Spectral characteristics of lunar impact melts and inferred mineralogy

Abstract– Two suites of lunar impact melt samples have been measured in NASA’s Reflectance Experiment Laboratory (RELAB) at Brown University. Suite 1 comprises seven Apollo 17 crystalline impact melt breccias and seven quenched glass equivalents. Suite 2 is made up of 15 additional impact melt samples (from Apollo 12, 15, 16, and 17) which exhibit a range of textures and compositions related to cooling conditions and glass abundance. A few of these samples have cooled slowly and fully crystallized, and thus have the same spectral properties as igneous rocks of similar texture and composition; they cannot be uniquely distinguished without geologic context. However, most of the impact melts and melt breccias contain either quantities of quenched glass and/or have developed microcrystalline nonequilibrium textures with well‐defined, diagnostic spectral properties. The microcrystalline textures are associated with a distinctive 600 nm absorption feature, apparently due to submicroscopic ilmenite inclusions in a transparent host (typically fine‐grained plagioclase). The reflectance properties of these lunar sample suites contribute to and constrain the identification and characterization of impact melts in remote sensing data.     

Ecohydrological responses to surface flow across borders: Two decades of changes in vegetation greenness and water use in the riparian corridor of the Colorado River delta

Hydrological and bioclimatic processes that lead to drought may stress plants and wildlife, restructure plant community type and architecture, increase monotypic stands and bare soils, facilitate the invasion of non-native plant species and accelerate soil erosion. Our study focuses on the impact of a paucity of Colorado River surface flows from the United States (U.S.) to Mexico. We measured change in riparian plant greenness and water use over the past two decades using remotely sensed measurements of vegetation index (VI), evapotranspiration (ET) and a new annualized phenology assessment metric (PAM) for ET. We measure these long-term (2000–2019) metrics and their short-term (2014–2019) response to an environmental pulse flow in 2014, as prescribed under Minute 319 of the 1944 Water Treaty between the two nations. In subsequent years, small-directed flows were provided to restoration areas under Minute 323. We use 250 m MODIS and 30 m Landsat imagery to evaluate three vegetation indices (NDVI, EVI, EVI2). We select EVI2 to parameterize an optical-based ET algorithm and test the relationship between ET from Landsat and MODIS by regression approaches. Our analyses show significant decreases in VIs and ET for both the 20-year and post-pulse 5-year periods. Over the last 20 years, EVI _Landsat declined 34% (30% by EVI_MODIS) and ET_Landsat-EVI declined 38% (27% by ET_MODIS-EVI), overall ca. 1.61 mm/day or 476 mm/year drop in ET; using PAM ET_Landsat-EVI the drop was from 1130 to 654 mm/year. Over the 5 years since the 2014 pulse flow, EVI_Landsat declined 20% (13% by EVI_MODIS) and ET_Landsat-EVI declined 23% (4% by ET_MODIS-EVI) with a 0.77 mm/day or a 209 mm/year 5-year drop in ET; using PAM ET_Landsat-EVI the drop was from 863 to 654 mm/year. Data and change maps show the pulse flow contributed enough water to slow the rate of loss, but only for the very short-term (1–2 years). These findings are critically important as they suggest further deterioration of biodiversity, wildlife habitat and key ecosystem services due to anthropogenic diversions of water in the U.S. and Mexico and from land clearing, fires and plant-related drought which affect hydrological processes.     

GGR Critical Review of Analytical Developments in 2006–2007

In 2005 the Geostandards and Geoanalytical Research editorial team, in the true spirit of scientific endeavour, embarked on an experiment of our own. We decided to trial a new kind of review, somewhat different from those more typically observed in journals, and one that would provide readers with a summary of analytical developments across a broad range of topics appropriate to the Earth sciences. The first contribution of this kind appeared in 2005, and reported on developments in 2003 (Hergt et al. 2005). The second, this time a biennial review, was published in 2006 and reported on highlights of the 2004 and 2005 literature (Hergt et al. 2006). Based on reprint requests, positive remarks at conferences and strong citations we consider the experiment a resounding success and proudly present here the third in this series. This comprises six individual review sections that cover the main analytical technologies and topical application fields in geoanalysis and geochemistry, including geological and environmental reference materials, ICP‐thermal and secondary ionisation‐mass spectrometry, as well as neutron activation analysis, X‐ray fluorescence and atomic absorption spectrometry.     

