Runoff evolution in the Swiss Alps: projections for selected high‐alpine catchments based on ENSEMBLES scenarios

The Alps are often referred to as the ‘water tower of Europe’. In Switzerland, many branches of the economy, especially the hydropower industry, are closely linked to and dependent on the availability of water. Assessing the impact of climate change on streamflow runoff is, thus, of great interest. Major efforts have already been made in this respect, but the analyses often focus on individual catchments and are difficult to intercompare. In this article, we analysed nine high‐alpine catchments spread over the Swiss Alps, selected for their relevance to a wide range of morphological characteristics. Runoff projections were carried out until the end of the current century by applying the Glacier Evolution Runoff Model (GERM) and climate scenarios generated in the framework of the ENSEMBLES project. We focused on assessing the uncertainty induced by the unknown climate evolution and provided general, statistically based statements, which should be useful as a ‘rule of thumb’ for analyses addressing questions related to water management. Catchments with a high degree of glacierization will undergo the largest changes. General statements about absolute variations in discharge are unreliable, but an overall pattern, with an initial phase of increased annual discharge, followed by a phase with decreasing discharge, is recognizable for all catchments with a significant degree of glacierization. In these catchments, a transition from glacial and glacio‐nival regime types to nival will occur. The timing of maximal annual runoff is projected to occur before 2050 in all basins. The time of year with maximal daily discharges is expected to occur earlier at a rate of 4·4 ± 1·7 days per decade. Compared to its present level, the contribution of snow‐ and icemelt to annual discharge is projected to drop by 15 to 25% until the year 2100. Copyright © 2011 John Wiley & Sons, Ltd.     

Rapid Analysis of 1,4‐Dioxane in Groundwater by Frozen Micro‐Extraction with Gas Chromatography/Mass Spectrometry

An innovative micro‐extraction of aqueous samples coupled with gas chromatography/mass spectrometry in selected ion‐monitoring mode (GC/MS‐SIM) was developed to selectively analyze for 1,4‐dioxane with low part‐per‐billion detection sensitivity. Recoveries of 1,4‐dioxane ranged from 93% to 117% for both spiked laboratory reagent water and natural groundwater matrices, the later having elevated organic carbon content (8.34 ± 0.31 mg/L as total organic carbon). We observed that freezing the aqueous sample along with the extraction solvent enhanced the extraction efficiency, minimized physical interferences, and improved sensitivity resulting in a limit of detection for 1,4‐dioxane to approximately 1.6 μg/L. This method substantially reduces the labor, time, reagents and cost, and uses instruments that are commonly found in analytical laboratories. This method requires a relatively small sample volume (200 μL), and can be considered a green analytical method as it minimizes the use of toxic solvents and the associated laboratory wastes.     

Combined model state and parameter estimation with an ensemble Kalman filter in a North Sea station 1-D numerical model

The combined estimation of model state and parameters is investigated by using an ensemble Kalman filter in a 1-D numerical study of the temperature profile at a North Sea station located at 55°30??North and 0°55??East. This simplified model implementation allows to test many configurations for the sampling of the model error for the model state as well as for the parameters. Temperature profiles from thermistor data are assimilated. The influence of a vertically or non-vertically correlated model error is examined through the computation of correlation coefficients, root mean square errors, and model bias. As the CS station is located in the North Sea region stratified in summer, vertically non-correlated model error terms have a slight positive impact on the assimilative runs. The benefit of the combined estimation of the model state and parameters is examined by comparison of a simulation where the model parameters are not adjusted to simulations with the combined estimation of the model state either with one parameter or with a set of parameters related to the surface heat exchange. The optical attenuation coefficient, the sensible, and latent heat exchange coefficients are considered. The best results are obtained when a set of parameters are simultaneously adjusted.     

