Rotational contours of CH2X chain species compared with several diffuse interstellar bands

We have calculated synthetic spectra of perpendicular and parallel rovibronic bands of cumulene carbene molecules of the form C _n H₂. The perpendicular bands are consistent with a regularly spaced group of diffuse interstellar bands (DIBs) near 6850 Å. Parallel bands calculated for these molecular structures are consistent with the intrinsic profile of the associated 6614-Å DIB. Both types of bands are expected for an electronic transition that these species should have at those energies. We could not determine if the molecule was charged or if an atom other than carbon terminated the chain-end. Constraints due to molecular geometry and temperature place the chain length at 7–15 carbons to fit the 6850-Å group and 9–13 carbons to fit the 6614-Å DIB.     

Is there an observable lack of reciprocity in PKP(DF) traveltimes?

On average, traveltimes of PKP_DF for equatorial ray paths through the quasieastern hemisphere of the inner core are around 0.5 s faster than equivalent ray paths through its quasiwestern hemisphere. In these observations, the eastern hemisphere is sampled primarily by westward and the western hemisphere by eastwardpropagating waves. Noting that westward propagation is faster than eastward propagation inside a rotating earth, I estimate the expected traveltime difference from Coriolis splitting of the displacement eigenfunctions of the PKP_DF equivalent modes. It turns out that Coriolis effects are too small to give rise to residuals of the required magnitude. Thus, the observations must be primarily due to velocity heterogeneities.     

Metamorphic petrology of a high‐T/low‐P granulite terrane (Damara belt,Namibia) – Constraints from pseudosection modelling and high‐precision Lu–Hf garnet‐whole rock dating

Migmatites comprise a minor volume of the high‐grade part of the Damara orogen of Namibia that is dominated by granite complexes and intercalated metasedimentary units. Migmatites of the Southern Central Zone of the Damara orogen consist of melanosomes with garnet+cordierite+biotite+K‐feldspar, and leucosomes, which are sometimes garnet‐ and cordierite‐bearing. Field evidence, petrographic observations, and pseudosection modelling suggest that, in contrast to other areas where intrusion of granitic magmas is more important, in situ partial melting of metasedimentary units was the main migmatite generation processes. Pseudosection modelling and thermobarometric calculations consistently indicate that the peak‐metamorphic grade throughout the area is in the granulite facies (~5 kbar at ~800°C). Cordierite coronas around garnet suggest some decompression from peak‐metamorphic conditions and rare andalusite records late, near‐isobaric cooling to <650°C at low pressures of ~3 kbar. The inferred clockwise P–T path is consistent with minor crustal thickening through continent–continent collision followed by limited post‐collisional exhumation and suggests that the granulite facies terrane of the Southern Central Zone of the Damara orogen formed initially in a metamorphic field gradient of ~35–40°C/km at medium pressures. New high‐precision Lu–Hf garnet‐whole rock dates are 530 ± 13 Ma, 522.0 ± 0.8 Ma, 520.8 ± 3.6 Ma, and 500.3 ± 4.3 Ma for the migmatites that record temperatures of ~800°C. This indicates that high‐grade metamorphism lasted for c. 20–30 Ma, which is compatible with previous estimates using Sm–Nd garnet‐whole rock systematics. In previous studies on Damara orogen migmatites where both Sm–Nd and Lu–Hf chronometers have been applied, the dates (c. 520–510 Ma) agree within their small uncertainties (0.6–0.8% for Sm–Nd and 0.1–0.2% for Lu–Hf). This implies rapid cooling after high‐grade conditions and, by implication, rapid exhumation at that time. The cause of the high geothermal gradient inferred from the metamorphic conditions is unknown but likely requires some extra heat that was probably added by intrusion of magmas from the lithospheric mantle, i.e., syenites that have been recently re‐dated at c. 545 Ma. Some granites derived from the lower crust at c. 545 Ma are the outcome rather than the cause of high‐T metamorphism. In addition, high contents of heat‐producing elements K, Th, and U may have raised peak temperatures by 150–200°C at the base of the crust, resulting in the widespread melting of fertile crustal rocks. The continuous gradation from centimetre‐scale leucosomes to decametre‐scale leucogranite sheets within the high‐grade metamorphic zone suggests that leucosome lenses coalesced to form larger bodies of anatectic leucogranites, thereby documenting a link between high‐grade regional metamorphism and Pan‐African magmatism. In view of the close association of the studied high‐T migmatites with hundreds of synmetamorphic high‐T granites that invaded the terrane as metre‐ to decametre‐wide sills and dykes, we postulate that crystallization of felsic lower crustal magma is, at least partly, responsible for heat supply. Late‐stage isobaric cooling of these granites may explain the occurrence of andalusite in some samples.     

