A comparison of anthropogenic mercury pollution in Kastela Bay (Croatia) with pristine estuaries in Ore (Sweden) and Krka (Croatia)

Anthropogenic mercury pollution was studied in Kastela Bay (Croatia), 10 years after chloralkaline plant (PVC) stopped production. The concentration of total mercury determined in sediments which are composed mainly of calcite and quartz, are in the range 14,280-30,400 ng/g. The values are higher than reported in the literature for Elbe and Seine estuaries and also above 25,000 ng/g used for criterion in remediation project in Minamata Bay. The concentration of methylmercury 6.05-36.74 ng/g are typical for slightly to highly contaminated estuarine sediments. The low ratio of methylmercury to total mercury found in sediments of Kastela Bay is in the range 0.04-0.18%. It can be explained that in this region predominate conditions which do not promote in-situ methylation. Sediments were found to be highly anoxic. Concentrations of total mercury in unfiltered surface waters are in the range 69-145 ng/l and in unfiltered bottom waters in the range 230-1,418 ngl(-1). High concentrations found in bottom waters suggest that either resuspension or partial dissolution of sediments takes place. An experiment performed on filtered and unfiltered waters showed that about 85% of total mercury in surface water and almost 100% in bottom water was retained on 45 microm filters. To demonstrate contrasts, two pristine estuaries from norths and south Europe were studied. Silicious sediments of Ore estuary (Sweden) and calcareous sediments of Krka estuary (Croatia) have total mercury concentrations close to accepted background level. The ratio of methylmercury to total mercury is < or = 1% in all samples with one exception. The highest observed ratio (2.70%) was in the surface sediment from E2 station in Krka estuary measured in March 2000. This location is suitable for studying methylmercury formation in pristine environment.     

Statistical Analysis of Water Quality Parameters in Seven Major Serbian Rivers during 2004‒2013 Period

Rivers on territory of the Republic of Serbia can be separated to three sea drainage basins: Black, Adriatic and Aegean. Majority of rivers belong to the Black Sea drainage basin. The Danube is the most important river in Serbia and one of the most important rivers of Europe. All rivers investigated in this paper represent direct or indirect tributaries of the Danube River and as that, they are belonging to the Black Sea drainage basin. In this study, the water quality status and the spatial and temporal trends of seven major rivers in Serbia were assessed through the application of ten parameters of Water Quality Index. Ten year (2004–2013) public database of environmental data was used. Into considerations were taken differences between every river individually and difference between sample positions on every single river. Based on the chemical parameters of water quality, it can be seen that the biggest rivers in Serbia show different values of WQ parameters. The highest WQ value is measured on the Drina River, while the lowest value is measured on the Ju?na Morava and the Tisza River. Analyses of parameters per period of year show that there is a statistically significant difference between values during warm and cold periods.     

Seasonal variations of physiological and cellular biomarkers and their use in the biomonitoring of north Adriatic coastal waters (Croatia)

Lysosomal membrane stability, the content of neutral lipids and lipofuscin as cellular biomarkers were measured in the digestive gland of mussels, Mytilus galloprovincialis Lam., during a one year survey at selected sites along the coast of the northern Adriatic. The ability of mussels to survive in air as a general physiological response was tested at the same sites. Annual changes of sea temperature, salinity, O(2) saturation, pH and chlorophyll a concentration were measured and the effects of these environmental factors on the biomarkers selected for this study were determined. Survival of mussels after aerial exposure was significantly (p < 0.05) reduced in mussels collected from the contaminated harbors of Pula and Rijeka compared to clean control sites. Lysosomal membrane stability of mussels from urban and industrial areas was also lower indicating exposure to different environmental contaminants. At the same sites, the content of neutral lipids and lipofuscin in digestive cells was significantly higher compared to the reference sites, suggesting alterations in lipid metabolism and contaminant-induced peroxidation of cell membranes. The greatest influence of natural environmental factors was observed for the aerial survival of mussels and the neutral lipids and lipofuscin content in the digestive gland, indicating that the annual cycles of biomarker responses should be well understood for a correct interpretation of biomonitoring results.     

HVSR of ambient noise in Ston (Croatia): comparison with theoretical spectra and with the damage distribution after the 1996 Ston-Slano earthquake

Horizontal-to-vertical spectral ratios (HVSR) of ambient vibrations measured in the ancient town of Ston (Croatia) on 99 locations, are shown to be well matched to the theoretical ones computed for body-waves as well as for the surface waves. This match is poorer for sites on the slopes of nearby hills. The ratios of measured peak horizontal ground acceleration during the damaging earthquake in 1996 (M _L = 6.0) and the ones obtained using empirical attenuation laws is approximately equal to the mapped value of the dynamic amplification factor determined on the basis of observed HVSR in the vicinity of the accelerometric station. The HVSR of the accelerogram is very similar to the HVSR of the ambient noise. The damage to the building stock in the old town centre caused by the earthquake series of 1996 is closely related to the estimated soil amplification and its fundamental frequency. More measurements in buildings are needed to arrive at confident conclusions about possible soil-structure resonance.     