Arsenic and Antimony in Groundwater Flow Systems: A Comparative Study

Arsenic (As) and antimony (Sb) concentrations and speciation were determined along flow paths in three groundwater flow systems, the Carrizo Sand aquifer in southeastern Texas, the Upper Floridan aquifer in south-central Florida, and the Aquia aquifer of coastal Maryland, and subsequently compared and contrasted. Previously reported hydrogeochemical parameters for all three aquifer were used to demonstrate how changes in oxidation–reduction conditions and solution chemistry along the flow paths in each of the aquifers affected the concentrations of As and Sb. Total Sb concentrations (Sb_T) of groundwaters from the Carrizo Sand aquifer range from 16 to 198 pmol kg⁻¹; in the Upper Floridan aquifer, Sb_T concentrations range from 8.1 to 1,462 pmol kg⁻¹; and for the Aquia aquifer, Sb_T concentrations range between 23 and 512 pmol kg⁻¹. In each aquifer, As and Sb (except for the Carrizo Sand aquifer) concentrations are highest in the regions where Fe(III) reduction predominates and lower where SO₄ reduction buffers redox conditions. Groundwater data and sequential analysis of the aquifer sediments indicate that reductive dissolution of Fe(III) oxides/oxyhydroxides and subsequent release of sorbed As and Sb are the principal mechanism by which these metalloids are mobilized. Increases in pH along the flow path in the Carrizo Sand and Aquia aquifer also likely promote desorption of As and Sb from mineral surfaces, whereas pyrite oxidation mobilizes As and Sb within oxic groundwaters from the recharge zone of the Upper Floridan aquifer. Both metalloids are subsequently removed from solution by readsorption and/or coprecipitation onto Fe(III) oxides/oxyhydroxides and mixed Fe(II)/Fe(III) oxides, clay minerals, and pyrite. Speciation modeling using measured and computed Eh values predicts that Sb(III) predominate in Carrizo Sand and Upper Floridan aquifer groundwaters, occurring as the Sb(OH)₃⁰ species in solution. In oxic groundwaters from the recharge zones of these aquifers, the speciation model suggests that Sb(V) occurs as the negatively charged Sb(OH)₆⁻ species, whereas in sufidic groundwaters from both aquifers, the thioantimonite species, HSb₂S₄ ⁻ and Sb₂S₄ ²⁻, are predicted to be important dissolved forms of Sb. The measured As and Sb speciation in the Aquia aquifer indicates that As(III) and Sb(III) predominate. Comparison of the speciation model results based on measured Eh values, and those computed with the Fe(II)/Fe(III), S(-II)/SO₄, As(III)/As(V), and Sb(III)/Sb(V) couples, to the analytically determined As and Sb speciation suggests that the Fe(II)/Fe(III), S(-II)/SO₄ couples exert more control on the in situ redox condition of these groundwaters than either metalloid redox couple.     

The American Crocodile in Biscayne Bay,Florida

Intensive crocodile monitoring programs conducted during the late 1970s and early 1980s in southern Florida resulted in an optimistic outlook for recovery of the protected species population. However, some areas with suitable crocodile habitat were not investigated, such as Biscayne Bay and the mainland shorelines of Barnes and Card Sounds. The objective of our study was to determine status and habitat use of crocodiles in the aforementioned areas. Spotlight and nesting surveys were conducted from September 1996 to December 2005. The results revealed annual increases in the number of crocodiles. Crocodiles preferred protected habitats such as canals and ponds. Fewer crocodiles were observed in higher salinity water. The distribution and abundance of crocodilians in estuaries is directly dependent on timing, amount, and location of freshwater delivery, providing an opportunity to integrate habitat enhancement with ongoing ecosystem restoration and management activities.     

Modeling studies of the bioluminescence potential dynamics in a high Arctic fjord during polar night

Ocean Dynamics - During polar nights in January 2012 and 2017, significantly higher bioluminescence (BL) potential emissions in the upper 50 m were observed in the fjord Rijpfjorden...     

Biostratigraphy of large benthic foraminifera from Hole U1468A (Maldives): a CT-scan taxonomic approach

Large benthic foraminifera are important components of tropical shallow water carbonates. Their structure, developed to host algal symbionts, can be extremely elaborate and presents stratigraphically-significant evolutionary patterns. Therefore their distribution is important in biostratigraphy, especially in the Indo-Pacific area. To provide a reliable age model for two intervals of IODP Hole U1468A from the Maldives Inner-Sea, large benthic foraminifera have been studied with computed tomography. This technique provided 3D models ideal for biometric-based identifications, allowing the upper interval to be placed in the late middle-Miocene and the lower interval in the late Oligocene.