Earthquakes in Switzerland and surrounding regions during 2004

This report of the Swiss Seismological Service summarizes the seismic activity in Switzerland and surrounding regions during 2004. During this period, 677 earthquakes and 96 quarry blasts were detected and located in the region under consideration. With 22 events with M_L≥2.5, the seismic activity in the year 2004 was close to the average over the last 30 years. As in previous years, most of the activity was concentrated in the Valais and in Graubünden. In addition, several moderate earthquakes occurred in the lower crust below the northern Alpine foreland. Unusual was that five earthquakes were sufficiently strong to cause ground shaking of intensity IV over large portions of the territory. Two were located in Switzerland (Liestal, M_L 3.8, and Brugg, M_L 4.0). The epicenters of the other three strong events were located outside Switzerland (Besan?on in the French Jura, M_L 4.8, Waldkirch in southern Germany, M_L 5.1, and Lago di Garda in northern Italy, M_L 5.3).     

Rare earth element partitioning between titanite and silicate melts: Henry’s law revisited

We present detailed experimental results on the partitioning of rare earth elements (REE) between titanite and a range of different silicate melts. Our results show that Henry’s law of trace element partitioning depends on bulk composition, the available partners for heterovalent substitution, crystal composition, and melt composition. We illustrate that the partition coefficients for Sm depend very strongly on the bulk concentration of Sm in the system. The substitution mechanism, by which rare earth elements are incorporated into the crystal structure, plays an important role for trace element partitioning and also for the onset of Henry’s law. Our data show that there are clear differences between substitution mechanisms of major elements compared to elements which are present only as traces. Our experiments also clearly show that the onset of Henry’s law depends on the concentrations of the sum of all trace elements which are incorporated into the crystal by the same substitution mechanism. For geochemical modelling of magmatic processes involving titanite, and indeed other accessory phases, it is of crucial importance to first evaluate whether the REE, and other trace elements, are present as traces or as major elements, only then appropriate D values may be chosen.     

Earthquakes in Switzerland and surrounding regions during 2012

This report of the Swiss Seismological Service summarizes the seismic activity in Switzerland and surrounding regions during 2012. During this period, 497 earthquakes and 88 quarry blasts were detected and located in the region under consideration. With a total of only 13 events with M_L ≥ 2.5, the seismic activity in the year 2012 was far below the average over the previous 37 years. Most noteworthy were the earthquake sequence of Filisur (GR) in January with two events of M_L 3.3 and 3.5, the M_L 4.2 and M_L 3.5 earthquakes at a depth of 32 km below Zug in February and the M_L 3.6 event near Vallorcine in October. The epicentral intensity of the M_L 4.2 event close to Zug was IV, with a maximum intensity of V reached in a few areas, probably due to site amplification effects.     

Timing of rockfalls in the Mont Blanc massif (Western Alps): evidence from surface exposure dating with cosmogenic <Superscript>10</Superscript>Be

Rockfalls and rock avalanches are a recurrent process in high mountain areas like the Mont Blanc massif. These processes are surveyed due to the hazard they present for infrastructure and alpinists. While rockfalls and rock avalanches have been documented for the last 150 years, we know very little about their frequency since the Last Glacial Maximum (LGM). In order to improve our understanding, it is imperative to date them on a longer timescale. A pilot campaign using Terrestrial Cosmogenic Nuclide (TCN) dating of five samples was carried out in 2006 at the Aiguille du Midi (3842 m a.s.l.). In 2011, a larger scale study (20 samples) was carried out in five other test sites in the Mont Blanc massif. This paper presents the exposure ages of the 2011 TCN study as well as the updated exposure ages of the 2006 study using newer TCN dating parameters. Most of these exposure ages lie within the Holocene but three ages are Pleistocene (59.87?±?6.10 ka for the oldest). A comparison of these ages with air temperature and glacier cover proxies explored the possible relationship between the most active rockfall periods and the warmest periods of the Holocene: two clusters of exposure ages have been detected, corresponding to the Middle Holocene (8.2–4.2 ka) and the Roman Warm Period (c. 2 ka) climate periods. Some recent rockfalls have also been dated (<?0.56 ka).     

