Hydrograph separation using tracers and digital filters to quantify runoff components in a semi‐arid mesoscale catchment

Chemical hydrograph separation using electrical conductivity and digital filters is applied to quantify runoff components in the 1,640 km² semi‐arid Kaap River catchment and its subcatchments in South Africa. A rich data set of weekly to monthly water quality data ranging from 1978 to 2012 (450 to 940 samples per site) was analysed at 4 sampling locations in the catchment. The data were routinely collected by South Africa's national Department of Water and Sanitation, using standard sampling procedures. Chemical hydrograph separation using electrical conductivity (EC) as a tracer was used as reference and a recursive digital filter was then calibrated for the catchment. Results of the two‐component hydrograph separation indicate the dominance of baseflow in the low flow regime, with a contribution of about 90% of total flow; however, during the wet season, baseflow accounts for 50% of total flow. The digital filter parameters were very sensitive and required calibration, using chemical hydrograph separation as a reference. Calibrated baseflow estimates ranged from 40% of total flow at the catchment outlet to 70% in the tributaries. The study demonstrates that routinely monitored water quality data, especially EC, can be used as a meaningful tracer, which could also aid in the calibration of a digital filter method and reduce uncertainty of estimated flow components. This information enhances our understanding of how baseflow is generated and contributed to streamflow throughout the year, which can aid in quantification of environmental flows, as well as to better parameterize hydrological models used for water resources planning and management. Baseflow estimates can also be useful for groundwater and water quality management.     

Trends in temperature and rainfall extremes in the Yellow River source region, China

Spatial and temporal changes in daily temperature and rainfall indices are analyzed for the source region of Yellow River. Three periods are examined: 1960–1990, 1960–2000 and 1960–2006. Significant warming trends have been observed for the whole study region over all the three periods, particularly over the period 1960–2006. This warming is mainly attributed to a significant increase in the minimum temperature, and characterized by pronounced changes in the low temperature events composing a significant increase in the magnitude and a significant decrease in the frequency. In contrast to the temperature indices, no significant changes have been observed in the rainfall indices at the majority of stations. However, the rainfall shows noticeable increasing trends during winter and spring from a basin-wide point of view. Conversely, the frequency and contribution of moderately heavy rainfall events to total rainfall show a significant decreasing trend in summer. To conclude, this study shows that over the past 40–45 years the source region of the Yellow River has become warmer and experienced some seasonally varying changes in rainfall, which also supports an emerging global picture of warming and the prevailing positive trends in winter rainfall extremes over the mid-latitudinal land areas of the Northern Hemisphere.     

Heat and moisture budgets from airborne measurements and high-resolution model simulations

High-resolution simulations with a mesoscale model are performed to estimate heat and moisture budgets of a well-mixed boundary layer. The model budgets are validated against energy budgets obtained from airborne measurements over heterogeneous terrain in Western Germany. Time rate of change, vertical divergence, and horizontal advection for an atmospheric column of air are estimated. Results show that the time trend of specific humidity exhibits some deficiencies, while the potential temperature trend is matched accurately. Furthermore, the simulated turbulent surface fluxes of sensible and latent heat are comparable to the measured fluxes, leading to similar values of the vertical divergence. The analysis of different horizontal model resolutions exhibits improved surface fluxes with increased resolution, a fact attributed to a reduced aggregation effect. Scale-interaction effects could be identified: while time trends and advection are strongly influenced by mesoscale forcing, the turbulent surface fluxes are mainly controlled by microscale processes.     

Constrained simulations of the local universe – II. The nature of the local Hubble flow

Using a suite of N -body simulations in different cold dark matter (CDM) scenarios, with cosmological constant (ΛCDM) and without (OCDM, SCDM), we study the Hubble flow (σ_H) in Local Volumes (LV) around Local Group (LG) like objects found in these simulations, and compare the numerical results with the most recent observations. We show that ΛCDM and OCDM models exhibit the same behaviour of σ_H. Hence, we demonstrate that the observed coldness of the Hubble flow is not likely to be a manifestation of the dark energy, contrary to previous claims. The coldness does not constitute a problem by itself but it poses a problem to the standard ΛCDM model only if the mean density within the LV is greater than twice the mean matter cosmic density. The lack of blueshifted galaxies in the LV, outside of the LG can be considered as another manifestation of the coldness of the flow. Finally, we show that the main dynamical parameter that affects the coldness of the flow is the relative isolation of the LG, and the absence of nearby Milky Way like objects within a distance of about  3 Mpc  .     

