Identifying characteristics of charge transfer transitions in minerals

Criteria used to identify Fe²⁺-Fe³⁺ and Fe²⁺-Ti⁴⁺ intervalence charge transfer absorption bands in electronic spectra are reviewed and compared to the characteristics of unperturbed Fe²⁺ crystal field bands and those that are intensified by interaction with Fe³⁺. Band energy is the least definitive diagnostic criterion. Changes in band intensity with temperature are also of limited value. Large widths are the most reliable characteristic of charge transfer bands. New optical absorption spectra are presented for euclase, as well as 80 K spectra of rockbridgeite, babingtonite and lazulite. Comparison of optical spectra to magnetic susceptibility measurements for rockbridgeite and babingtonite provides support for recent theories regarding the effect of magnetic coupling on the variation of charge transfer intensity with temperature.     

The shape of Fraught – urban – rural – the nation-state: tensions and dynamics

I argue that the tension between cities and nation states go through the countryside, or rural areas, at least in the U.S. Further, cities are decidedly constrained in their abilities to effectuate many of the changes associated with them: addressing climate change, economic inequality and more. What is missing is the way in which rural alienation from economic prosperity plays out politically.     

A study case of bioluminescence potential dynamics in the Delaware Bay with observations and modeling

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Regional debris-flow and debris-flood frequency–magnitude relationships

Construction of frequency–magnitude (F–M) relationships of debris floods and debris flows is challenging because of few direct observations, discontinuous event occurrence, loss of field evidence, the difficulty of accessing the sediment archive and the challenge of finding suitable statistical methods to analyse the dataset. Consultants often face budget limitations that prohibit application of the full gamut of absolute dating methods, stratigraphic analysis and analytical tools necessary to fully resolve the F–M legacy. In some cases, F–M curves are needed for watersheds without local information, or where obtaining this information is prohibitively expensive. For such watersheds, the F–M relationship may be estimated where several F–M curves have already been assembled in a specific region. Individual F–M curves are normalized by fan area or fan volume, then stratified by process type and geomorphic activity level. This paper describes the development of regional F–M curves for debris flows in southwestern British Columbia and debris flows and debris floods in the Bow River valley near Canmore, Alberta. We apply the regional relationships to other cases in Canada and the United States and demonstrate that the method can be globalized. The regional approach is compared to cases where detailed F–M relationships have been established by other means. Strong negative deviations from the regional debris-flow or debris-flood magnitude trends could signal inherent watershed stability, while strong positive deviations could signal extraordinary landslide processes, or suggest that the fan may be largely of paraglacial origin. We highlight some of these outlying cases and develop a method whereby the regional curves can be meaningfully adjusted, or reliance can be placed on lower or upper confidence bounds of the F–M curves. We caution against the indiscriminate use of the regionally based F–M curves, especially in watersheds where multiple geomorphic processes are active. © 2020 John Wiley & Sons, Ltd.     

The planet formation imager

The Planet Formation Imager (PFI, www.planetformationimager.org) is a next-generation infrared interferometer array with the primary goal of imaging the active phases of planet formation in nearby star forming regions. PFI will be sensitive to warm dust emission using mid-infrared capabilities made possible by precise fringe tracking in the near-infrared. An L/M band combiner will be especially sensitive to thermal emission from young exoplanets (and their disks) with a high spectral resolution mode to probe the kinematics of CO and H₂O gas. In this paper, we give an overview of the main science goals of PFI, define a baseline PFI architecture that can achieve those goals, point at remaining technical challenges, and suggest activities today that will help make the Planet Formation Imager facility a reality.     

Water isotopic composition traces source and dynamics of water supply in a semi-arid agricultural landscape

Changes in seasonality and form of precipitation alter the structure and function of grassland and steppe ecosystems and pose challenges for land management and crop production in regions like the Northern Great Plains, North America. This research uses isotopic composition of water (δ¹⁸O and δ²H) to explore the sources and fate of soil water in lower-elevation agricultural areas of the Judith River watershed, in the headwaters of the Missouri River, USA. Extensive non-irrigated cereal crop production in this area occurs on well-drained soils and depends on careful water management. Our observations indicate that colder precipitation contributes isotopically distinct water to cultivated terrace soils relative to downgradient groundwaters and streams. Riparian waters also exhibit a higher fraction of contributions from colder precipitation relative to terrace groundwaters and streams. Apparent contributions from colder precipitation in terrace and riparian soil waters suggest that snowmelt is a key component of the water supply to these systems. Riparian waters also show evidence of evaporation suggesting that water spends sufficient time in some ponds and open channels in the riparian corridor to reflect fractionation by evaporation. The evolution of water isotopic composition from soils to shallow aquifers to stream corridors indicates source water partitioning as precipitation moves through this semi-arid agricultural landscape. The apparent mixing processes evident in this evolution reveal source water dynamics that are necessary to understand plant transpiration, solute processing, and contaminant leaching processes.     

The effect of tidal forcing on biogeochemical processes in intertidal salt marsh sediments

Background  

Early diagenetic processes involved in natural organic matter (NOM) oxidation in marine sediments have been for the most part characterized after collecting sediment cores and extracting porewaters. These techniques have proven useful for deep-sea sediments where biogeochemical processes are limited to aerobic respiration, denitrification, and manganese reduction and span over several centimeters. In coastal marine sediments, however, the concentration of NOM is so high that the spatial resolution needed to characterize these processes cannot be achieved with conventional sampling techniques. In addition, coastal sediments are influenced by tidal forcing that likely affects the processes involved in carbon oxidation.