Estimating Effective Porosity in Bedrock Aquifers

Flow in many bedrock aquifers is through fracture networks. Point to point tracer tests using applied tracers provide a direct measure of time of travel and are most useful for determining effective porosity. Calculated values from these tests are typically between 10⁻⁴ and 10⁻² (0.01% to 1%), with these low values indicating preferential flow through fracture and channel networks. Tracer tests are not commonly used in site investigations, and specific yield is often used as a proxy for effective porosity. The most popular methods have used centrifuge measurements, water table fluctuations, pumping tests, and packer tests. Specific yield varies substantially with the testing method. No method is as reliable as tracer testing for providing estimates of effective porosity, but all methods provide complementary insights on aquifer structure. Temporal and spatial scaling effects suggest that bedrock aquifers have hierarchical structures, with a network of more permeable fractures and channels, which are connected to less permeable fractures and to the matrix. Consequences of the low effective porosities include groundwater velocities that often exceed 100 m/d and more frequent microbial contamination than in aquifers in unconsolidated sediments. The large uncertainty over the magnitude of effective porosity in bedrock aquifers makes it an important parameter to determine in studies where time of travel is of interest.     

Focusing effect of bent GaAs crystals for <Emphasis Type="Italic">γ</Emphasis>-ray Laue lenses: Monte Carlo and experimental results

We report on results of observation of the focusing effect from the planes (220) of Gallium Arsenide (GaAs) crystals. We have compared the experimental results with the Monte Carlo simulations of the focusing capability of GaAs tiles performed with a dedicated ray-tracer. The GaAs tiles were bent using a lapping process developed at the cnr/imem - Parma (Italy) in the framework of the laue project, funded by ASI, dedicated to build a broad band Laue lens prototype for astrophysical applications in the hard X-/soft γ-ray energy range (80-600 keV). We present and discuss the results obtained from their characterization, mainly in terms of focusing capability. Bent crystals will significantly increase the signal to noise ratio of a telescope based on a Laue lens, consequently leading to an unprecedented enhancement of sensitivity with respect to the present non focusing instrumentation.     

Petrology of spinel lherzolite xenoliths from Youkou volcano,Adamawa Massif,Cameroon Volcanic Line: mineralogical and geochemical fingerprints of sub-rift mantle processes

The basaltic maar of Youkou, situated in the Adamawa Volcanic Massif in the eastern branch of the continental segment of the Cameroon Volcanic Line, contains mantle-derived xenoliths of various types in pyroclastites. Spinel-bearing lherzolite xenoliths from the Youkou volcano generally exhibit protogranular textures with olivine (Fo_89.4?90.5), enstatite (En_89???91Fs_8.7?9.8Wo_0.82?1.13), clinopyroxene, spinel (Cr#_Sp?=?9.4–13.8), and in some cases amphibole (Mg_#?=?88.5–89.1). Mineral equilibration temperatures in the lherzolite xenoliths have been estimated from three–two pyroxene thermometers and range between 835 and 937 °C at pressures of 10–18 kbar, consistent with shallow mantle depths of around 32–58 km. Trends displayed by bulk-rock MgO correlate with Al₂O₃, indicating that the xenoliths are refractory mantle residues after partial melting. The degree of partial melting estimated from spinel compositions is less than 10%: evidences for much higher degrees of depletion are preserved in one sample, but overprinted by refertilization in others. Trace element compositions of the xenoliths are enriched in highly incompatible elements (LREE, Sr, Ba, and U), indicating that the spinel lherzolites underwent later cryptic metasomatic enrichment induced by plume-related hydrous silicate melts. The extreme fertility (Al₂O₃?=?6.07–6.56 wt% in clinopyroxene) and the low CaO/Al₂O₃ ratios in the spinel lherzolites suggest that they could not be a simple residue of partial melting of primitive mantle and must have experienced refertilization processes driven by the infiltration of carbonatite or carbonated silicate melts.     

The wider context of the Lower Jurassic Toarcian oceanic anoxic event in Yorkshire coastal outcrops,UK

The Toarcian Oceanic Anoxic Event (T-OAE, ～183 Ma) was characterized by enhanced carbon burial, a prominent negative carbon-isotope excursion (CIE) in marine carbonate and organic matter, and numerous geochemical anomalies. A precursor excursion has also been documented at the Pliensbachian/Toarcian boundary, but its possible causes are less constrained. The T-OAE is intensively studied in the Cleveland Basin, Yorkshire, UK, whose sedimentary deposits have been litho-, bio- and chemostratigraphically characterised. Here, we present new elemental data produced by hand-held X-ray fluorescence analysis to test the expression of redox-sensitive trace metals and detrital elements across the upper Pliensbachian to mid-Toarcian of the Cleveland Basin. Detrital elemental concentrations (Al, Si, Ti, Zr) are used as proxies for siliciclastic grain content and thus, sea-level change, which match previous sequence stratigraphic interpretations from the Cleveland Basin. The timescale of the event is debated, though our new elemental proxies of relative sea level change show evidence for a cyclicity of 350 cm that may be indicative of ～405 kyr eccentricity cycles in Yorkshire. Trends in total organic carbon and redox-sensitive elements (S, Fe, Mo, As) confirm scenarios of widespread ocean deoxygenation across the T-OAE. The correlation of comparable trends in Mo across the T-OAE in Yorkshire and the Paris Basin suggests a similar oceanic drawdown of this element accompanying widespread anoxia in the two basins. Data from Yorkshire point to a transgressive trend at the time of the Mo drawdown, which contradicts the “basin restriction” model for the euxinic conditions that characterise the CIE interval.     

