Heterogeneous distribution of phosphorus in olivine from otherwise well-equilibrated spinel peridotite xenoliths and its implications for the mantle geochemistry of lithium

The major- and trace-element abundances of the coexisting phases of four metasomatized spinel peridotite xenoliths from the Anakies locality (SE Australia) were determined by electron microprobe and laser-ablation ICP-MS. The compositions of all phases are remarkably homogeneous, with the exception of phosphorus (P), lithium (Li) and sodium (Na) in olivine. These three elements are enriched in large parts of most olivine crystals due to a second metasomatic episode. Apart from these elements, all phases are in mutual equilibrium with respect to both their major- and trace-element compositions. Li and Na show a strong correlation with P in olivine, although molar Li + Na are an order of magnitude less than molar P, indicating that the substitution mechanism of these elements is more complex than the simple charge-balanced coupled exchange ^IVSi⁴⁺ + ^VI(FeMg)²⁺ = ^IVP⁵⁺ + ^VI(LiNa)⁺. We suggest that Li and Na are decorating octahedral-site cation vacancies formed by the original incorporation of P. Elemental maps revealed that the P zoning patterns are concentric in a few large olivine porphyroblasts, but form irregular patches in most crystals. This distribution of P is proposed to be the result of a two-stage process, whereby the initial concentric zoning, caused by its exceptionally sluggish diffusion after metasomatic influx, is broken up by extensive sub-solidus deformation and recrystallization, attesting to large grain-scale strains even within the lithosphere. Such strains must be an efficient means of ensuring trace-element equilibrium during partial melting. The association of Li with P in olivine may help to explain the variability of Li abundances in mantle minerals and to interpret Li diffusion experiments and Li isotopic fractionation.     

Estimating water balance components in irrigated agriculture using a combined approach of soil moisture and energy balance monitoring,and numerical modelling

Information on water balance components such as evapotranspiration and groundwater recharge are crucial for water management. Due to differences in physical conditions, but also due to limited budgets, there is not one universal best practice, but a wide range of different methods with specific advantages and disadvantages. In this study, we propose an approach to quantify actual evapotranspiration, groundwater recharge and water inflow, i.e. precipitation and irrigation, that considers the specific conditions of irrigated agriculture in warm, arid environments. This approach does not require direct measurements of precipitation or irrigation quantities and is therefore suitable for sites with an uncertain data basis. For this purpose, we combine soil moisture and energy balance monitoring, remote sensing data analysis and numerical modelling using Hydrus. Energy balance data and routine weather data serve to estimate ET₀. Surface reflectance data from satellite images (Sentinel-2) are used to derive leaf area indices, which help to partition ET₀ into energy limited evaporation and transpiration. Subsequently, first approximations of water inflow are derived based on observed soil moisture changes. These inflow estimates are used in a series of forward simulations that produce initial estimates of drainage and ET_act, which in turn help improve the estimate of water inflow. Finally, the improved inflow estimates are incorporated into the model and then a parameter optimization is performed using the observed soil moisture as the reference figure. Forward simulations with calibrated soil parameters result in final estimates for ET_act and groundwater recharge. The presented method is applied to an agricultural test site with a crop rotation of cotton and wheat in Punjab, Pakistan. The final model results, with an RMSE of 2.2% in volumetric water content, suggest a cumulative ET_act and groundwater recharge of 769 and 297 mm over a period of 281 days, respectively. The total estimated water inflow accounts for 946 mm, of which 77% originates from irrigation.     

A unique aspect of ballast water management requirements - The same location concept

Under certain circumstances vessels do not need to meet ballast water management requirements as stated in the International Convention for the Management and Control of Ballast Water and Sediments (BWM Convention). Besides exceptions to ensure e.g., (a) the safety of a ship, (b) discharge of ballast water for the purpose of avoiding or minimizing pollution incidents, (c) uptake and discharge on high seas of the same ballast water, the same location concept comes into play as ballast water discharges from a ship at the same location where it was taken up is also excepted from BWM requirements. The term same location was not defined in this instrument, hence it is exposed to different interpretations (e.g., a terminal, a port, a larger area where two or more ports may be located). As the BWM Convention is an instrument with biological meaning, the authors recommend a biologically meaningful definition of the same location in this contribution.     

