Identification and occurrence of 25-norbenzohopanes in biodegraded bitumen from Palaeozoic carbonates in northern Alberta

In addition to the previously reported 25-norhopanes and 25-norhopanoic acids, for the first time we report the identification of 25-norbenzohopanes. The hydrocarbon composition of the bitumen from Palaeozoic carbonates in northern Alberta displays molecular evidence for severe levels of biodegradation characterised by the removal of C₃₀–C₃₅ hopanes. Biodegradation is also indicated by the removal of C₃₂ and C₃₃ benzohopanes. The appearance of C₃₁ and C₃₂ 25-norbenzohopanes corresponds to the decrease in C₃₂ and C₃₃ benzohopanes, suggesting that 25-norbenzohopanes originate by demethylation of benzohopane counterparts. Demethylation at C-10 in the hopanoids affects a broader class of compounds that so far includes the hopanes and hopanoic acids, as well as the benzylated hopanoid species.     

Fluvial channels on Titan: Initial Cassini RADAR observations

Cassini radar images show a variety of fluvial channels on Titan's surface, often several hundreds of kilometers in length. Some (predominantly at low- and mid-latitude) are radar-bright and braided, resembling desert washes where fines have been removed by energetic surface liquid flow, presumably from methane rainstorms. Others (predominantly at high latitudes) are radar-dark and meandering and drain into or connect polar lakes, suggesting slower-moving flow depositing fine-grained sediments. A third type, seen predominantly at mid- and high latitudes, have radar brightness patterns indicating topographic incision, with valley widths of up to 3 km across and depth of several hundred meters. These observations show that fluvial activity occurs at least occasionally at all latitudes, not only at the Huygens landing site, and can produce channels much larger in scale than those observed there. The areas in which channels are prominent so far amount to about 1% of Titan's surface, of which only a fraction is actually occupied by channels. The corresponding global sediment volume inferred is not enough to account for the extensive sand seas. Channels observed so far have a consistent large-scale flow pattern, tending to flow polewards and eastwards.     

Spatially-averaged flow statistics within a canopy of large bluff bodies: Results from direct numerical simulations

The flow within a canopy of large bluff bodies is highly turbulent and spatially heterogeneous. Results from direct numerical simulations over groups of cubical obstacles are analysed using the double-averaging methodology. The obstacles occupy a significant fraction of the canopy space; this gives rise to substantial dispersive stresses within the canopy. The underlying bluff-body turbulent dynamics is different from typical canopy turbulence, and this is reflected in the double-averaged statistics. The spatially-averaged velocities, stresses and drag force depend significantly upon the layout of the obstacles. An ongoing challenge is to parameterise these spatially-averaged quantities in terms of the obstacle geometry and layout.     

Double-averaged velocity and stress distributions for hydraulically-smooth and transitionally-rough turbulent flows

We analyse experimental measurements of turbulent open-channel flow over hydraulically-smooth and transitionally-rough beds using the double-averaging methodology. Oil with a viscosity of 15×10^?6 m2/s is used instead of water so that transitional-range roughness Reynolds numbers can be achieved with large (11.1 mm) roughness elements, allowing spatial variations in the mean velocity field to more easily be measured. Distributions of double-averaged velocities, turbulence intensities, form-induced intensities, and viscous, Reynolds, form-induced and total shear stresses are studied with comparisons made between distributions for hydraulically-smooth, transitionally-rough, and fully-rough boundaries. Measured streamwise turbulence intensities for all experiments peaked at a constant distance from the bed (z ⁺+d ⁺ = 15) when elevation scale is adjusted using the zero-plane displacement d for the logarithmic velocity distribution. This collapse suggests that turbulence intensity distributions may be useful in assessing appropriate values of d for transitionally-rough and fully-rough boundaries. Form-induced normal and shear stresses above the roughness tops were found to collapse towards a common curve independent of roughness Reynolds number.     

Seismic scale saturation relations in turbidite reservoirs undergoing waterflood

Estimates of the effective fluid modulus from seismic cannot be directly converted to the true pore-volume weighted mean saturation     determined from fluid flow principles by using the saturation laws currently in use. One of the reasons is that seismic waves sample the reservoir geology and production induced saturation heterogeneity in a different way from the fluids. This mismatch prevents accurate quantitative evaluation of saturation changes from 4D seismic analysis. To tackle this problem, a reservoir-related saturation law is developed for a turbidite reservoir – this geology being chosen because the architecture for a single sand package can be modelled as a stack of horizontal beds. An effective medium and perturbation theory are applied to the determination of the seismic properties of this model. This calculation provides a relationship that connects the true saturation     to the effective fluid modulus from seismic via statistical measures of the vertical spread of the porosity and saturation variations in the reservoir. These statistics can be extracted from the simulation model and if known, enable the new saturation law to deliver a significant improvement in accuracy when estimating     compared to other well-known laws. The relationship that has been developed also captures the effect of inter-bedded shales and can therefore be used to estimate true saturation in regions of the reservoir with moderate to low net-to-gross, provided the fraction of the shale component is known. In practice, the final choice of saturation law depends upon the reservoir information available, the assumptions that can be tolerated and the accuracy required in any particular reservoir characterization study.     