Effects of area under‐estimations of sloped mountain terrain on simulated hydrological behaviour: a case study using the ACRU model

Sloped areas calculated from a GIS raster file, such as a digital elevation model, are smaller than the true surface area, because they are projected to a planimetric plane. In mountainous regions this sloped area under‐estimation (SAUE) can have significant consequences on hydrological calculations. A sensitivity analysis is conducted, using the ACRU agro‐hydrological modelling system in a small watershed in Glacier National Park, Montana, USA, to investigate the sensitivity of the SAUE on key elements of the hydrological cycle, including precipitation depth, April snow depth, August soil moisture deficit, actual evapotranspiration depth, and runoff depth. The sensitivity analysis is based on 224 unique combinations of slope, soil and land cover types, elevation with associated precipitation depths, and north and south facing radiation regimes. Results revealed an increasing influence of the SAUE on all hydrological processes with increasing slope steepness. Distinct differences and magnitudes between different land cover types, different elevations, and, in particular, different exposition were quantified. Actual evapotranspiration increases with SAUE, while runoff decreases. April soil water is simulated to decrease with an increase in SAUE. Finally, a comparison of a streamflow simulation of a small and steep alpine watershed with and without consideration of the SAUE is carried out. The sloped area of the small watershed is under‐estimated by 20·9%, and the difference in simulated runoff is 12·3%. When the SAUE was not considered, runoff was simulated to be higher, the associated coefficient of determination was slightly lower, and the slope of the regression line was flatter. Copyright © 2010 John Wiley & Sons, Ltd.     

Synoptic drivers of 400 years of summer temperature and precipitation variability on Mt. Olympus,Greece

The Mediterranean region has been identified as a global warming hotspot, where future climate impacts are expected to have significant consequences on societal and ecosystem well-being. To put ongoing trends of summer climate into the context of past natural variability, we reconstructed climate from maximum latewood density (MXD) measurements of Pinus heldreichii (1521–2010) and latewood width (LWW) of Pinus nigra (1617–2010) on Mt. Olympus, Greece. Previous research in the northeastern Mediterranean has primarily focused on inter-annual variability, omitting any low-frequency trends. The present study utilizes methods capable of retaining climatically driven long-term behavior of tree growth. The LWW chronology corresponds closely to early summer moisture variability (May–July, r = 0.65, p < 0.001, 1950–2010), whereas the MXD-chronology relates mainly to late summer warmth (July–September, r = 0.64, p < 0.001; 1899–2010). The chronologies show opposing patterns of decadal variability over the twentieth century (r = ?0.68, p < 0.001) and confirm the importance of the summer North Atlantic Oscillation (sNAO) for summer climate in the northeastern Mediterranean, with positive sNAO phases inducing cold anomalies and enhanced cloudiness and precipitation. The combined reconstructions document the late twentieth—early twenty-first century warming and drying trend, but indicate generally drier early summer and cooler late summer conditions in the period ~1700–1900 CE. Our findings suggest a potential decoupling between twentieth century atmospheric circulation patterns and pre-industrial climate variability. Furthermore, the range of natural climate variability stretches beyond summer moisture availability observed in recent decades and thus lends credibility to the significant drying trends projected for this region in current Earth System Model simulations.     

Integrating GRASS GIS and Jupyter Notebooks to facilitate advanced geospatial modeling education

Open education materials are critical for the advancement of open science and the development of open-source software. These accessible and transparent materials provide an important pathway for sharing both standard geospatial analysis workflows and advanced research methods. Computational notebooks allow users to share live code with in-line visualizations and narrative text, making them a powerful interactive teaching tool for geospatial analytics. Specifically, Jupyter Notebooks are quickly becoming a standard format in open education. In this article, we introduce a new GRASS GIS package, grass.jupyter , that enhances the existing GRASS Python API to allow Jupyter Notebook users to easily manage and visualize GRASS data including spatiotemporal datasets. While there are many Python-based geospatial libraries available for use in Jupyter Notebooks, GRASS GIS has extensive geospatial functionality including support for multi-temporal analysis and dynamic simulations, making it a powerful teaching tool for advanced geospatial analytics. We discuss the development of grass.jupyter and demonstrate how the package facilitates teaching open-source geospatial modeling with a collection of Jupyter Notebooks designed for a graduate-level geospatial modeling course. The open education notebooks feature spatiotemporal data visualizations, hydrologic modeling, and spread simulations such as the spread of invasive species and urban growth.     

‘I hate sand … it gets everywhere’—Phanerozoic sedimentary recycling from NW Africa

Over 10,000 published detrital zircon ages have been reprocessed (applying a +10% normal and reverse concordance range) and analysed to understand the evolution of the detrital zircon record of north-west Africa during the Phanerozoic. Using dissimilarity and clustering analysis, shifts in detrital zircon populations allow interpretation of the evolution of source regions and source to sink systems throughout the Phanerozoic within the West Gondwana superfan. Previous thermochronology and field studies conducted across north-west Africa indicate significant and sustained shifts in source regions in Meso-Cenozoic times which are not recorded in the detrital zircon geochronology record. This discrepancy is most notable for Mesozoic to modern source to sink studies focused on the evolution of the Atlasic rift and opening of the Atlantic and Tethyan Oceans to the west and north respectively. Our results indicate a high degree of similarity between samples from Cambrian times onwards due to successive phases of sediment recycling. This highlights the need to integrate detrital zircon analysis with other techniques to provide confident reconstruction of sediment routing systems across Morocco. This systematic review also reveals the ubiquitous occurrence of Mesoproterozoic zircons within Moroccan sediment. No basement of this age is known from north-west Africa—often described as the ‘Mesoproterozoic Gap’, which was thought to be a diagnostic feature of sediment derived from the West African Craton. However, zircons of this age form 7% of all analysed zircons and are present in sediments from at least 700 Ma. The presence of this population is interpreted as strongly diagnostic of provenance from either the Amazonian Craton or the Eastern Gondwana Orogen within Central Africa. Their presence in the Moroccan detrital record from the Neoproterozoic onwards raises questions about the position of the West African Craton in the Proterozoic, and for the spatial extent of Mesoproterozoic orogeny within north Africa.