Automated facies identification by Direct Push-based sensing methods (CPT,HPT) and multivariate linear discriminant analysis to decipher geomorphological changes and storm surge impact on a medieval coastal landscape

In ad 1362, a major storm surge drowned wide areas of cultivated medieval marshland along the north-western coast of Germany and turned them into tidal flats. This study presents a new methodological approach for the reconstruction of changing coastal landscapes developed from a study site in the Wadden Sea of North Frisia. Initially, we deciphered long-term as well as event-related short-term geomorphological changes, using a geoscientific standard approach of vibracoring, analyses of sedimentary, geochemical and microfaunal palaeoenvironmental parameters and radiocarbon dating. In a next step, Direct Push (DP)-based Cone Penetration Testing (CPT) and the Hydraulic Profiling Tool (HPT) were applied at vibracore locations to obtain in situ high-resolution stratigraphic data. In a last step, multivariate linear discriminant analysis (LDA) was successfully applied to efficiently identify different sedimentary facies (e.g., fossil marsh or tidal flat deposits) from the CPT and HPT test dataset, to map the facies' lateral distribution, also in comparison to reflection seismic measurements and test their potential to interpolate the borehole and CPT/HPT data. The training dataset acquired for the key site from coring and DP sensing finally allows an automated facies classification of CPT/HPT data obtained elsewhere within the study area. The new methodological approach allowed a detailed reconstruction of the local coastal landscape development in the interplay of natural marsh formation, medieval land reclamation and storm surge-related land losses.     

Fossa Carolina: The First Attempt to Bridge the Central European Watershed—A Review,New Findings,and Geoarchaeological Challenges

The Central European watershed passes through the southern Franconian Jura in Bavaria, Germany. This principal watershed divides the Rhine/Main catchment and the Danube catchment. In the early Middle Ages, when ships were an important means of transportation, Charlemagne decided to connect these catchments by the construction of a canal known as the Fossa Carolina. In this paper, we present for the first time ¹⁴C data from the Fossa Carolina fill and document a high‐resolution stratigraphic record of the Carolingian and post‐Carolingian trench infilling. Our results provide clear evidence for peat layers in different levels of the trench infill, suggesting a chain of ponds. However, the majority of these peat layers yield mid‐Medieval and younger ages. The period of major peat growth was during the Medieval climatic optimum. Therefore, our preliminary results do not prove the use of the trench during Carolingian times. However, first results from the reconstruction of the Carolingian trench bottom support the hypothesis that the Fossa was primarily planned as a navigable chain of ponds and not as a continuous canal. In the eastern part of the trench, a dam is located that was postulated in former studies to be part of a barrage for supplying the Carolingian canal with water. New ¹⁴C data indicate much younger ages and do not support the Carolingian barrage concept.     

A rock magnetic record from Lama Lake, Taymyr Peninsula, northern Central Siberia

An 11 m long sediment core ftorn Lama Lake, Northern Siberia, has been subjected to intense sedimentological, geochemical and rock magnetic analyses. According to a palynologic investigation the recovered sediments cover the whole Holocene and the late Pleistocene reaching back to about 17 ka. IRM acquisition experiments, hysteresis loop and back field as well as thermomagnetic measurements revealed magnetite in the pseudo-single domain range as the only remanence carrier. Sharp rock magnetic boundaries occur at 20 and 745 cm sub-bottom depth that are clearly linked to shifts in the median grain size of the magnetite. These boundaries are close to the present boundaries that bracket an anoxic zone between the subrecent and a late Pleistocene oxic section of the sediments. Within the anoxic section, magnetites are characterized by significantly larger median grain sizes but within a very narrow grain size range. The shift from fine grained magnetite within the oxic sediments to coarse grained magnetite is interpreted as the result of dissolution of the finest magnetite grains within the anoxic sediments. A significant shift of the Ti/Fe-ratio of the bulk sediment at a sub-bottom depth of 735 cm does not correspond to thermomagnetic properties, i.e. Curie-temperatures do not follow the variable Ti-content of the sediment.     

Late Neogene Atlantic circulation model

A hydrodynamical-numerical model of the general circulation in the Paleo-Atlantic Ocean is applied to the climatological conditions of the period 3.6 to 2.4 m.a. b.p. For three different stages of this interval representing the transition from a warmer to a cooler climate the circulation and the temperature fields are calculated. Generally, a tendency towards a weakening of the currents is achieved.

