

     

重庆涪陵页岩气勘查开发区环境地质调查进展

紧密结合国家非常规能源勘探开发的重大战略,聚焦重庆涪陵页岩气勘查开发区环境地质调查工作,总结了研究区岩溶发育特征与分布规律,评价了涪陵页岩气开发区区域水资源量和地下水质量。在此基础上,收集分析国内外资料,梳理了页岩气勘查开发所引发的6类环境(地质)问题及勘查、钻井、压裂、开采、闭井等5个阶段需关注的地质环境问题或风险等,其中涪陵页岩气勘查开发区主要诱发水土污染、地质灾害和大气污染等环境(地质)问题; 基本识别了2种地下水污染模式、3种污染类型及可能的地下水污染风险途径; 初步确定了涪陵页岩气勘查开发区污染指示性特征因子,并形成了页岩气勘查开发区地质环境影响评价指标体系,可指导页岩气勘查开发的环境地质调查。该研究为页岩气国家新型清洁能源的绿色开发和开发区生态文明建设提供支撑。     

Association of phosphate with rhyolite glass in marine Neogene tuffs from Patagonia,Argentina

The precipitation/replacement of Ca‐phosphate is a complex process that commonly takes place during the early diagenesis in marine sediments. The unusual occurrence of shallow marine, early diagenetic phosphatic deposits associated with glassy tuffs in the Neogene Gaiman Formation, in the Chubut Province, Patagonia, Argentina, constitutes a good case example for the study of replacement and precipitation of Ca‐phosphate on an unstable substrate. Isocon diagrams illustrate that chemical changes during glass diagenesis include gains in loss on ignition and Ca, and losses of K. These changes are the result of glass hydration during sea water–glass interaction, together with adsorption and diffusion of ions into the bulk shard; combined, these represent an incipient process of volcanic glass replacement by Ca‐phosphate. Subsequent early diagenetic P enrichment in the pore solutions led to phosphate precipitation, associated with pitting on the glass shards and pumice. The associated development of a reactive surface promoted the incorporation of P and Ca into their margins. Lastly, precipitation of calcium phosphate filled the vesicles and other open cavities, inhibiting further glass dissolution. The high porosity and reactivity of the volcanic glass provided an appropriate substrate for phosphate precipitation, leading to the development of authigenic apatite concretions in the volcanic‐glass bearing strata of the Gaiman Formation. This research is of significance for those concerned with marine phosphatic deposits and sheds light on the processes of early diagenetic phosphate precipitation by replacement of an atypical, unstable substrate like hydrated volcanic glass.     

Stone Age settlement and Holocene shore displacement in the Narva‐Luga Klint Bay area,eastern Gulf of Finland

Based on geological and archaeological proxies from NW Russia and NE Estonia and on GIS‐based modelling, shore displacement during the Stone Age in the Narva‐Luga Klint Bay area in the eastern Gulf of Finland was reconstructed. The reconstructed shore displacement curve displays three regressive phases in the Baltic Sea history, interrupted by the rapid Ancylus Lake and Litorina Sea transgressions c. 10.9–10.2 cal. ka BP and c. 8.5–7.3 cal. ka BP, respectively. During the Ancylus transgression the lake level rose 9 m at an average rate of about 13 mm per year, while during the Litorina transgression the sea level rose 8 m at an average rate of about 7 mm per year. The results show that the highest shoreline of Ancylus Lake at an altitude of 8–17 m a.s.l. was formed c. 10.2 cal. ka BP and that of the Litorina Sea at an altitude of 6–14 m a.s.l., c. 7.3 cal. ka BP. The oldest traces of human activity dated to 8.5–7.9 cal. ka BP are associated with the palaeo‐Narva River in the period of low water level in the Baltic basin at the beginning of the Litorina Sea transgression. The coastal settlement associated with the Litorina Sea lagoon, presently represented by 33 Stone Age sites, developed in the area c. 7.1 cal. ka BP and existed there for more than 2000 years. Transformation from the coastal settlement back to the river settlement indicates a change from a fishing‐and‐hunting economy to farming and animal husbandry c. 4.4 cal. ka BP, coinciding with the time of the overgrowing of the lagoon in the Narva‐Luga Klint Bay area.     

内蒙古中西部宝音图群石榴角闪岩的地球化学、变质作用及年代学特征

宝音图群分布于内蒙古中西部狼山、图古日格和达茂旗一带,主要由云母片岩、石英片岩、石英岩、角闪岩和大理岩组成。在狼山格尔敖包沟和图古日格西南地区发育十分典型的石榴角闪岩,均以似层状或透镜状产自云母片岩中,但两地具有不同的矿物组合,前者主要以石榴石+角闪石+斜长石+含钛矿物（金红石和钛铁矿）为特征,后者主要以石榴石+角闪石+绿帘石+含钛矿物（金红石和钛铁矿）为特征。地球化学研究显示两个地区的石榴角闪岩原岩具有相似的化学组成,均为亚碱性玄武岩的拉斑系列。宝音图群的石榴角闪岩具有右倾的稀土配分模式,REE总量为83.31×10^-6~125.9×10^-6,（La/Yb）_N比值为2.17~6.48,δEu=0.87~0.98。Ta、Nb、Ti没有明显的负异常,其配分型式类似E-MORB特点。微量元素构造判别图解表明这些石榴角闪岩的原岩产于板内拉张环境中。本文通过模拟格尔敖包沟样品LS01和图古日格西南地区样品LS35的P-T视剖面图研究其变质作用及矿物演化过程,结果显示这两个样品均经历了早期进变质,峰期以及峰后近等温减压的顺时针型P-T轨迹。样品LS01的峰期温压条件为~11kbar/~735℃,模拟得到的峰期矿物组合可能为石榴石+角闪石+斜长石+黑云母+透辉石+金红石+熔体,P-M（H₂O）视剖面图显示,由于峰后演化过程中存在饱和流体渗透,导致峰期透辉石无法保留。样品LS35的峰期温度压力条件为~8kbar/675℃,其峰期组合为石榴石+角闪石+绿帘石+金红石。两个地区的石榴角闪岩的温度压力条件明显不同,推测宝音图群中呈透镜体或似层状产出的变质基性岩,存在着递增型的变质作用。锆石LA-ICP-MS U-Pb年代学的研究结果显示石榴角闪岩样品LS01的变质锆石年龄为394±8Ma。由此推测这些石榴角闪岩的原岩可能形成于华北北缘在新元古代发育的裂陷盆地,在泥盆纪中期,宝音图群作为华北克拉通的一部分,被卷入到与古亚洲洋闭合有关的造山过程,发育中压型递增变质作用。

     

Hydrogeochemical processes of thallium in a rural area of Southwest Guizhou, China

The water system in a rural area of Lanmuchang in Southwest Guizhou is facing a risk of thallium (Tl) contamination due to Tl mineralization around the area. The major trace elements and Tl in the water system are studied to understand the hydrogeochemical processes of Tl constrained by Tl mineralization. The results showed that the dispersion pattern of Tl follows a descending order in concentration from mine groundwater (deep groundwater) →stream water→shallow groundwater→background water, reflecting the impact of Tl mineralization on the hydrogeochemical composition. Tl concentrations in stream water in both regimes are remarkably higher (2-30 fold) downstream than up- and mid-streams, probably caused by the unidentified discharge of deep groundwater. Low Tl levels are detected in the current drinking water, however, the highly elevated Tl in stream water and ground water may pose a potential environmental risk through daily washing and agricultural irrigation. This study suggests that human activities, such as agricultural irrigation, could intensify the environmental risk of Tl.