New insights into volcanic processes from deep mining of the southern diatreme within the Argyle lamproite pipe,Western Australia

Underground mining and deep drilling of the richly diamondiferous ~1.2 Ga Argyle lamproite in Western Australia has prompted a re-evaluation of the geology of the pipe. Argyle is considered to be a composite pipe that formed by the coalescence of several diatremes and has been offset and elongated by post-emplacement faulting. Recent geological studies have recognised at least five distinct volcaniclastic lamproite lithofacies with differing diamond grades. The new data suggest that the centre of the southern (main) diatreme is occupied by well-bedded, olivine lamproite lapilli tuff with very high diamond grades (>10 ct/t). Characteristic features include a clast-supported fabric and high modal abundance of densely packed lamproite lapilli and coarse-grained, likely mantle-derived olivine now replaced by serpentine and/or talc. The persistence of small-scale graded and cross-bedding in this lithofacies to depths of ~1.5 km below the original surface prior to erosion suggests phreatomagmatic volcanism forming the diatreme was syn-eruptively accompanied by subsidence of the tephra, maintaining a steep-walled diatreme in the water-saturated country rock sediments.

     

Functional and Compositional Responses of Periphyton Mats to Simulated Saltwater Intrusion in the Southern Everglades

Periphyton plays key ecological roles in karstic, freshwater wetlands and is extremely sensitive to environmental change making it a powerful tool to detect saltwater intrusion into these vulnerable and valuable ecosystems. We conducted field mesocosm experiments in the Florida Everglades, USA to test the effects of saltwater intrusion on periphyton metabolism, nutrient content, and diatom species composition, and how these responses differ between mats from a freshwater versus a brackish marsh. Pulsed saltwater intrusion was simulated by dosing treatment chambers monthly with a brine solution for 15 months; control chambers were simultaneously dosed with site water. Periphyton from the freshwater marsh responded to a 1-ppt increase in surface water salinity with reduced productivity and decreased concentrations of total carbon, nitrogen, and phosphorus. These functional responses were accompanied by significant shifts in periphytic diatom assemblages. Periphyton mats at the brackish marsh were more functionally resilient to the saltwater treatment (~?2 ppt above ambient), but nonetheless experienced significant shifts in diatom composition. These findings suggest that freshwater periphyton is negatively affected by small, short-term increases in salinity and that periphytic diatom assemblages, particularly at the brackish marsh, are a better metric of salinity increases compared with periphyton functional metrics due to functional redundancy. This research provides new and valuable information regarding periphyton dynamics in response to changing water sources in the southern Everglades that will allow us to extend the use of periphyton, and their diatom assemblages, as tools for environmental assessments related to saltwater intrusion.     

Historical Trends of Benthic Invertebrate Biodiversity Spanning 182 Years in a Southern New England Estuary

Benthic invertebrates support numerous ecosystem functions and services including shellfish production, energy flow to fishes, and biogeochemical cycles. The decline of marine biodiversity worldwide has raised concerns about effects on ecosystems. To examine biodiversity trends of Narragansett Bay over time, a list was compiled of all benthic invertebrate species collected from the bay since 1834. The list covers 104 studies spanning 182 years and currently holds 1214 unique taxa from 21 phyla, the majority of all animal phyla on Earth. A permuted estimator of number of species suggested there are about 300 more yet to be discovered. Widely varying sampling gear and sieve mesh sizes precluded the use of abundance data. Instead, multidimensional scaling and taxonomic distinctness were used with presence-absence data to examine biodiversity trends. The changes in community composition and decline of benthic biodiversity (p?<?0.01) since 1855 are what would be expected of a community that gradually deteriorated in the face of increasing anthropogenic stressors. Taxonomic distinctness had negative correlations (p?<?0.05) with human population in the watershed, total nitrogen inputs, and inputs of metals. This loss of benthic biodiversity has implications for ecosystem functions and services. As some of the stressors waned in the last two or three decades, following passage of environmental legislation in the 1970s, biodiversity appeared to show a partial recovery. An inventory of species, how it has changed over time, and understanding what caused those changes are important for assessing whether remediation programs are achieving improved water quality and ecosystem health.     

Temporal Changes in Seawater Carbonate Chemistry and Carbon Export from a Southern California Estuary

Estuaries are important subcomponents of the coastal ocean, but knowledge about the temporal and spatial variability of their carbonate chemistry, as well as their contribution to coastal and global carbon fluxes, are limited. In the present study, we measured the temporal and spatial variability of biogeochemical parameters in a saltmarsh estuary in Southern California, the San Dieguito Lagoon (SDL). We also estimated the flux of dissolved inorganic carbon (DIC) and total organic carbon (TOC) to the adjacent coastal ocean over diel and seasonal timescales. The combined net flux of DIC and TOC (F_DIC?+?TOC) to the ocean during outgoing tides ranged from ??1.8±0.5?×?10³ to 9.5±0.7?×?10³?mol C h^?1 during baseline conditions. Based on these fluxes, a rough estimate of the net annual export of DIC and TOC totaled 10±4?×?10⁶?mol C year^?1. Following a major rain event (36 mm rain in 3 days), F_DIC?+?TOC increased and reached values as high as 29.0 ±?0.7?×?10³?mol C h^?1. Assuming a hypothetical scenario of three similar storm events in a year, our annual net flux estimate more than doubled to 25 ±?4?×?10⁶?mol C year^?1. These findings highlight the importance of assessing coastal carbon fluxes on different timescales and incorporating event scale variations in these assessments. Furthermore, for most of the observations elevated levels of total alkalinity (TA) and pH were observed at the estuary mouth relative to the coastal ocean. This suggests that SDL partly buffers against acidification of adjacent coastal surface waters, although the spatial extent of this buffering is likely small.