Cluster strong lensing in the Millennium simulation: the effect of galaxies and structures along the line-of-sight

We use ray-tracing through the Millennium simulation to study how secondary matter structures along the line-of-sight and the stellar mass in galaxies affect strong cluster lensing, in particular the cross-section for giant arcs. Furthermore, we investigate the distribution of the cluster Einstein radii and the radial distribution of giant arcs. We find that additional structures along the line-of-sight increase the strong-lensing optical depth by  ∼10–25 per cent  , while strong-lensing cross-sections of individual clusters are frequently boosted by as much as  ∼50 per cent  . The enhancement is mainly due to structures that are not correlated with the lens. Cluster galaxies increase the strong-lensing optical depth by up to a factor of 2, while interloping galaxies are not significant. We conclude that these effects need to be taken into account for predictions of the giant arc abundance, but they are not large enough to fully account for the reported discrepancy between predicted and observed abundances.
Furthermore, we find that Einstein radii defined via the area enclosed by the critical curve are 10–30 per cent larger than those defined via radial surface mass density profiles. The contributions of radial and tangential arcs to the radial distribution of arcs can be clearly distinguished. The radial distribution of tangential arcs is very broad and extends out to several Einstein radii. Thus, individual arcs are not well suited for constraining Einstein radii.     

最早的栉水母动物化石——华南伊迪 卡拉纪的“八臂仙母虫”

华南伊迪卡拉系陡山沱组保存的磷酸盐化球状化石中有一部分被认为是最早的后生动物胚胎化石, 但由于缺乏成年或幼年过渡期的化石证据, 对这些最早微化石的动物属性还一直存在争议。最近在贵州江口县翁会地区伊迪卡拉(震旦)系陡山沱组的页岩中发现一个与“庙河生物群”相似的宏体碳质压膜化石群, 其中包含一个盘状的宏体化石新类型——八臂仙母虫(Eoandromeda octobrachiata, Tang et al. 2008), 具有八条螺旋状辐射的旋臂, 封闭在一个包膜内。这种八辐射结构在八射珊瑚和栉水母动物中都可见到, 但同时具有的螺旋特性与现生的所有类群都无法对比。在贵州陡山沱组的“瓮安生物群”中发现的球状胚胎化石同样具有螺旋性状, 尽管还没有直接的个体发育证据, 但我们认为新属种可能代表这些螺旋状胚胎化石的成年实体化石。最新报道的南澳大利亚Rawnsley石英岩层中也发现相似的印痕化石, 被归为同一类别, 表明华南的“庙河生物群”与澳大利亚的“伊迪卡拉生物群”时代相当。翁会化石库中少量出露的三辐射化石与俄罗斯“白海生物群”的典型分子—Albumares和Anfesta可以对比。新发现的倾斜保存的八臂仙母虫化石和碳质条带呈子午线状排列的核桃状化石, 可能是该类化石归属栉水母类的有力证据, 这一发现推测可将栉水母类的最早化石记录从“澄江生物群”的早寒武世推前大约3千万年。     

Comparison of groundwater recharge estimation methods for the semi-arid Nyamandhlovu area, Zimbabwe

The Nyamandhlovu aquifer is the main water resource in the semi-arid Umguza district in Matebeleland North Province in Zimbabwe. The rapid increase in water demand in the city of Bulawayo has prompted the need to quantify the available groundwater resources for sustainable utilization. Groundwater recharge estimation methods and results were compared: chloride mass balance method (19–62 mm/year); water-table fluctuation method (2–50 mm/year); Darcian flownet computations (16–28 mm/year); ¹⁴C age dating (22–25 mm/year); and groundwater modeling (11–26 mm/year). The flownet computational and modeling methods provided better estimates for aerial recharge than the other methods. Based on groundwater modeling, a final estimate for recharge (from precipitation) on the order of 15–20 mm/year is believed to be realistic, assuming that part of the recharge water transpires from the water table by deep-rooted vegetation. This recharge estimate (2.7–3.6% of the annual precipitation of 555 mm/year) compares well with the results of other researchers. The advantages/disadvantages of each recharge method in terms of ease of application, accuracy, and costs are discussed. The groundwater model was also used to quantify the total recharge of the Nyamandhlovu aquifer system (20?×?10⁶–25?×?10⁶ m³/year). Groundwater abstractions exceeding 17?×?10⁶ m³/year could cause ecological damage, affecting, for instance, the deep-rooted vegetation in the area.     