Microphysical and chemical characteristics of cloud droplet residuals and interstitial particles in continental stratocumulus clouds

During June and July 2003 the Sources and Origins of Atmospheric Cloud Droplets experiment (SOACED) was carried out on a mountain-top site in central Sweden. The main objective of the experiment was to characterise the microphysical and chemical properties of cloud droplet residuals and interstitial aerosol particles in continental clouds and to understand the processes controlling cloud properties at this location.Interstitial and residual aerosol size distributions, cloud liquid water content and species- and size-resolved aerosol mass concentrations are the main variables employed to address questions pertaining to the cloud droplet number concentration and scavenging efficiency during a stratocumulus cloud event observed on July 28, 2003. In this cloud event, about 56% of the aerosol mass was associated with organic species, whilst SO₄ accounted for 23% and NH₄ for 14%. NO₃ and Cl made up about 7% of the total mass.The partitioning of the aerosol particles between cloud droplets and interstitial air has been studied in terms of their microphysical properties. The scavenging efficiency, defined as the fraction of particles activated into cloud elements compared to the total amount of particles, was investigated as a function of size. The scavenging efficiency curves displayed different shapes during the cloud event, from an S-shaped curve, with low scavenging efficiency in the Aitken mode and larger scavenging efficiency in the accumulation mode, to more unusual shapes where Aitken-mode particles were either solely activated or activated in addition to accumulation-mode particles.This study suggests that alterations of the aerosol chemical composition occurred during the measurement period, changing the hygroscopic nature of the CCN and decreasing their activation diameter. It is also hypothesized that entrainment of drier air aloft may have introduced inhomogeneities in the supersaturation field and modified the S-shaped scavenging curves.     

Towards Adaptive Grids for Atmospheric Boundary-Layer Simulations

We present a proof-of-concept for the adaptive mesh refinement method applied to atmospheric boundary-layer simulations. Such a method may form an attractive alternative to static grids for studies on atmospheric flows that have a high degree of scale separation in space and/or time. Examples include the diurnal cycle and a convective boundary layer capped by a strong inversion. For such cases, large-eddy simulations using regular grids often have to rely on a subgrid-scale closure for the most challenging regions in the spatial and/or temporal domain. Here we analyze a flow configuration that describes the growth and subsequent decay of a convective boundary layer using direct numerical simulation (DNS). We validate the obtained results and benchmark the performance of the adaptive solver against two runs using fixed regular grids. It appears that the adaptive-mesh algorithm is able to coarsen and refine the grid dynamically whilst maintaining an accurate solution. In particular, during the initial growth of the convective boundary layer a high resolution is required compared to the subsequent stage of decaying turbulence. More specifically, the number of grid cells varies by two orders of magnitude over the course of the simulation. For this specific DNS case, the adaptive solver was not yet more efficient than the more traditional solver that is dedicated to these types of flows. However, the overall analysis shows that the method has a clear potential for numerical investigations of the most challenging atmospheric cases.     

Lagrangian Particle Dispersion Models in the Grey Zone of Turbulence: Adaptations to FLEXPART-COSMO for Simulations at 1 km Grid Resolution

Boundary-Layer Meteorology - Lagrangian particle dispersion models (LPDMs) are frequently used for regional-scale inversions of greenhouse gas emissions. However, the turbulence parameterizations...     