Thermal history of Northwest Africa 5073––A coarse‐grained Stannern‐trend eucrite containing cm‐sized pyroxenes and large zircon grains

Abstract– We report on the bulk chemical composition, petrology, oxygen isotopic composition, trace element composition of silicates, and degree of self‐irradiation damage on zircon grains of the eucrite Northwest Africa (NWA) 5073 to constrain its formation and postcrystallization thermal history, and to discuss their implications for the geologic history of its parent body. This unequilibrated and unbrecciated meteorite is a new member of the rare Stannern‐trend eucrites. It is mainly composed of elongated, zoned pyroxene phenocrysts up to 1.2 cm, plagioclase laths up to 0.3 cm in length, and is rich in mesostasis. The latter contains zircon grains up to 30 μm in diameter, metal, sulfide, tridymite, and Ca‐phosphates. Textural observations and silicate compositions, coupled with the occurrence of extraordinary Fe‐rich olivine veins that are restricted to large pyroxene laths, indicate that NWA 5073 underwent a complex thermal history. This is also supported by the annealed state of zircon grains inferred from μ‐Raman spectroscopic measurements along with U and Th data obtained by electron probe microanalyses.     

Earthquakes in Switzerland and surrounding regions during 2009

This report of the Swiss Seismological Service summarizes the seismic activity in Switzerland and surrounding regions during 2009. During this period, 450 earthquakes and 68 quarry blasts were detected and located in the region under consideration. The three strongest events occurred about 15 km NW of Basel in southern Germany (M_L 4.2), near Wildhaus in the Toggenburg (M_L 4.0) and near Bivio in Graubünden (M_L 3.5). Although felt by the population, they were not reported to have caused any damage. With a total of 24 events with M_L ≥ 2.5, the seismic activity in the year 2009 was close to the average over the previous 34 years.     

ATR-FTIR spectroscopic study of the adsorption of desferrioxamine B and aerobactin to the surface of lepidocrocite (γ-FeOOH)

The adsorption of two model siderophores, desferrioxamine B (DFOB) and aerobactin, to lepidocrocite (γ-FeOOH) was investigated by attenuated total reflection infrared spectroscopy (ATR-FTIR). The adsorption of DFOB was investigated between pH 4.0 and 10.6. The spectra of adsorbed DFOB indicated that two to three hydroxamic acid groups of adsorbed DFOB were deprotonated in the pH range 4.0-8.2. Deprotonation of hydroxamic acid groups of adsorbed DFOB at pH values well below the first acid dissociation constant of solution DFOB species (pK_a = 8.3) and well below the point of zero charge of lepidocrocite (pH_PZC = 7.4) suggested that the surface speciation at the lower end of this pH range (pH 4) is dominated by a surface DFOB species with inner-sphere coordination of two to three hydroxamic acids groups to the surface. Maximum adsorption of DFOB occurred at approximately pH 8.6, close to the first pK_a value of the hydroxamic acid groups, and decreased at lower and higher pH values.The spectra of adsorbed aerobactin in the pH range 3-9 indicated at least three different surface species. Due to the small spectral contributions of the hydroxamic acid groups of aerobactin, the interactions of these functional groups with the surface could not be resolved. At high pH, the spectral similarity of adsorbed aerobactin with free aerobactin deprotonated at the carboxylic acid groups indicated outer-sphere complexation of the carboxylate groups. With decreasing pH, a significant peak shift of the asymmetric carboxylate stretch vibration was observed. This finding suggested that the (lateral) carboxylic acid groups are coordinated to the surface either as inner-sphere complexes or as outer-sphere complexes that are strongly stabilized at the surface by hydrogen bonding at low pH.     

On the variability of the surface environment response to synoptic forcing over complex terrain: a multivariate data analysis approach

Synoptic climatology relates the atmospheric circulation with the surface environment. The aim of this study is to examine the variability of the surface meteorological patterns, which are developing under different synoptic scale categories over a suburban area with complex topography. Multivariate Data Analysis techniques were performed to a data set with surface meteorological elements. Three principal components related to the thermodynamic status of the surface environment and the two components of the wind speed were found. The variability of the surface flows was related with atmospheric circulation categories by applying Correspondence Analysis. Similar surface thermodynamic fields develop under cyclonic categories, which are contrasted with the anti-cyclonic category. A strong, steady wind flow characterized by high shear values develops under the cyclonic Closed Low and the anticyclonic H–L categories, in contrast to the variable weak flow under the anticyclonic Open Anticyclone category.