Impact of lateral transport on organic proxies in the Southern Ocean

Lateral transport of fine-grained organic carbon particles can complicate the interpretation of paleoclimate records based on organic proxies. Here we investigated the effect of lateral transport on newly developed temperature and soil organic matter proxies, TEX₈₆ and BIT index, respectively, in core MD88-769 recovered from the South East Indian Ridge. Our results show that TEX₈₆ and BIT records in comparison to diatom and foraminifera records were representative for more local climate changes while alkenones and n-alkanes originated from distant areas by oceanic and atmospheric transport, respectively. This suggests that TEX₈₆ and BIT paleoclimate records are primarily influenced by local conditions and less subjected to long-distance lateral transport than other organic proxies in the Southern Ocean.     

Occurrence and biomarker potential of 23-methyl steroids in diatoms and sediments

23-Methyl sterols have been reported to be synthesized by a few marine algae, but unambiguous identification of 23-methyl steroids in sediments and petroleum is lacking. We report the presence of 23-methylcholesta-5,22E-dien-3β-ol in 14 out of 106 diatom cultures, thereby showing that diatoms, together with dinoflagellates, may be an important environmental source for such steroids. Synthesis of authentic 23-methylcholestanes showed that their mass spectra are identical to those of 24-methylcholestanes, but that they elute earlier on apolar stationary phases during gas chromatography (GC) analysis. Co-injection of the authentic standards with sediment extracts revealed the presence of these compounds in the Skole unit of the Oligocene Menelite Formation, the Miocene Monterey Formation and the Messinian Vena del Gesso Formation. In addition, we tentatively identified 23,24-dimethyl-27-norcholestanes in some of these sediments. Molecular clock calculations suggest that diatoms are a possible source for 23-methyl steroids in sediments and petroleum from the late Jurassic onwards.     

Effects of long term oxic degradation on the U37K′, TEX86 and BIT organic proxies

One of the primary prerequisites for the application of organic proxies is that they should not be substantially affected by diagenesis. However, studies have shown that oxic degradation of biomarker lipids can affect their relative distribution. We tested the diagenetic stability of the $U_{37}^{K^{\prime }}$ and TEX₈₆ palaeothermometers upon long term oxygen exposure. For this purpose, we studied the distributions of alkenones and glycerol dialkyl glycerol tetraethers (GDGTs) in different sections of turbidites at the Madeira Abyssal Plain (MAP) that experienced different degrees of oxygen exposure. Sediments were deposited anoxically on the shelf and then transported by turbidity currents to the MAP, which has oxic bottom water. This resulted in partial degradation of the turbidite organic matter as a result of long term exposure to oxic bottom water. Concentrations of GDGTs and alkenones were reduced by one to two orders of magnitude in the oxidized parts of the turbidites compared to the unoxidized parts, indicating substantial degradation. High-resolution analysis of the Pleistocene F-turbidite showed that the $U_{37}^{K^{\prime }}$ index of long chain alkenones increased only slightly (0.01, corresponding to <0.5 °C) in the oxidized part of the turbidite, suggesting minor preferential degradation of the C_37:3 alkenone, in agreement with previous studies. TEX₈₆ values showed a small increase (0.02, corresponding to ～2 °C) in the F-turbidite, like $U_{37}^{K^{\prime }}$, while for other Pliocene/Miocene turbidites it either remained unchanged or decreased substantially (up to 0.06, corresponding to ～6 °C). Previous observations showed that the BIT index, a proxy for the contribution of soil organic matter to total organic carbon, was always substantially higher in the oxidized part in all the turbidites, as a result of preferential degradation of marine-derived GDGTs. This relative increase in soil-derived GDGTs affects TEX₈₆, as the isoprenoid GDGT distribution on the continent can be quite different from that in the marine environment. Our results indicate that the organic proxies are affected by long term oxic degradation to different extents; this should be taken into account when applying these proxies in palaeoceanographic studies of sediments which have been exposed to prolonged oxic degradation.