The impact of internal waves on upper continental slopes: insights from the Mozambican margin (southwest Indian Ocean)

Evidences of sedimentation affected by oceanic circulation, such as nepheloid layers and contourites are often observed along continental slopes. However, the oceanographic processes controlling sedimentation along continental margins remain poorly understood. Multibeam bathymetry and high-resolution seismic reflection data revealed a contourite depositional system in the Mozambican upper continental slope composed of a contourite terrace (a surface with a gentle seaward slope dominated by erosion) and a plastered drift (a convex-shape sedimentary deposit). A continuous alongslope channel and a field of sand dunes (mainly migrating upslope), formed during Holocene, were identified in the contourite terrace at the present seafloor. Seismic reflection data of the water column show internal waves and boluses propagating in the pycnocline near the upper slope. The channel and the dunes are probably the result of the interaction of the observed internal waves with the seafloor under two different conditions. The alongslope channel is located in a zone where intense barotropic tidal currents may arrest internal solitary waves, generating a hydraulic jump and focused erosion. However, upslope migrating dunes may be formed by bottom currents induced by internal solitary waves of elevation propagating landwards in the pycnocline. These small-scale sedimentary features generated by internal waves are superimposed on large-scale contouritic deposits, such as plastered drifts and contourite terraces, which are related to geostrophic currents. These findings provide new insights into the oceanographic processes that control sedimentation along continental margins that will help interpretation of palaeoceanographic conditions from the sedimentary record. © 2020 The Authors. Earth Surface Processes and Landforms published by John Wiley & Sons Ltd     

Geschichte und Ursachen des Röhrichtrückgangs am Ammersee (Deutschland)

The development of aquatic reed stands at Lake Ammersee was documented by using vertical airborne photographs which were taken during four partial and five complete flights beginning in 1944. A dramatic decline of reed, especially of those parts which stood in deep water, was demonstrated. Between the years 1963 and 1969 60% and until 1992 another 30% of the Phragmitetum disappeared. Only at the east bank did the lake reed beds slightly expand.The examination of possible factors affecting the development of reed at Lake Ammersee lead to the following scenario: Until 1940 reed stands at Lake Ammersee spread and covered large aquatic areas. Only the east bank of the lake, where the influence of wind and waves was high, and banks near towns and recreation areas remained uncovered. Since the regulation of the River Ammer between 1920 and 1938 flood occurrence increased enormously. The flood disaster of the year 1965 coincided with the period of the highest rate of reed decline. The peak of eutrophication in the lake was reached in 1975. Huge carpets of green algae caused further retreat of reeds.At the present time recovery is not possible because of the negative influence of human recreation and of reed consuming waterfowl. Interestingly enough an expansion of reed has been observed at the east bank of Lake Ammersee at places were there was no Phragmites previously.     

SIMS studies of Allende projectiles fired into Stardust‐type aluminum foils at 6 km/sec

Abstract— We have explored the feasibility of C, N, and O isotopic measurements by NanoSIMS and of elemental abundance determinations by time‐of‐flight secondary ion mass spectrometry (TOF‐SIMS) on residues of Allende projectiles that impacted Stardust‐type aluminum foils in the laboratory at 6 km/sec. These investigations are part of a consortium study aimed at providing the foundation for the characterization of matter associated with microcraters that were produced during the encounter of the Stardust space probe with comet 81P/Wild‐2. Eleven experimental impact craters were studied by NanoSIMS and eighteen by TOF‐SIMS. Crater sizes were between 3 and 190 μm. The NanoSIMS measurements have shown that the crater morphology has only a minor effect on spatial resolution and on instrumental mass fractionation. The achievable spatial resolution is always better than 200 nm, and C and O isotopic ratios can be measured with a precision of several percent at a scale of several 100 nm, which is the typical size of presolar grains. This clearly demonstrates that presolar matter, provided it survives the impact into the aluminum foil partly intact, is recognizable even if embedded in material of solar system origin. TOF‐SIMS studies are restricted to materials from the crater rim. The element ratios of the major rock‐forming elements in the Allende projectiles are well‐characterized by the TOF‐SIMS measurements, indicating that fractionation of those elements during impact can be expected to be negligible. This permits chemical information on the type of impactor material to be obtained. For any more detailed assignments to specific chondrite groups, however, information on the abundances of the light elements, especially C, is crucial. This information could not be obtained in the present study due to unavoidable contamination during impact experiments.