Dynamics of rocking podium structures

A rocking podium structure is a class of structures consisting of a superstructure placed on top of a rigid slab supported by free‐standing columns. The free‐standing columns respond to sufficiently strong ground motion excitation by uplifting and rocking. Uplift works as a mechanical fuse that limits the forces transmitted to the superstructure, while rocking enables large lateral displacements. Such ‘soft‐story’ system runs counter to the modern seismic design philosophy but has been used to construct several hundred buildings in countries of the former USSR following Polyakov's rule‐of‐thumb guidelines: (i) that the superstructure behave as a rigid body and (ii) that the maximum lateral displacement of the rocking podium frame be estimated using elastic earthquake displacement response spectra. The objectives of this paper are to present a dynamic model for analysis of the in‐plane seismic response of rocking podium structures and to investigate if Polyakov's rule‐of‐thumb guidelines are adequate for the design of such structures. Examination of the rocking podium structure response to analytical pulse and recorded ground motion excitations shows that the rocking podium structures are stable and that Polyakov's rule‐of‐thumb guidelines produce generally conservative designs. Copyright © 2017 John Wiley & Sons, Ltd.     

Selenium deficiency as a consequence of human activity and its correction

Problems of sustainable development in connection with the change of biogeochemical cycle of selenium and overcoming its deficiency in Russia, Serbia, Belarus and other countries are reported. The history of the biological role of selenium as an essential trace element is discussed. A special program of «Overcoming of selenium deficiency» has been developed by researches of Russia, Serbia and Belarus in view of high morbidity rates for cardiovascular, tumor and endemic diseases affecting the population of both the above and some other countries, including children, prevalence of selenium deficiency among livestock species and aggravation of the environmental situation as a result of man-made processes.     

Repetitiveness and underlying characteristics of climatologic parameters in winter

Starting from the standpoint that there are seasonal differences of climate variations on both global and local level, the authors of this paper had focused on analyzing climatologic parameters in winter months. The trends of several important parameters were detected, with temperature and precipitation having increasing, but number of ice days and snow cover having decreasing trends. Spectral analysis showed repetitive nature of climatologic parameters, some of them having the same or similar periods of about 6 to 7 years, 10 to 12 or 17.5 years, and 22 to 24 years. The precipitation has periodicity of 8 and 14 years. Further analysis of the underlying structure of the data by principal component analysis detected three easily explained dimensions: Temperature-Snow, Precipitation-Cyclone and Spring-in-Winter dimension. The spectral analysis of three virtual variables obtained by principal component analysis confirmed good agreement of original variables with the virtual dimensions.     

Toxicological effects of biocide Slimicide C-30 on some marine invertebrates

Sublethal and lethal effects of biocide Slimicide C-30 on the developmental stages of mussels Mytilus galloprovincialis and juvenile and adult mysid Leptomysis mediterranea were studied.Biocide at a concentration as low as 0.02 mg l^?1 caused an incipient effect in the embryonic development of mussels where a decreased number of normally developed larvae from eggs was evident. Slimicide C-30 effective concentration (EC 50/96) was 0.07 mg l^?1.In the mysids, the median lethal concentration (96 h LC₅₀) was 0.11 mg l^?1.Previous incubation of Slimicide C-30 at 38°C affected a small delay in mortality time (LT₅₀) but did not cause marked change in the acute toxicity to mysids.     

An assessment of global and regional climate change based on the EH5OM climate model ensemble

An analysis of climate change for global domain and for the European/Mediterranean region between the two periods, 1961–1990 (representing the twentieth century or “present” climate) and 2041–2070 (representing future climate), from the three-member ensemble of the EH5OM climate model under the IPCC A2 scenario was performed. Ensemble averages for winter and summer seasons were considered, but also intra-ensemble variations and the change of interannual variability between the two periods. First, model systematic errors are assessed because they could be closely related to uncertainties in climate change. A strengthening of westerlies (zonalization) over the northern Europe is associated with an erroneous increase in MSLP over the southern Europe. This increase in MSLP is related to a (partial) suppression of summer convective precipitation. Global warming in future climate is relatively uniform in the upper troposphere and it is associated with a 10% wind increase in the subtropical jet cores. However, spatial irregularities in the low-level temperature signal single out some regions as particularly sensitive to climate change. For Europe, the largest near-surface temperature increase in winter is found over its north-eastern part (more than 3°C), and the largest summer warming (over 3.5°C) is over south Europe. For south Europe, the increase in temperature averages is almost an order of magnitude larger than the increase in interannual variability. The magnitude of the warming is larger than the model systematic error, and the spread among the three model realisations is much smaller than the magnitude of climate change. This further supports the significance of estimated future temperature change. However, this is not the case for precipitation, implying therefore larger uncertainties for precipitation than for temperature in future climate projections.     

An analytical model of a deformable cantilever structure rocking on a rigid surface: experimental validation

This paper describes an experimental program to examine the dynamic response of deformable cantilevers rocking on a rigid surface. The primary goal of the tests is to verify and validate a dynamic rocking model that describes the behavior of these structures. The benchmark response data was obtained from shaking‐table tests on deformable rocking specimens with different natural vibration frequencies and different aspect ratios excited by analytical pulses and recorded ground motions. The responses computed using the model are found to be in good agreement with the benchmark test results. Widely used impact, restitution and damping assumptions are revisited based on the experiment results and the analytical model findings. Copyright © 2015 John Wiley & Sons, Ltd.