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Zusammenfassung Ein hydrodynamisch-numerisches Modell der allgemeinen Zirkulation im Paläoatlantik wird mit den klimatologischen Randbedingungen der Periode 3.6 bis 2.4 m.a. zurück betrieben. Für drei verschiedene Zustände dieses Intervalls, die den Übergang von einer Warmzeit zu einer Kaltzeit darstellen, werden die Zirkulation und die Temperaturverteilung berechnet. Generell ergibt sich ein Trend zu einer Abschwächung des Strömungssystems.

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Résumé Un modèle numérique hydrodynamique de la circulation générale dans l'Océan Paléoatlantique est appliqué aux conditions climatiques de la période comprise entre 3.6 et 2.4 ma. Pour trois moments différents de cet intervalle, représentant la transition entre un climat plus chaud et un climat plus froid, on a calculé la distribution des circulations et des températures. En général, on observe que les courants ont tendance à atténuer.

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Mineralogy of the lunar crust: Results from Clementine

Abstract— The central peaks of 109 impact craters across the Moon are examined with Clementine ultraviolet-visible (UVVIS) camera multispectral data. The craters range in diameter from 40 to 180 km and are believed to have exhumed material from 5–30 km beneath the surface to form the peaks, including both upper and lower crustal rocks depending on whether craters have impacted into highlands or basins. Representative five-color spectra from spectrally and spatially distinct areas within the peaks are classified using spectral parameters, including “key ratio” (which is related to mafic mineral abundance) and “spectral curvature” (linked to absorption band shape, which distinguishes between low- and high-Ca pyroxene and olivine). The spectral parameters are correlated to mineralogical abundances, related in turn to highland plutonic rock compositions. The derived rock compositions for the various central peaks are presented in a global map. From these results, it is evident that the lunar crust is compositionally diverse, both globally and at local 100 m scales found within individual sets of central peaks. Although the central peaks compositions imply a crust that is generally consistent with previous models of crustal structure, they also indicate a more anorthositic crust than generally assumed, with a bulk plagioclase content of ～81%, evolving from “pure” anorthosite near the surface towards more mafic, low-Ca pyroxene-rich compositions with depth (comparable to anorthositic norite). Evidence for mafic plutons occurs in both highlands and basins and represent all mafic highland rock types. However, the lower crust is more compositionally diverse than the highlands, with both a greater range of rock types and more diversity within individual sets of central peaks.     

Mediterranean climate extremes in synoptic downscaling assessments

The behaviour of precipitation and maximum temperature extremes in the Mediterranean area under climate change conditions is analysed in the present study. In this context, the ability of synoptic downscaling techniques in combination with extreme value statistics for dealing with extremes is investigated. Analyses are based upon a set of long-term station time series in the whole Mediterranean area. At first, a station-specific ensemble approach for model validation was developed which includes (1) the downscaling of daily precipitation and maximum temperature values from the large-scale atmospheric circulation via analogue method and (2) the fitting of extremes by generalized Pareto distribution (GPD). Model uncertainties are quantified as confidence intervals derived from the ensemble distributions of GPD-related return values and described by a new metric called “ratio of overlapping”. Model performance for extreme precipitation is highest in winter, whereas the best models for maximum temperature extremes are set up in autumn. Valid models are applied to a 30-year period at the end of the twenty-first century (2070–2099) by means of ECHAM5/MPI-OM general circulation model data for IPCC SRES B1 scenario. The most distinctive future changes are observed in autumn in terms of a strong reduction of precipitation extremes in Northwest Iberia and the Northern Central Mediterranean area as well as a simultaneous distinct increase of maximum temperature extremes in Southwestern Iberia and the Central and Southeastern Mediterranean regions. These signals are checked for changes in the underlying dynamical processes using extreme-related circulation classifications. The most important finding connected to future changes of precipitation extremes in the Northwestern Mediterranean area is a reduction of southerly displaced deep North Atlantic cyclones in 2070–2099 as associated with a strengthened North Atlantic Oscillation. Thus, the here estimated future changes of extreme precipitation are in line with the discourse about the influence of North Atlantic circulation variability on the changing climate in Europe.