A survey of antifoulants in sediments from Ports and Marinas along the French Mediterranean coast

Due to deleterious effects on non-target organisms, the use of organotin compounds on boat hulls of small vessels (<25 m) has been widely prohibited. The International Maritime Organisation (IMO) resolved that the complete prohibition on organotin compounds acting as biocides in antifouling systems should commence in 2008. As a result of restrictions on the use of organotin based paints, other antifouling formulations containing organic biocides have been utilised. This survey was conducted to assess the contamination of replacement biocides in the marine environment following the ban of TBT-based paints. Surface sediments samples were collected in the major ports and marinas along the France Mediterranean coastline (Cote d’Azur) and analysed for organotin compounds, Irgarol 1051, Sea-nine 211^TM, Chlorothalonil, Dichlofluanid and Folpet. Every port and marina exhibited high levels of organotin compounds, with concentrations in sediments ranging from 37 ng Sn g⁻¹dry wt in Menton Garavan to over 4000 ng Sn g⁻¹dry wt close to the ship chandler within the port of Villefranche-sur-Mer. TBT degradation indexes suggested that fresh inputs are still made. Among the other antifoulants monitored, only Irgarol 1051 exhibited measurable concentrations in almost every port, with concentrations ranging from 40 ng g⁻¹dry wt (Cannes) to almost 700 ng g⁻¹dry wt (Villefranche-sur-Mer, ship chandler).     

Circulation of bubbly magma and gas segregation within tunnels of the potential Yucca Mountain repository

Following an intersection of rising magma with drifts of the potential Yucca Mountain nuclear waste repository, a pathway is likely to be established to the surface with magma flowing for days to weeks and affecting the performance of engineered structures located along or near the flow path. In particular, convective circulation could occur within magma-filled drifts due to the exsolution and segregation of magmatic gas. We investigate gas segregation in a magma-filled drift intersected by a vertical dyke by means of analogue experiments, focusing on the conditions of sustained magma flow. Degassing is simulated by electrolysis, producing micrometric bubbles in viscous mixtures of water and golden syrup, or by aerating golden syrup, producing polydisperse bubbly mixtures with 40% of gas by volume. The presence of exsolved bubbles induces a buoyancy-driven exchange flow between the dyke and the drift that leads to gas segregation. Bubbles segregate from the magma by rising and accumulating as a foam at the top of the drift, coupled with the accumulation of denser degassed magma at the base of the drift. Steady-state influx of bubbly magma from the dyke into the drift is balanced by outward flux of lighter foam and denser degassed magma. The length and time scales of this gas segregation are controlled by the rise of bubbles in the horizontal drift. Steady-state gas segregation would be accomplished within hours to hundreds of years depending on the viscosity of the degassed magma and the average size of exsolved gas bubbles, and the resulting foam would only be a few cm thick. The exchange flux of bubbly magma between the dyke and the drift that is induced by gas segregation ranges from 1 m³ s⁻¹, for the less viscous magmas, to 10⁻⁸ m³ s⁻¹, for the most viscous degassed magmas, with associated velocities ranging from 10⁻¹ to 10⁻⁹ m s⁻¹ for the same viscosity range. This model of gas segregation also predicts that the relative proportion of erupted degassed magma, that could potentially carry and entrain nuclear waste material towards the surface, would depend on the value of the dyke magma supply rate relative to the value of the gas segregation flux, with violent eruption of gassy as well as degassed magmas at relatively high magma supply rates, and eruption of mainly degassed magma by milder episodic Strombolian explosions at relatively lower supply rates.     

Contrasting types of metasomatism in dunite, wehrlite and websterite xenoliths from Kimberley, South Africa

Dunite, wehrlite and websterite are rare members of the mantle xenolith suite in the Kimberley kimberlites of the Kaapvaal Craton in southern Africa. All three types were originally residues of extensive melt extraction and experienced varying amounts and types of melt re-enrichment. The melt depletion event, dated by Re-Os isotope systematics at 2.9 Ga or older, is evidenced by the high Mg# (Mg/(Mg + Fe)) of silicate minerals (olivine (0.89-0.93); pyroxene (0.88-0.93); garnet (0.72-0.85)), high Cr# (Cr/(Cr + Al)) of spinel (0.53-0.84) and mostly low whole-rock SiO₂, CaO and Al₂O₃ contents. Shortly after melt depletion, websterites were formed by reaction between depleted peridotites and silica-rich melt (>60 wt% SiO₂) derived by partial melting of eclogite before or during cratonization. The melt-peridotite interaction converted olivine into orthopyroxene.All three xenolith types have secondary metasomatic clinopyroxene and garnet, which occur along olivine grain boundaries and have an amoeboid texture. As indicated by the preservation of oxygen isotope disequilibrium in the minerals and trace-element concentrations in clinopyroxene and garnet, this metasomatic event is probably of Mesozoic age and was caused by percolating alkaline basaltic melts. This melt metasomatism enriched the xenoliths in CaO, Al₂O₃, FeO and high-field-strength-elements, and might correspond to the Karoo magmatism at 200 Ma. The websterite xenoliths experienced both the orthoyproxene-enrichment and clinopyroxene-garnet metasomatic events, whereas dunite and wehrlite xenoliths only saw the later basaltic melt event, and may have been situated further away from the source of melt migration channels.